A nitrogen model for European catchments: INCA, new model structure and equations

Abstract. A new version of the Integrated Nitrogen in Catchments model (INCA) was developed and tested using flow and streamwater nitrate concentration data collected from the River Kennet during 1998. INCA is a process-based model of the nitrogen cycle in the plant/soil and in-stream systems. The model simulates the nitrogen export from different land-use types within a river system, and the in-stream nitrate and ammonium concentrations at a daily time-step. The structure of the new version differs from the original, in that soil-water retention volumes have been added and the interface adapted to permit multiple crop and vegetation growth periods and fertiliser applications. The process equations are now written in terms of loads rather than concentrations allowing a more robust tracking of mass conservation when using numerical integration. The new version is able to reproduce the seasonal dynamics observed in the streamwater nitrogen concentration data, and the loads associated with plant/soil system nitrogen processes reported in the literature. As such, the model results suggest that the new structure is appropriate for the simulation of nitrogen in the River Kennet and an improvement on the original model. The utility of the INCA model is discussed in terms of improving scientific understanding and catchment management. Keywords: modelling, water quality, nitrogen, nitrate, River Kennet, River Thames

[1]  Marie-Odile Cordier,et al.  Parameterisation of hydrological models: a review and lessons learned from studies of an agricultural catchment (Naizin, France) , 2002 .

[2]  R. Harding,et al.  The water use of the Balquhidder catchments: a processes approach , 1993 .

[3]  N Oreskes,et al.  Verification, Validation, and Confirmation of Numerical Models in the Earth Sciences , 1994, Science.

[4]  M. Field,et al.  The meteorological office rainfall and evaporation calculation system -- MORECS , 1983 .

[5]  Véronique Beaujouan,et al.  Modelling the effect of the spatial distribution of agricultural practices on nitrogen fluxes in rural catchments , 2001 .

[6]  J. Wright,et al.  A comparison of the macrophyte cover and macroinvertebrate fauna at three sites on the River Kennet in the mid 1970s and late 1990s. , 2002, The Science of the total environment.

[7]  C. Neal,et al.  On modelling the effects of afforestation on acidification in heterogeneous catchments at different spatial and temporal scales , 2001 .

[8]  A. Edwards,et al.  The prediction and management of water quality in a relatively unpolluted major Scottish catchment: current issues and experimental approaches , 1997 .

[9]  E. J. Wilson,et al.  A semi-distributed integrated flow and nitrogen model for multiple source assessment in catchments (INCA): Part II — application to large river basins in south Wales and eastern England , 1998 .

[10]  C. Neal A view of water quality from the Plynlimon watershed , 1997 .

[11]  E. J. Wilson,et al.  A semi-distributed ntegrated itrogen model for multiple source assessment in tchments (INCA): Part I — model structure and process equations , 1998 .

[12]  L. Frederick Introduction to Soil Microbiology , 1962 .

[13]  George M. Hornberger,et al.  Eutrophication in peel inlet—III. A model for the nitrogen scenario and a retrospective look at the preliminary analysis , 1984 .

[14]  G. Hornberger Eutrophication in peel inlet—I. The problem-defining behavior and a mathematical model for the phosphorus scenario , 1980 .

[15]  F. Green,et al.  Altitudinal gradients of soil temperatures in Europe. , 1980 .

[16]  Keith Beven,et al.  Prophecy, reality and uncertainty in distributed hydrological modelling , 1993 .

[17]  A. Gustard,et al.  Low flow estimation in Scotland , 1987 .

[18]  W. Bowden The biogeochemistry of nitrogen in freshwater wetlands , 1987 .

[19]  E. Matzner,et al.  N fluxes in two nitrogen saturated forested catchments in Germany: dynamics and modelling with INCA , 2002 .

[20]  J. Nash,et al.  River flow forecasting through conceptual models part I — A discussion of principles☆ , 1970 .

[21]  J. Kirchner,et al.  Fractal stream chemistry and its implications for contaminant transport in catchments , 2000, Nature.

[22]  Andrew J. Wade,et al.  The prediction and management of aquatic nitrogen pollution across Europe: an introduction to the Integrated Nitrogen in European Catchments project (INCA) , 2002 .

[23]  R. Spear Eutrophication in peel inlet—II. Identification of critical uncertainties via generalized sensitivity analysis , 1980 .

[24]  Keith Beven,et al.  Bayesian estimation of uncertainty in land surface‐atmosphere flux predictions , 1997 .

[25]  P G Whitehead,et al.  Steady state and dynamic modelling of nitrogen in the River Kennet: impacts of land use change since the 1930s. , 2002, The Science of the total environment.

[26]  Helen P Jarvie,et al.  Water quality functioning of lowland permeable catchments: inferences from an intensive study of the RIVER KENNEt and upper River Thames. , 2002, The Science of the total environment.

[27]  David S Lee,et al.  Acid deposition in the United Kingdom 1992-1994 , 1997 .

[28]  W. A. Virtue,et al.  Modelling nitrogen dynamics and distributions in the River Tweed, Scotland: an application of the INCA model , 2002 .