Reliability of ultra thin ZrO2 films on strained-Si

Abstract Ultra thin high- k zirconium oxide (equivalent oxide thickness ∼1.57 nm) films have been deposited on strained-Si/relaxed-Si 0.8 Ge 0.2 heterolayers using zirconium tetra- tert -butoxide (ZTB) as an organometallic source at low temperature ( 2 gate dielectric during constant current (CCS) and voltage stressing (CVS) has been investigated. Stress induced leakage current (SILC) through ZrO 2 is modeled by taking into account the inelastic trap-assisted tunneling (ITAT) mechanism via traps located below the conduction band of ZrO 2 layer. Trap generation rate and trap cross-section are extracted. A capture cross-section in the range of ∼10 −19  cm 2 as compared to ∼10 −16  cm 2 in SiO 2 has been observed. The trapping charge density, Q ot and charge centroid, X t are also empirically modeled. The time dependence of defect density variation is calculated within the dispersive transport model, assuming that these defects are produced during random hopping transport of positively charge species in the insulating layer. Dielectric breakdown and reliability of the dielectric films have been studied using constant voltage stressing. A high time-dependent dielectric breakdown (TDDB, t bd  > 1500 s) is observed under high constant voltage stress.

[1]  Guido Groeseneken,et al.  A consistent model for the thickness dependence of intrinsic breakdown in ultra-thin oxides , 1995, Proceedings of International Electron Devices Meeting.

[2]  J. Stathis Percolation models for gate oxide breakdown , 1999 .

[3]  R. Prins,et al.  Structure and Redox Behavior of Zirconium in Microporous Zr-Silicalites Studied by EXAFS and ESR Techniques , 2001 .

[4]  Marc Heyns,et al.  Charge trapping in very thin high-permittivity gate dielectric layers , 2000 .

[5]  D. Dimaria,et al.  THE PROPERTIES OF ELECTRON AND HOLE TRAPS IN THERMAL SILICON DIOXIDE LAYERS GROWN ON SILICON , 1978 .

[6]  M. Houssa High k Gate Dielectrics , 2003 .

[7]  M. Che,et al.  Characterization and Reactivity of Molecular Oxygen Species on Oxide Surfaces , 1983 .

[8]  Investigation of electrical properties of furnace grown gate oxide on strained-Si , 2004 .

[9]  J. McPherson,et al.  Trends in the ultimate breakdown strength of high dielectric-constant materials , 2003 .

[10]  A. Stesmans,et al.  Trap-assisted tunneling in high permittivity gate dielectric stacks , 2000 .

[11]  F. Geobaldo,et al.  An EPR study on the formation of the superoxide radical ion on monoclinic zirconia , 1991 .

[12]  Physics-based single-piece charge model for strained-Si MOSFETs , 2005, IEEE Transactions on Electron Devices.

[13]  Elyse Rosenbaum,et al.  Mechanism of stress-induced leakage current in MOS capacitors , 1997 .

[14]  A. R. Wazzan,et al.  MOS (Metal Oxide Semiconductor) Physics and Technology , 1986 .

[15]  A. Shluger,et al.  Structure and electrical levels of point defects in monoclinic zirconia , 2001 .

[16]  C. Maiti,et al.  High frequency characterization and continuum modeling of ultrathin high-k (ZrO2) gate dielectrics on strained-Si , 2006 .

[17]  E. Simoen,et al.  Inherent density of point defects in thermal tensile strained (100)Si∕SiO2 entities probed by electron spin resonance , 2006 .

[18]  R. People,et al.  Physics and applications of Ge x Si 1-x /Si strained-layer heterostructures , 1986 .

[19]  J. Fossum,et al.  On the threshold Voltage of strained-Si-Si/sub 1-x/Ge/sub x/ MOSFETs , 2005, IEEE Transactions on Electron Devices.

[20]  C. Sah,et al.  Generation-annealing of oxide and interface traps at 150 and 298 K in oxidized silicon stressed by Fowler-Nordheim electron tunneling , 1988 .

[21]  Morrell H. Cohen,et al.  Paramagnetic Resonance of Oxygen in Alkali Halides , 1959 .

[22]  K. C. Kao,et al.  Electrical Transport in Solids , 1983 .

[23]  S. Selberherr,et al.  Modeling of tunneling current and gate dielectric reliability for nonvolatile memory devices , 2004, IEEE Transactions on Device and Materials Reliability.

[24]  A. Aboukaïs,et al.  Transformation of tetragonal zirconia phase to monoclinic phase in the presence of Fe3+ ions as probes: an EPR study , 1999 .

[25]  John Robertson,et al.  Point defects in HfO2 high K gate oxide , 2005 .

[26]  J.C. Lee,et al.  MOSCAP and MOSFET characteristics using ZrO/sub 2/ gate dielectric deposited directly on Si , 1999, International Electron Devices Meeting 1999. Technical Digest (Cat. No.99CH36318).

[27]  L. Terman An investigation of surface states at a silicon/silicon oxide interface employing metal-oxide-silicon diodes , 1962 .

[28]  H. Ade,et al.  Electronic structure of noncrystalline transition metal silicate and aluminate alloys , 2001 .

[29]  Young-Hee Kim,et al.  Reliability characteristics of high-k dielectrics , 2004, Microelectron. Reliab..

[30]  J. Robertson,et al.  Point defects in ZrO/sub 2/ high-/spl kappa/ gate oxide , 2005, IEEE Transactions on Device and Materials Reliability.

[31]  S. Laux,et al.  Band structure, deformation potentials, and carrier mobility in strained Si, Ge, and SiGe alloys , 1996 .

[32]  F. B. McLean,et al.  Simple approximate solutions to continuous-time-random-walk transport. Technical report. [Applied to charge transport in amorphous materials] , 1976 .

[33]  Generation of superoxide ions at oxide surfaces , 1999 .

[34]  J. McPherson,et al.  Thermochemical description of dielectric breakdown in high dielectric constant materials , 2003 .

[35]  Harry B. Gray,et al.  Electrons and chemical bonding , 1964 .

[36]  P. Lai,et al.  Characterization of charge trapping and high-field endurance for 15-nm thermally nitrided oxides , 1991 .

[37]  C. K. Maiti,et al.  Strained silicon heterostructures : materials and devices , 2001 .