Kinetic and Thermodynamic Control of Structure Transformations in a Family of Cobalt(II)-Organic Frameworks.

Dynamic metal-organic frameworks (MOFs) that respond to external stimuli have recently attracted great attention. However, the subtle control of dynamic processes as well as the illustration of the underlying mechanism, which is crucial for the targeted construction and modulation purpose, is extremely challenging. Herein, we report the achievement of simultaneous kinetic and thermodynamic modulation of the structure transformation processes of a family of cobalt(II)-organic frameworks, through the rational combination of coligand replacement, solvent molecule substitution, and ligand-based solid solution strategies. On the basis of the systematic investigation of the structural transformation behaviors, the underlying response mechanism and principles for modulation were illustrated. It is expected that this work can provide valuable hints for the study and further development of dynamic materials.

[1]  Chun He,et al.  Flexible, Luminescent Metal-Organic Frameworks Showing Synergistic Solid-Solution Effects on Porosity and Sensitivity. , 2016, Angewandte Chemie.

[2]  P. Cheng,et al.  Coordination-Driven Polymerization of Supramolecular Nanocages. , 2015, Journal of the American Chemical Society.

[3]  P. Kortunov,et al.  New High- and Low-Temperature Phase Changes of ZIF-7: Elucidation and Prediction of the Thermodynamics of Transitions. , 2015, Journal of the American Chemical Society.

[4]  S. Kitagawa,et al.  Control of molecular rotor rotational frequencies in porous coordination polymers using a solid-solution approach. , 2015, Journal of the American Chemical Society.

[5]  Song Gao,et al.  An A-site mixed-ammonium solid solution perovskite series of [(NH2 NH3 )x (CH3 NH3 )1-x ][Mn(HCOO)3 ] (x=1.00-0.67). , 2015, Angewandte Chemie.

[6]  L. Wojtas,et al.  Structural Insight into Guest Binding Sites in a Porous Homochiral Metal-Organic Material. , 2015, Journal of the American Chemical Society.

[7]  Song Gao,et al.  Influence of Guest Exchange on the Magnetization Dynamics of Dilanthanide Single-Molecule-Magnet Nodes within a Metal-Organic Framework. , 2015, Angewandte Chemie.

[8]  Nathaniel L. Rosi,et al.  Orthogonal Ternary Functionalization of a Mesoporous Metal-Organic Framework via Sequential Postsynthetic Ligand Exchange. , 2015, Journal of the American Chemical Society.

[9]  Joanna Aizenberg,et al.  Dynamic polymer systems with self-regulated secretion for the control of surface properties and material healing. , 2015, Nature materials.

[10]  J. Gascón,et al.  Postsynthetic Improvement of the Physical Properties in a Metal-Organic Framework through a Single Crystal to Single Crystal Transmetallation. , 2015, Angewandte Chemie.

[11]  E. Gutiérrez‐Puebla,et al.  Tunable catalytic activity of solid solution metal-organic frameworks in one-pot multicomponent reactions. , 2015, Journal of the American Chemical Society.

[12]  Qiang Zhang,et al.  Sequential linker installation: precise placement of functional groups in multivariate metal-organic frameworks. , 2015, Journal of the American Chemical Society.

[13]  Wei‐Xiong Zhang,et al.  Self-catalysed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviours , 2015, Nature Communications.

[14]  P. K. Bharadwaj,et al.  Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework. , 2015, Chemical communications.

[15]  P. Feng,et al.  Pore space partition by symmetry-matching regulated ligand insertion and dramatic tuning on carbon dioxide uptake. , 2015, Journal of the American Chemical Society.

[16]  Chun He,et al.  Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitive thermoresponsive dielectric materials. , 2015, Angewandte Chemie.

[17]  J. Hupp,et al.  Beyond Post‐Synthesis Modification: Evolution of Metal—Organic Frameworks via Building Block Replacement , 2014 .

[18]  Jing Li,et al.  Luminescent Metal—Organic Frameworks for Chemical Sensing and Explosive Detection , 2014 .

[19]  Teppei Yamada,et al.  Introduction of an ionic liquid into the micropores of a metal-organic framework and its anomalous phase behavior. , 2014, Angewandte Chemie.

[20]  Feng Luo,et al.  Photoswitching CO₂ capture and release in a photochromic diarylethene metal-organic framework. , 2014, Angewandte Chemie.

[21]  Mohamed Eddaoudi,et al.  A supermolecular building approach for the design and construction of metal-organic frameworks. , 2014, Chemical Society reviews.

[22]  Yi‐nan Wu,et al.  Magnetic metal-organic frameworks: γ-Fe2O3@MOFs via confined in situ pyrolysis method for drug delivery. , 2014, Small.

[23]  M. Jansen,et al.  Highly luminescent thin films of the dense framework ∞(3)[EuIm2] with switchable transparency formed by scanning femtosecond-pulse laser deposition. , 2014, Angewandte Chemie.

