Air stable hybrid organic-inorganic light emitting diodes using ZnO as the cathode

An air stable hybrid organic-inorganic light emitting device is presented. This architecture makes use of metal oxides as charge injecting materials into the light emitting polymer, avoiding the use of air sensitive cathodes commonly employed in organic light emitting diode manufacturing. We report the application of zinc oxide as a cathode in an organic light emitting device. This electroluminescent device shows high brightness levels reaching 6500cd∕m2 at voltages as low as 8V. Compared to a conventional device using low workfunction metal cathodes, our device shows a lower turn-on voltage and it can operate in air.

[1]  H. Morkoç,et al.  A COMPREHENSIVE REVIEW OF ZNO MATERIALS AND DEVICES , 2005 .

[2]  Shizuo Tokito,et al.  Metal oxides as a hole-injecting layer for an organic electroluminescent device , 1996 .

[3]  David P. Norton,et al.  Origin of green luminescence in ZnO thin film grown by molecular-beam epitaxy , 2005 .

[4]  P. Patil Versatility of chemical spray pyrolysis technique , 1999 .

[5]  Jun Endo,et al.  27.5L: Late‐News Paper: Multiphoton Organic EL device having Charge Generation Layer , 2003 .

[6]  Yong Ding,et al.  Semiconducting and Piezoelectric Oxide Nanostructures Induced by Polar Surfaces , 2004 .

[7]  R. Swanepoel,et al.  XRD analysis of ZnO thin films prepared by spray pyrolysis , 1997 .

[8]  X. Fang,et al.  Zinc oxide nanostructures: morphology derivation and evolution. , 2005, The journal of physical chemistry. B.

[9]  Donal D. C. Bradley,et al.  A Multilayered Polymer Light‐Emitting Diode Using a Nanocrystalline Metal‐Oxide Film as a Charge‐Injection Electrode , 2007 .

[10]  N. Greenham,et al.  Barriers to electron extraction in polymer light-emitting diodes , 2001 .

[11]  M. Grätzel,et al.  Sensitized Electroluminescence on Mesoporous Oxide Semiconductor Films , 1997 .

[12]  L. Gauckler,et al.  Thin Film Deposition Using Spray Pyrolysis , 2005 .

[13]  Zhang Zhi-feng,et al.  Organic light-emitting diodes with a nanostructured TiO2 layer at the interface between ITO and NPB layers , 2003 .

[14]  C. D. Kartha,et al.  Effect of fluorine doping on structural, electrical and optical properties of ZnO thin films , 2005 .

[15]  R. Könenkamp,et al.  Ultraviolet electroluminescence from ZnO/polymer heterojunction light-emitting diodes. , 2005, Nano letters.

[16]  Katsuyuki Morii,et al.  Encapsulation-free hybrid organic-inorganic light-emitting diodes , 2006 .