Getting excited about lanthanide complexation chemistry

Lanthanide complexation chemistry in solution is an active research theme because of the importance of gadolinium complexes as contrast agents in magnetic resonance imaging, and of luminescent europium and terbium complexes as probes in biochemistry. The physicochemical principles and theory underpinning this work are being refined to account for recent developments such as the reappraisal of complex hydration state.

[1]  Willem Verboom,et al.  UvA-DARE (Digital Academic Repository) New sensitizer-modified calix[4]arenes enabling near-UV excitation of complexed luminescent lanthanide ions , 2001 .

[2]  G. Mathis.  Probing molecular interactions with homogeneous techniques based on rare earth cryptates and fluorescence energy transfer. , 1995, Clinical chemistry.

[3]  P. Selvin,et al.  Luminescent Polyaminocarboxylate Chelates of Terbium and Europium: The Effect of Chelate Structure , 1995 .

[4]  Gabriel González,et al.  Unexpectedly large change of water exchange rate and mechanism on [Ln(DTPA-BMA)(H2O)] complexes along the lanthanide(III) series , 1995 .

[5]  Joseph H. Reibenspies,et al.  The Amide Oxygen as a Donor Group. Metal Ion Complexing Properties of Tetra-N-acetamide Substituted Cyclen: A Crystallographic, NMR, Molecular Mechanics, and Thermodynamic Study , 1995 .

[6]  Melvyn Rowen Churchill,et al.  Laser-induced luminescence studies and crystal structure of the europium(III) complex of 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane. The link between phosphate diester binding and catalysis by lanthanide(III) macrocyclic complexes , 1995 .

[7]  W. Horrocks,et al.  On correlating the frequency of the 7F0 → 5D0 transition in Eu3+ complexes with the sum of ‘nephelauxetic parameters’ for all of the coordinating atoms , 1995 .

[8]  P. Anelli,et al.  NMR Evidence of a Long Exchange Lifetime for the Coordinated Water in Ln(III)-Bis(methyl amide)-DTPA Complexes (Ln = Gd, Dy) , 1994 .

[9]  M. Botta,et al.  Solution and Solid-State Characterization of Highly Rigid, Eight-Coordinate Lanthanide(III) Complexes of a Macrocyclic Tetrabenzylphosphinate , 1994 .

[10]  C. Allen Chang,et al.  Characterization of Lanthanide Complexes with a Series of Amide-Based Macrocycles, Potential MRI Contrast Agents, Using Eu3+ Luminescence Spectroscopy and Molecular Mechanics , 1994 .

[11]  Paul R. Selvin,et al.  Luminescence resonance energy transfer , 1994 .

[12]  Melvyn Rowen Churchill,et al.  Lanthanide(III) tetraamide macrocyclic complexes as synthetic ribonucleases: Structure and catalytic properties of [La(tcmc)(CF 3 SO 3 )(EtOH)](CF 3 SO 3 ) 2 , 1994 .

[13]  C. H. Lake,et al.  Synthesis and solution properties of lanthanum(III), europium(III), and lutetium(III) THP complexes and an x-ray diffraction study of a crystal containing four stereoisomers of a europium(III) THP complex (THP = 1,4,7,10-tetrakis(2-hydroxypropyl)-1,4,7,10-tetraazacyclododecane). Methyl groups impart , 1994 .

[14]  M. F. Ottaviani,et al.  Magnetic‐Field‐Dependent Electronic Relaxation of Gd3+ in Aqueous Solutions of the Complexes [Gd(H2O)8]3+, [Gd(propane‐1,3‐diamine‐N,N,N′,N′‐tetraacetate)(H2O)2]−, and [Gd(N,N′‐bis[(N‐methylcarbamoyl)methyl]‐3‐azapentane‐1,5‐diamine‐3,N,N′‐triacetate)(H2O)] of interest in magnetic‐resonance imaging , 1993 .

[15]  J. Guillet,et al.  Synthesis and photophysics of a water-soluble, naphthalene-containing .beta.-cyclodextrin , 1993 .

[16]  R R Edelman,et al.  Magnetic resonance imaging (1). , 1993, The New England journal of medicine.

[17]  G. Mathis,et al.  Europium(III) trisbipyridine cryptate label for time-resolved fluorescence detection of polymerase chain reaction products fixed on a solid support. , 1993, Clinical chemistry.

[18]  Massimo Guardigli,et al.  Luminescent lanthanide complexes as photochemical supramolecular devices , 1993 .