[24]  A. Cooper,et al.  Molecular dynamics simulations of gas selectivity in amorphous porous molecular solids. , 2013, Journal of the American Chemical Society.

[25]  X. Bu,et al.  A controllable gate effect in cobalt(II) organic frameworks by reversible structure transformations. , 2013, Angewandte Chemie.

[26]  P. Kambhampati,et al.  Chemical and thermodynamic control of the surface of semiconductor nanocrystals for designer white light emitters. , 2013, ACS nano.

[27]  G. Shimizu,et al.  Enhancing proton conduction in a metal-organic framework by isomorphous ligand replacement. , 2013, Journal of the American Chemical Society.

[28]  Cheng Wang,et al.  A chiral porous metal-organic framework for highly sensitive and enantioselective fluorescence sensing of amino alcohols. , 2012, Journal of the American Chemical Society.

[29]  Yong Cui,et al.  Chiral nanoporous metal-metallosalen frameworks for hydrolytic kinetic resolution of epoxides. , 2012, Journal of the American Chemical Society.

[30]  K. Rissanen,et al.  Breathing molecular crystals: halogen- and hydrogen-bonded porous molecular crystals with solvent induced adaptation of the nanosized channels , 2012 .

[31]  Omar K Farha,et al.  Metal-organic framework materials as chemical sensors. , 2012, Chemical reviews.

[32]  Seth M Cohen,et al.  Postsynthetic methods for the functionalization of metal-organic frameworks. , 2012, Chemical reviews.

[33]  M. Eddaoudi,et al.  Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material. , 2012, Journal of the American Chemical Society.

[34]  J. Lang,et al.  Highly efficient separation of a solid mixture of naphthalene and anthracene by a reusable porous metal-organic framework through a single-crystal-to-single-crystal transformation. , 2011, Journal of the American Chemical Society.

[35]  Rui‐Biao Lin,et al.  Pore Surface Tailored SOD‐Type Metal‐Organic Zeolites , 2011, Advanced materials.

[36]  P. Chatterjee,et al.  Single crystal-to-single crystal irreversible transformation from a discrete vanadium(V)-alcoholate to an aldehydic-vanadium(IV) oligomer. , 2010, Journal of the American Chemical Society.

[37]  Keiji Nakagawa,et al.  Solid solutions of soft porous coordination polymers: fine-tuning of gas adsorption properties. , 2010, Angewandte Chemie.

[38]  C. Serre,et al.  Dynamics of benzene rings in MIL-53(Cr) and MIL-47(V) frameworks studied by 2H NMR spectroscopy. , 2010, Angewandte Chemie.

[39]  Zheng Huang,et al.  Ligand exchanges and selective catalytic hydrogenation in molecular single crystals , 2010, Nature.

[40]  Qiang Xu,et al.  Non-, micro-, and mesoporous metal-organic framework isomers: reversible transformation, fluorescence sensing, and large molecule separation. , 2010, Journal of the American Chemical Society.

[41]  Lan-sun Zheng,et al.  Solvent-induced transformation of single crystals of a spin-crossover (SCO) compound to single crystals with two distinct SCO centers. , 2010, Journal of the American Chemical Society.

[42]  A. J. Blake,et al.  Cation-induced kinetic trapping and enhanced hydrogen adsorption in a modulated anionic metal–organic framework , 2009, Nature Chemistry.

[43]  Nathaniel L Rosi,et al.  Cation-triggered drug release from a porous zinc-adeninate metal-organic framework. , 2009, Journal of the American Chemical Society.

[44]  Kunlun Hong,et al.  Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material. , 2008, Journal of the American Chemical Society.

[45]  Miguel A. Garcia-Garibay,et al.  Amphidynamic character of crystalline MOF-5: rotational dynamics of terephthalate phenylenes in a free-volume, sterically unhindered environment. , 2008, Journal of the American Chemical Society.

[46]  Xiao-Ning Cheng,et al.  A Dynamic Porous Magnet Exhibiting Reversible Guest‐Induced Magnetic Behavior Modulation , 2007 .

[47]  Jun Gao,et al.  Linear and star-shaped polynuclear Ru(II) complexes of 2-(2'-pyridyl)benzimidazolyl derivatives: syntheses, photophysical properties and red light-emitting devices. , 2006, Dalton transactions.

[48]  S. Kitagawa,et al.  Dynamic porous properties of coordination polymers inspired by hydrogen bonds. , 2005, Chemical Society reviews.

[49]  Yang Shi-ping.  Nanoscale metal-organic frameworks for biomedical imaging and drug delivery , 2012 .

[50]  P. Allan,et al.  In-situ Single-Crystal Diffraction Studies of the Structural Transition of Metal-Organic Framework Cu-SIP-3 , 2010 .

[51]  Rein V Ulijn,et al.  Enzyme-assisted self-assembly under thermodynamic control. , 2009, Nature nanotechnology.