Recent advances in reverse osmosis membranes

Abstract A review is presented of the developments of the past several years in the area of reverse osmosis membranes. These developments have occurred along two lines: new membrane materials and new membrane fabrication methods. Among the new materials can be cited aromatic polyamides, polybenzimidazole, polyphenylene oxide, hydrated metal oxides, crosslinked and blended cellulose acetates, crosslinked polyvinylpyrrolidone, crosslinked polyethylenimine, and derivatives of several of these materials. The water and salt permeabilities of many of these materials and of the cellulose acetates are compared. Important developments in the area of fabrication methods include the extension of asymmetric membrane techniques to new materials, supported ultra-thin films, hollow fibers and asymmetric hollow fibers, and dynamically formed membranes. A comparison of these materials and fabrication methods requires some kind of figure of merit and one such parameter is discussed.

[1]  T. Wydeven,et al.  Solute rejection by porous glass membranes. I - Hyperfiltration of sodium chloride and urea feed solutions. , 1971 .

[2]  E. Klein,et al.  The Use of Solubility Parameters for Solvent Selection in Asymmetric Membrane Formation , 1972 .

[3]  G. S. Park,et al.  The diffusion of some organic substances in polystyrene , 1951 .

[4]  Sidney Loeb,et al.  Sea Water Demineralization by Means of an Osmotic Membrane , 1963 .

[5]  H. Lonsdale,et al.  Permeability of cellulose acetate membranes to selected solutes , 1971 .

[6]  O. Kedem,et al.  The mechanism for formation of “skinned” membranes , 1970 .

[7]  James S. Johnson,et al.  Hyperfiltration Studies. IV. Salt Rejection by Dynamically Formed Hydrous Oxide Membranes1 , 1966 .

[8]  P. Parrini,et al.  Reverse osmosis properties of poly(trans-2,5-dimethylpiperazine fumaramide) films , 1972 .

[9]  R. L. Riley,et al.  Transport properties of cellulose acetate osmotic membranes , 1965 .

[10]  Robert M Keller,et al.  Turbulence promoters for hyperfiltration with dynamic membranes. , 1970, Environmental science & technology.

[11]  H. Lonsdale,et al.  Transport in Composite Reverse Osmosis Membranes , 1971 .

[12]  Mark E. Cohen,et al.  Hollow-Fiber Reverse Osmosis Membranes , 1972 .

[13]  James S. Johnson,et al.  Hyperfiltration. XXI. Dynamically formed hydrous Zr(IV) oxide-polyacrylate membranes , 1972 .

[14]  R. Baker,et al.  A rationale for the preparation of Loeb-Sourirajan-type cellulose acetate membranes , 1971 .

[15]  A. Tobolsky,et al.  Synthesis, characterization, and permeation properties of polyether‐based polyurethanes , 1972 .

[16]  F. Grün Measurements of Diffusion in Rubber , 1949 .

[17]  G. S. Park,et al.  The diffusion of some halo-methanes in polystyrene , 1950 .

[18]  D. Lancet,et al.  The Mechanism of Membrane Formation: Membrane Structures and Their Relation to Preparation Conditions , 1972 .

[19]  Charles E. Reid,et al.  Water and ion flow across cellulosic membranes , 1959 .

[20]  J. Ferry,et al.  Ultrafilter Membranes and Ultrafiltration. , 1936 .

[21]  R. McKinney Reverse Osmosis Separations With Aromatic Polyamide Films and Hollow Fibers , 1972 .

[22]  R. L. Riley,et al.  Preparation of ultrathin reverse osmosis membranes and the attainment of theoretical salt rejection , 1967 .

[23]  J. O. Gardner,et al.  Cellulose Acetate Membranes: Electron Microscopy of Structure , 1964, Science.

[24]  K. S. Spiegler,et al.  Transport processes in ionic membranes , 1958 .

[25]  James S. Johnson Polyelectrolytes in Aqueous Solutions—Filtration, Hyperfiltration, and Dynamic Membranes , 1972 .

[26]  R. L. Riley,et al.  Replication electron microscopy of cellulose acetate osmotic membranes , 1966 .

[27]  J. Anderson,et al.  Mathematical analysis of factors influencing the skin thickness of asymmetric reverse osmosis membranes , 1973 .

[28]  R. Bloch,et al.  The mechanism for formation of “skinned” membranes I. Structure and properties of membranes cast from binary solutions , 1970 .

[29]  A. Katchalsky,et al.  Thermodynamic analysis of the permeability of biological membranes to non-electrolytes. , 1958, Biochimica et biophysica acta.

[30]  H. K. Lonsdale,et al.  Phenol transport in cellulose acetate membranes , 1967 .