[19]  M. Tweedle,et al.  Macrocyclic polyaminocarboxylate complexes of lanthanides as magnetic resonance imaging contrast agents , 1993 .

[20]  Maurizio Grandi,et al.  Synthesis, characterization, and 1/T1 NMRD profiles of gadolinium(III) complexes of monoamide derivatives of DOTA-like ligands. X-ray structure of the 10-[2-[[2-hydroxy-1-(hydroxymethyl)ethyl]amino]-1-[(phenylmethoxy)methyl]-2-oxoethyl]-1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid-gadolinium( , 1992 .

[21]  Massimo Guardigli,et al.  Luminescence of lanthanide cryptates: effects of phosphate and iodide anions , 1992 .

[22]  Xiangyun Wang,et al.  A kinetic investigation of the lanthanide DOTA chelates. Stability and rates of formation and of dissociation of a macrocyclic gadolinium(III) polyaza polycarboxylic MRI contrast agent , 1992 .

[23]  M. Botta,et al.  Synthesis and NMRD studies of gadolinium(3+) complexes of macrocyclic polyamino polycarboxylic ligands bearing .beta.-benzyloxy-.alpha.-propionic residues , 1992 .

[24]  V. Balzani,et al.  Luminescent europium(3+), terbium(3+) and gadolinium(3+) complexes of a branched-triazacyclononane ligand containing three 2,2'-bipyridine units , 1991 .

[25]  M. Botta,et al.  An NMR relaxation study of aqueous solutions of Gd(III) chelates , 1991 .

[26]  R. Rogers,et al.  Macrocycle complexation chemistry. 35. Survey of the complexation of the open chain 15-crown-5 analog tetraethylene glycol with the lanthanide chlorides , 1991 .

[27]  V. Balzani,et al.  Luminescence Properties of Eu3⊕ and Tb3⊕ Complexes of Branched Macrocyclic Ligands Containing Four 2,2′‐Bipyridine Units , 1991 .

[28]  A. Oser,et al.  Multiple end labeling of oligonucleotides with terbium chelate-substituted psoralen for time-resolved fluorescence detection. , 1990, Analytical biochemistry.

[29]  Vincenzo Balzani,et al.  ANTENNA EFFECT IN LUMINESCENT LANTHANIDE CRYPTATES: A PHOTOPHYSICAL STUDY , 1990 .

[30]  R. Holz,et al.  Spectroscopic characterization of some rare earth complexes of triethylenetetraaminehexaacetic acid , 1990 .

[31]  S. H. Koenig,et al.  Synthesis and Characterization of the Gadolinium(3+) Complex of DOTA-Propylamide: A Model DOTA-Protein Conjugate , 1989 .

[32]  M. Benning,et al.  f-Element/crown ether complexes. 22. Preparation and structural characterization of lanthanide chloride complexes of 12-crown-4 , 1988 .

[33]  E. Diamandis,et al.  A new europium chelate for protein labelling and time-resolved fluorometric applications. , 1988, Clinical biochemistry.

[34]  W K Roth,et al.  Sensitive non-radioactive dot-blot hybridization using DNA probes labelled with chelate group substituted psoralen and quantitative detection by europium ion fluorescence. , 1988, Nucleic acids research.

[35]  R. Lauffer,et al.  Paramagnetic metal complexes as water proton relaxation agents for NMR imaging: theory and design , 1987 .

[36]  Gérard Mathis,et al.  Energy Transfer Luminescence of Europium(III) and Terbium(III) Cryptates of Macrobicyclic Polypyridine Ligands , 1987 .

[37]  J. Desreux,et al.  Structural characterization of a terbium(III) complex with 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetic acid. Lanthanide ions and the conformation of the 14-membered macrocycles , 1984 .

[38]  A. Abusaleh,et al.  EXCITATION and DE‐EXCITATION PROCESSES IN LANTHANIDE CHELATES BEARING AROMATIC SIDECHAINS , 1984, Photochemistry and photobiology.

[39]  S. Segal,et al.  Receptor-mediated endocytosis of tuftsin by macrophage cells. , 1984, Biochemical and biophysical research communications.

[40]  J. Desreux,et al.  Crystal and molecular structure of sodium aqua(1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetato)europate(III) tetrahydrate Na+(EuDOTA.H2O)-.4H2O, and its relevance to NMR studies of the conformational behavior of the lanthanide complexes formed by the macrocyclic ligand DOTA , 1984 .

[41]  V. Balzani,et al.  Energy-transfer processes of excited states of coordination compounds , 1983 .

[42]  N. Turro,et al.  Analysis of static and dynamic host-guest associations of detergents with cyclodextrins via photoluminescence methods , 1982 .

