Petrophysical and geochemical properties of Columbia River flood basalt: Implications for carbon sequestration

This study presents borehole geophysical data and sidewall core chemistry from the Wallula Pilot Sequestration Project in the Columbia River flood basalt. The wireline logging data were reprocessed, core‐calibrated and interpreted in the framework of reservoir and seal characterization for carbon dioxide storage. Particular attention is paid to the capabilities and limitations of borehole spectroscopy for chemical characterization of basalt. Neutron capture spectroscopy logging is shown to provide accurate concentrations for up to 8 major and minor elements but has limited sensitivity to natural alteration in fresh‐water basaltic reservoirs. The Wallula borehole intersected 26 flows from 7 members of the Grande Ronde formation. The logging data demonstrate a cyclic pattern of sequential basalt flows with alternating porous flow tops (potential reservoirs) and massive flow interiors (potential caprock). The log‐derived apparent porosity is extremely high in the flow tops (20–45%), and considerably overestimates effective porosity obtained from hydraulic testing. The flow interiors are characterized by low apparent porosity (0–8%) but appear pervasively fractured in borehole images. Electrical resistivity images show diverse volcanic textures and provide an excellent tool for fracture analysis, but neither fracture density nor log‐derived porosity uniquely correlate with hydraulic properties of the Grande Ronde formation. While porous flow tops in these deep flood basalts may offer reservoirs with high mineralization rates, long leakage migration paths, and thick sections of caprock for CO2 storage, a more extensive multiwell characterization would be necessary to assess lateral variations and establish sequestration capacity in this reservoir.

[1]  M. Celia,et al.  Alteration of Caprock Fracture Geometries During Flow of CO 2 -acidified Brine: Informing Basin-scale Leakage Models From Pore-scale modeling and Core-scale Experiments , 2011 .

[2]  Herbert T. Schaef,et al.  Carbonate mineralization of volcanic province basalts , 2010 .

[3]  Paul E. Olsen,et al.  Potential on-shore and off-shore reservoirs for CO2 sequestration in Central Atlantic magmatic province basalts , 2010, Proceedings of the National Academy of Sciences.

[4]  E. C. Sullivan,et al.  Preliminary Hydrogeologic Characterization Results from the Wallula Basalt Pilot Study , 2009 .

[5]  R. J. Smith,et al.  Natural Analog CCS Site Characterization Soda Springs, Idaho Implications for the Long-term Fate of Carbon Dioxide Stored in Geologic Environments , 2009 .

[6]  Peter B. Kelemen,et al.  Permanent storage of carbon dioxide in geological reservoirs by mineral carbonation , 2009 .

[7]  B. Peter McGrail,et al.  Dissolution of Columbia River Basalt under mildly acidic conditions as a function of temperature: Experimental results relevant to the geological sequestration of carbon dioxide , 2009 .

[8]  A. T. Owen,et al.  Basalt- CO2–H2O interactions and variability in carbonate mineralization rates , 2009 .

[9]  W. Broecker,et al.  Permanent carbon dioxide storage into basalt: the CarbFix Pilot Project, Iceland , 2009 .

[10]  Peter B. Kelemen,et al.  In situ carbonation of peridotite for CO2 storage , 2008, Proceedings of the National Academy of Sciences.

[11]  Taro Takahashi,et al.  Carbon dioxide sequestration in deep-sea basalt , 2008, Proceedings of the National Academy of Sciences.

[12]  Stefan Bachu,et al.  CO2 storage in geological media: Role, means, status and barriers to deployment , 2008 .

[13]  S. Farag,et al.  Petrophysical Characterization of a Complex Volcanic Reservoir, YingCheng Group, Daqing, China1 , 2008 .

[14]  Taro Takahashi,et al.  Experimental evaluation of in situ CO2‐water‐rock reactions during CO2 injection in basaltic rocks: Implications for geological CO2 sequestration , 2007 .

[15]  James J. Dooley,et al.  Potential for carbon dioxide sequestration in flood basalts , 2006 .

[16]  Martin Stute,et al.  Contact zone permeability at intrusion boundaries: new results from hydraulic testing and geophysical logging in the Newark Rift Basin, New York, USA , 2006 .

