Carrier recombination at single dislocations in GaN measured by cathodoluminescence in a transmission electron microscope

We study radiative and nonradiative recombination at individual dislocations in GaN by cathodoluminescence performed in a transmission electron microscope. The dislocations are produced by indentation of dislocation free single crystals and have a-type Burgers vectors (b=1/3〈1120〉). They are aligned along 〈1120〉 directions in the basal plane. Our direct correlation between structural and optical properties on a microscopic scale yields two main results: (i) 60°-basal plane dislocations show radiative recombination at 2.9 eV; (ii) screw-type basal plane dislocations act as nonradiative recombination centers. We explain the nonradiative recombination by splitting this dislocation into 30° partials that have dangling bonds in the core. The dissociation width of these dislocations is <2 nm.

[1]  Ellen B. Stechel,et al.  Charge accumulation at a threading edge dislocation in gallium nitride , 1999 .

[2]  Lester F. Eastman,et al.  Scattering of electrons at threading dislocations in GaN , 1998 .

[3]  James S. Speck,et al.  Scanning capacitance microscopy imaging of threading dislocations in GaN films grown on (0001) sapphire by metalorganic chemical vapor deposition , 1998 .

[4]  Ferdinand Scholz,et al.  Diffusion length of photoexcited carriers in GaN , 1997 .

[5]  S. Denbaars,et al.  Scanning tunneling microscope-induced luminescence of GaN at threading dislocations , 1999 .

[6]  M. Scheffler,et al.  Proceedings of the 23rd International Conference on THE PHYSICS OF SEMICONDUCTORS , 1996 .

[7]  Ulrike Grossner,et al.  The effect of doping and growth stoichiometry on the core structure of a threading edge dislocation in GaN , 1998 .

[8]  J. Furthmüller,et al.  Theoretical investigation of edge dislocations in AlN , 1998 .

[9]  V. Narayanamurti,et al.  Direct observation of localized high current densities in GaN films , 1999 .

[10]  W. Read LXXXVII. Theory of dislocations in germanium , 1954 .

[11]  Henryk Temkin,et al.  Electron beam induced current measurements of minority carrier diffusion length in gallium nitride , 1996 .

[12]  David P. Bour,et al.  Spatial distribution of the luminescence in GaN thin films , 1996 .

[13]  S. Porowski High pressure growth of GaN — new prospects for blue lasers , 1996 .

[14]  E. C. Carr,et al.  CORRELATION OF CATHODOLUMINESCENCE INHOMOGENEITY WITH MICROSTRUCTURAL DEFECTS IN EPITAXIAL GAN GROWN BY METALORGANIC CHEMICAL-VAPOR DEPOSITION , 1997 .

[15]  J. Weyher,et al.  Study of individual grown-in and indentation-induced dislocations in GaN by defect-selective etching and transmission electron microscopy , 2001 .

[16]  James S. Speck,et al.  The role of threading dislocations in the physical properties of GaN and its alloys , 1999 .

[17]  Xiao Yan Zhu,et al.  Electronic structures of GaN edge dislocations , 2000 .

[18]  J. Werner,et al.  Polycrystalline Semiconductors II , 1991 .

[19]  Lester F. Eastman,et al.  The role of dislocation scattering in n-type GaN films , 1998 .

[20]  Sven Öberg,et al.  DEEP ACCEPTORS TRAPPED AT THREADING-EDGE DISLOCATIONS IN GAN , 1998 .

[21]  J. Zolper,et al.  Nonalloyed Ti/Al Ohmic contacts to n‐type GaN using high‐temperature premetallization anneal , 1996 .

[22]  K. Ebeling,et al.  Microstructure, growth mechanisms and electro-optical properties of heteroepitaxial GaN layers on sapphire (0001) substrates , 1996 .

[23]  P. Fernández,et al.  Influence of deformation on the luminescence of GaN epitaxial films , 1998 .

[24]  O. Ambacher,et al.  Carrier Recombination at Screw Dislocations in n‐Type AlGaN Layers , 1999 .

[25]  P. Petroff,et al.  Nonradiative Recombination at Dislocations in III-V Compound Semiconductors , 1980 .

[26]  Satoshi Kurai,et al.  Direct Evidence that Dislocations are Non-Radiative Recombination Centers in GaN , 1998 .

[27]  Sven Öberg,et al.  Theory of Threading Edge and Screw Dislocations in GaN , 1997 .

[28]  I. S. Smirnova,et al.  Perfect Dislocations in the Wurtzite Lattice , 1968 .

[29]  Peter Goodhew,et al.  Electron Microscopy And Analysis , 1975 .