[43]  N. Turro,et al.  A STUDY OF THE KINETICS OF INCLUSION OF HALONAPHTHALENES WITH ß‐CYCLODEXTRIN VIA TIME CORRELATED PHOSPHORESCENCE , 1982 .

[44]  W. Horrocks,et al.  Lanthanide ion luminescence probes of the structure of biological macromolecules , 1981 .

[45]  W. Horrocks,et al.  Time-resolved europium(III) excitation spectroscopy: a luminescence probe of metal ion binding sites. , 1979, Science.

[46]  M. Drew.  Structures of high coordination complexes , 1978 .

[47]  J. Freed.  Dynamic effects of pair correlation functions on spin relaxation by translational diffusion in liquids. II. Finite jumps and independent T1 processes , 1978 .

[48]  C. Kittrell,et al.  Laser-induced lanthanide ion laminescence lifetime measurements by direct excitation of metal ion levels. A new class of structural probe for calcium-binding proteins and nucleic acids. , 1977, Journal of the American Chemical Society.

[49]  Y. Haas,et al.  Pathways of radiative and radiationless transitions in europium(III) solutions. The role of high energy vibrations , 1971 .

[50]  Y. Haas,et al.  Radiative and radiationless transitions in solutions of rare earth ions: Vibrational coupling of H2O and D2O to electronic levels of Gd3+ , 1971 .

[51]  G. Crosby,et al.  Temperature Dependence of Luminescence Intensity of Tb3+ Complexes , 1970 .

[52]  M. Kleinerman,et al.  Exciton‐Migration Processes in Crystalline Lanthanide Chelates. I. Triplet Exciton Migration in Lanthanide Chelates of 1,10‐Phenathroline , 1968 .

[53]  J. Kropp,et al.  Comment on the Fluorescence of Trivalent Europium in D2O—H2O Mixtures , 1966 .

[54]  Maurice W. Windsor,et al.  Luminescence and Energy Transfer in Solutions of Rare‐Earth Complexes. I. Enhancement of Fluorescence by Deuterium Substitution , 1965 .

[55]  J. Kropp,et al.  Enhancement of Fluorescence Yield of Rare‐Earth Ions by Heavy Water , 1963 .

[56]  Nicolaas Bloembergen,et al.  Proton Relaxation Times in Paramagnetic Solutions. Effects of Electron Spin Relaxation , 1961 .

[57]  S. Weissman,et al.  Intramolecular Energy Transfer The Fluorescence of Complexes of Europium , 1942 .

[58]  G. Ulrich,et al.  SYNTHESIS AND LUMINESCENCE OF EU3+ AND TB3+ COMPLEXES WITH NOVEL CALIX4ARENE LIGANDS CARRYING 2,2'-BIPYRIDINE SUBUNITS , 1995 .

[59]  Gabriel González,et al.  Water-exchange, electronic relaxation, and rotational dynamics of the MRI contrast agent [Gd(DTPA-BMA)(H2O)] in aqueous solution: a variable pressure, temperature, and magnetic field oxygen-17 NMR study , 1994 .

[60]  F. S. Richardson,et al.  Circularly polarized luminescence. , 1993, Methods in enzymology.

[61]  L. Helm,et al.  Oxygen-17 NMR study of water exchange on gadolinium polyaminopolyacetates [Gd(DTPA)(H2O)]2- and [Gd(DOTA)(H2O)]- related to NMR imaging , 1993 .

[62]  T. Norman,et al.  Hepato-biliary and renal excretion in mice of charged and neutral gadolinium complexes of cyclic tetra-aza-phosphinic and carboxylic acids. , 1993, Magnetic resonance imaging.

[63]  P. Anelli,et al.  LUMINESCENCE PROPERTIES OF EU3+ COMPLEXES OF HIGHLY POLYDENTATE LIGANDS , 1991 .

[64]  Seymour H. Koenig,et al.  Field-cycling relaxometry of protein solutions and tissue: Implications for MRI , 1990 .

[65]  D. Parker.  Tumour targeting with radiolabelled macrocycle–antibody conjugates , 1990 .

[66]  E Soini,et al.  Time-resolved fluorometer for lanthanide chelates--a new generation of nonisotopic immunoassays. , 1983, Clinical chemistry.

[67]  A. Heller.  FORMATION OF HOT OH BONDS IN THE RADIATIONLESS RELAXATIONS OF EXCITED RARE EARTH IONS IN AQUEOUS SOLUTIONS , 1966 .