Vocational colleges actively respond to the national "The Belt and Road" strategy and participate in the practice of international cooperation in running schools. However, the main body of international cooperation in vocational education is schools, which lacks the effective participation of enterprises, resulting in unsatisfactory results. In order to improve the cooperation, this paper takes Chongqing Vocational Institute of Engineering as an example, proposes a new cooperation mode called CEC for International Vocational education, and makes a detailed analysis of this mode. Keywords—"The Belt and Road"; Vocational education; International cooperation; CEC model