Novel phosphorus-doped lead oxide electrode for oxygen evolution reaction

A facile and cost-effective electrochemical approach was proposed for the first time to prepare a phosphorus-doped lead dioxide (P-PbO2) electrode on a lead substrate. This was achieved by introducing a pyrophosphate solution containing Cu2+, F− and peptone as essential additives. Such a novel P-PbO2 electrode exhibits a significantly improved electrocatalytic activity for the oxygen evolution reaction as compared to a traditional Pb/PbO2 electrode.

[1]  D. Nocera,et al.  Proton-electron transport and transfer in electrocatalytic films. Application to a cobalt-based O2-evolution catalyst. , 2013, Journal of the American Chemical Society.

[2]  Y. Lai,et al.  Electrochemical behaviors of co-deposited Pb/Pb–MnO2 composite anode in sulfuric acid solution – Tafel and EIS investigations , 2012 .

[3]  Y. Lai,et al.  Oxygen evolution and corrosion behaviors of co-deposited Pb/Pb-MnO2 composite anode for electrowinning of nonferrous metals , 2011 .

[4]  D. Pinisetty,et al.  Fabrication and characterization of electrodeposited antimony telluride crystalline nanowires and nanotubes , 2011 .

[5]  Weiqing Zhang,et al.  Mesoporous cobalt oxide film prepared by electrodeposition as anode material for Li ion batteries , 2010 .

[6]  Yingjie Zhu,et al.  Monodisperse α-Fe2O3 Mesoporous Microspheres: One-Step NaCl-Assisted Microwave-Solvothermal Preparation, Size Control and Photocatalytic Property , 2010, Nanoscale research letters.

[7]  A. Fekry,et al.  Electrochemical impedance studies of modified Ni–P and Ni–Cu–P deposits in alkaline medium , 2010 .

[8]  D. Gardner,et al.  Electrodeposited amorphous Co–P based alloy with improved thermal stability , 2010 .

[9]  Huiling Liu,et al.  Comparative studies on the electrocatalytic properties of modified PbO2 anodes , 2008 .

[10]  A. N. Gavrilov,et al.  Influence of structural defects on the electrocatalytic activity of platinum , 2008 .

[11]  F. Delogu,et al.  Electrochemical performance of mechanically treated SnO2 powders for OER in acid solution , 2008 .

[12]  Jian-qing Zhang,et al.  The influence of F- doping on the activity of PbO2 film electrodes in oxygen evolution reaction , 2007 .

[13]  D. Devilliers,et al.  Electrodeposition of Fluorine-doped Lead Dioxide , 2007 .

[14]  D. Pletcher,et al.  The fabrication of lead dioxide layers on a titanium substrate , 2006 .

[15]  W. Jardim,et al.  Influence of the Electrolyte Composition on the Kinetics of the Oxygen Evolution Reaction and Ozone Production Processes , 2006 .

[16]  Y. Stefanov,et al.  Developing and studying the properties of Pb–TiO2 alloy coated lead composite anodes for zinc electrowinning , 2005 .

[17]  D. Pletcher,et al.  The Influence of Deposition Conditions and Dopant Ions on the Structure, Activity, and Stability of Lead Dioxide Anode Coatings , 2005 .

[18]  D. Devilliers,et al.  Electroanalytical investigations on electrodeposited lead dioxide , 2004 .

[19]  A. Velichenko,et al.  Oxygen and ozone evolution at fluoride modified lead dioxide electrodes , 1999 .

[20]  Meilin Liu,et al.  Significance of interfaces in solid-state cells with porous electrodes of mixed ionic–electronic conductors , 1998 .

[21]  D. Pavlov,et al.  Mechanism of the Elementary Electrochemical Processes Taking Place during Oxygen Evolution on the Lead Dioxide Electrode , 1996 .

[22]  B. Conway,et al.  Structure influence on electrocatalysis and adsorption of intermediates in the anodic O2 evolution at dimorphic α- and β-PbO2☆ , 1994 .

[23]  J. Vaid,et al.  Electrodeposition of Lead from the Pyrophosphate Bath , 1957 .

[24]  Lijun Gao,et al.  Electrodeposited PbO2 thin film on Ti electrode for application in hybrid supercapacitor , 2009 .