论文信息 - Sulfoxide-Directed Iterative Assembly into Oligoarenes

Sulfoxide-Directed Iterative Assembly into Oligoarenes

Abstract A series of oligoarenes have been synthesized via sulfoxide-based iterative dehydrogenative transformations. By utilizing the sulfinyl moieties as on/off-switchable directing groups, overreactions and/or undesired oligomerizations were completely suppressed. Since the dehydrogenative couplings were not hampered by steric hinderance, sterically encumbered oligoarenes were synthesized.

H. Yorimitsu | T. Yanagi | K. Nogi

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