Preliminary investigation on solid solution softening effects on NiAl based alloys induced by minor Ru alloying addition

Abstract The effects of micro-Ru alloying addition on NiAl alloys were investigated by optical microscopy, SEM, X-ray diffraction and powder X-ray diffraction. The mechanical properties were characterised by Vickers microhardness measurement and compression tests at room temperature and various elevated temperatures. Micro-Ru alloying addition does not modify the crystal structure of NiAl alloys. However, local electronic structure may be modified owing to the specific site occupancy preference of Ru, smaller size difference between Ru and Al and different electronic nature of Ru and Ni. This is partially verified by the decrease of the long range order degree accurately measured via powder X-ray diffraction. As a result, a maximum softening effect occurs at 0·5 at.-%Ru addition indicated by Vickers microhardness measurement and compression testing results.

[1]  H. Su,et al.  Enthalpies of formation in the Al–Ni–Ru system by direct reaction synthesis calorimetry , 2005 .

[2]  F. Mücklich,et al.  RuAl and its alloys. Part I. Structure, physical properties, microstructure and processing , 2005 .

[3]  A. Casagrande,et al.  Effect of ternary additions of iron on microstructure and microhardness of the intermetallic NiAl in reactive sintering , 2004 .

[4]  J. Zhou,et al.  Preliminary investigation on the phosphorous-induced softening in polycrystalline NiAl intermetallic compound , 2003 .

[5]  T. Mitchell,et al.  Alloying of MoSi2 for improved mechanical properties , 2001 .

[6]  T. Mitchell,et al.  Solid solution hardening and softening in MoSi2 alloys , 2001 .

[7]  M. Balasubramanian,et al.  Site selectivity and bonding in the β-phase aluminides: Studies of RuAl, PdAl, and Pd and Ru dopants in NiAl , 2000 .

[8]  M. Witcomb,et al.  An investigation of the B2 phase between AlRu and AlNi in the Al–Ni–Ru ternary system , 1998 .

[9]  Y. Murata,et al.  Solid solution softening and hardening in alloyed MoSi2 , 1998 .

[10]  I. Wolff Toward a better understanding of ruthenium aluminide , 1997 .

[11]  I. Wolff Synthesis of RuAl by reactive powder processing , 1996 .

[12]  G. Sauthoff,et al.  Mechanical properties of ru-ni-ai alloys , 1996 .

[13]  D. R. Johnson,et al.  Containerless Automated Processing of High-Purity Intermetallic Compounds and Composites , 1996 .

[14]  H. Inui,et al.  Plastic deformation of MoSi2 single crystals , 1995 .

[15]  R. Noebe,et al.  Physical and mechanical properties of the B2 compound NiAl , 1993 .

[16]  R. Field,et al.  The effect of iron, gallium and molybdenum on the room temperature tensile ductility of NiAl , 1992 .

[17]  Y. Chou,et al.  Alloy softening in Ni3Al polycrystals , 1992 .

[18]  D. West,et al.  The constitution of the Ni-Al-Ru system , 1986 .