[17]  L. O. Boldreel Wire-line log-based stratigraphy of flood basalts from the Lopra-1/1A well, Faroe Islands , 2006 .

[18]  H. Petcovic,et al.  Goldschmidt Conference 2005: Field Trip Guide to the Columbia River Basalt Group , 2005 .

[19]  L. François,et al.  Basalt weathering laws and the impact of basalt weathering on the global carbon cycle , 2003 .

[20]  Klaus S. Lackner,et al.  A Guide to CO2 Sequestration , 2003, Science.

[21]  Vernon G. Johnson,et al.  Natural Gas Storage in Basalt Aquifers of the Columbia Basin, Pacific Northwest USA: A Guide to Site Characterization , 2002 .

[22]  P. Hooper Chemical discrimination of Columbia River basalt flows , 2000 .

[23]  S. Reidel Emplacement of Columbia River flood basalt , 1998 .

[24]  Peter R. Hooper,et al.  Volcanism and Tectonism in the Columbia River Flood-Basalt Province , 1990 .

[25]  C. Broglia,et al.  Effect of alteration, formation absorption, and standoff on the response of the thermal neutron porosity log in gabbros and basalts: Examples from Deep Sea Drilling Project‐Ocean Drilling Program Sites , 1990 .

[26]  Roger N. Anderson,et al.  Geochemical well logging in basalts: The Palisades Sill and the oceanic crust of Hole 504B , 1990 .

[27]  P. Pezard Electrical properties of mid-ocean ridge basalt and implications for the structure of the upper oceanic crust in Hole 504B , 1990 .

[28]  D. Moos,et al.  In-Situ Structure and Properties of 110-Ma Crust from Geophysical Logs in DSDP Hole 418A , 1988 .

[29]  Frederick L. Paillet,et al.  Character and distribution of borehole breakouts and their relationship to in situ stresses in Deep Columbia River Basalts , 1987 .

[30]  A. Aydin,et al.  Surface morphology of columnar joints and its significance to mechanics and direction of joint growth , 1987 .

[31]  P. Long,et al.  Structures, textures, and cooling histories of Columbia River basalt flows , 1986 .

[32]  M. Herron Mineralogy from Geochemical Well Logging , 1986 .

[33]  S. P. Luttrell,et al.  Effective porosities of basalt: A technical basis for values and probability distributions used in preliminary performance assessments , 1984 .

[34]  S. Reidel Stratigraphy and petrogenesis of the Grande Ronde Basalt from the deep canyon country of Washington, Oregon, and Idaho , 1983 .

[35]  A. T. Owen,et al.  Basalt Reactivity Variability with Reservoir Depth in Supercritical CO2 and Aqueous Phases , 2011 .

[36]  E. C. Sullivan,et al.  Breakthroughs in seismic and borehole characterization of Basalt sequestration targets , 2011 .

[37]  Frank A. Spane,et al.  The Wallula basalt sequestration pilot project , 2011 .

[38]  Richard E. Ernst,et al.  Revised definition of Large Igneous Provinces (LIPs) , 2008 .

[39]  S. Farag,et al.  Petrophysical Characterization Of A Complex Volcanic Reservoir , 2007 .

[40]  D. Goldberg,et al.  Natural fracturing and petrophysical properties of the Palisades dolerite sill , 2005, Geological Society, London, Special Publications.

[41]  K. Lackner,et al.  Climate change. A guide to CO2 sequestration. , 2003, Science.

[42]  M. Saar,et al.  Permeability‐porosity relationship in vesicular basalts , 1999 .

[43]  Peter R. Hooper,et al.  The Grande Ronde Basalt, Columbia River Basalt Group; Stratigraphic descriptions and correlations in Washington, Oregon, and Idaho , 1989 .

[44]  Donald A. Swanson,et al.  Revisions to the estimates of the areal extent and volume of the Columbia River Basalt Group , 1989 .

[45]  J. Schweitzer,et al.  Elemental concentrations from thermal neutron capture gamma-ray spectra in geological formations , 1989 .

[46]  L. L. Raymer,et al.  An Improved Sonic Transit Time-To-Porosity Transform , 1980 .

[47]  W. Meredith,et al.  Statistics and Data Analysis , 1974 .