A model to assess the rate of evaporation of chemical compounds from surface waters

A model has been developed to assess the rate of evaporation of chemical compounds from surface waters. It is based on the two-boundary-layer model of Lewis and Whitman, on critically evaluated literature data and on specific experiments. The rate of evaporation is assessed as a function of the diffusion coefficient in air and water and of Henry's coefficient in water, being the physico-chemical parameters, and as a function of the wind speed, the water temperature and the water depth, being the environmental parameters.

[1]  P. Liss Processes of gas exchange across an air-water interface☆ , 1973 .

[2]  M. Coantic,et al.  The effect of evaporation and condensation on gas transfer across an air-water-interface , 1981 .

[3]  J. Ledwell Gas exchange across the air-water interface , 1982 .

[4]  W. Shiu,et al.  Determination of air-water Henry's law constants for hydrophobic pollutants , 1979 .

[5]  J. S. Rowlinson,et al.  Molecular Thermodynamics of Fluid-Phase Equilibria , 1969 .

[6]  D. L. Haynes,et al.  Volatilization rates of intermediate and low volatility chemicals from water , 1981 .

[7]  Arvo Lannus,et al.  Gas‐Liquid Reactions , 1970 .

[8]  W. K. Lewis,et al.  Principles of Gas Absorption. , 1924 .

[9]  Edward A. Mason,et al.  Gaseous Diffusion Coefficients , 1972 .

[10]  W. Broecker,et al.  The vertical distribution of radon in the Bomex area , 1971 .

[11]  P. Liss,et al.  Flux of Gases across the Air-Sea Interface , 1974, Nature.

[12]  W. H. Durum,et al.  The aeration capacity of streams , 1967 .

[13]  J. Kanwisher,et al.  Effect of wind on CO2 exchange across the sea surface , 1963 .

[14]  G. Lugg,et al.  Diffusion coefficients of some organic and other vapors in air , 1968 .

[15]  W. Broecker,et al.  Surface radon measurements in the North Pacific Ocean station Papa , 1974 .

[16]  P. Liss The Exchange of Gases Across Lake Surfaces , 1976 .

[17]  W. Broecker,et al.  Radon evasion rates in the Atlantic and Pacific oceans as determined during the Geosecs Program , 1979 .

[18]  R. Reid,et al.  The Properties of Gases and Liquids , 1977 .

[19]  T. Hoover,et al.  Effects of hydration on carbon dioxide exchange across an air‐water interface , 1969 .

[20]  C. Wilke,et al.  Correlation of diffusion coefficients in dilute solutions , 1955 .

[21]  C. Y. Lee,et al.  Estimation of Diffusion Coefficients for Gases and Vapors , 1955 .

[22]  S. Emerson Gas exchange rates in small Canadian Shield lakes1 , 1975 .

[23]  Walter Hayduk,et al.  Prediction of diffusion coefficients for nonelectrolytes in dilute aqueous solutions , 1974 .

[24]  L. Hasse,et al.  Gas exchange across the air-sea interface , 1980 .

[25]  R. Reijnhart,et al.  Evaporation of crude oil at sea , 1982 .