Power Modulator for High-Yield Production of Plasma-Activated Water

Water can be activated by applying plasma to water, for instance, by creating plasma inside (bubbles in) the water, or along a water surface. Plasma-activated water (PAW) typically contains hydrogen peroxide, nitrates, nitrites, and peroxynitrite, and typically has a pH ranging from 2 to 4. The components of PAW and the low pH have proven synergistic antimicrobial effects against bacteria, biofilms, yeasts, and other microorganisms. This paper describes a power modulator and a plasma reactor system for high-yield production of PAW at high production rate. A compact and solid-state dual resonant system has been realized and successfully demonstrated for industrial PAW production. The system generates up to 80-kV (theoretical 120 kV is possible) dual-resonant high-voltage pulses with an oscillation frequency up to 2 MHz, pulse repetition rate > 20 kHz, and an average power of 800-W continuous. In addition to the power modulator, the PAW production system consists of a transient arc plasma reactor and a loop system. Depending on the application, the system is able to activate 10–100 L/h. The disinfecting properties of the PAW production system have been verified by experiments on the reduction of Staphylococcus Epidermidis. Directly after its production, the log reduction of S. Epidermidis can be as high as >8 log. During a period of at least 40 min after its production, the PAW has “mild” disinfecting properties, being able to deactivate S. Epidermidis by 3–4.1 log.

[1]  A.C.M. de Queiroz Multiple resonance networks , 2002 .

[2]  Ajm Guus Pemen,et al.  Corona Above Water Reactor for Systematic Study of Aqueous Phenol Degradation , 2006 .

[3]  Young I Cho,et al.  Concentration of hydrogen peroxide generated by gliding arc discharge and inactivation of E. coli in water , 2013 .

[4]  P. Lukeš,et al.  Chemical analysis of reactive species and antimicrobial activity of water treated by nanosecond pulsed DBD air plasma , 2015 .

[5]  A. Mizuno,et al.  Chemistry of the Positive and Negative Electrical Discharges Formed in Liquid Water and Above a Gas–Liquid Surface , 2009 .

[6]  Petr Lukes,et al.  Formation of ROS and RNS in Water Electro-Sprayed through Transient Spark Discharge in Air and their Bactericidal Effects , 2013 .

[7]  Bruce R. Locke,et al.  Review of the methods to form hydrogen peroxide in electrical discharge plasma with liquid water , 2011 .

[8]  Jrr Verlet,et al.  Plasma–liquid interactions: a review and roadmap , 2016 .

[9]  M. Janda,et al.  Transient spark: a dc-driven repetitively pulsed discharge and its control by electric circuit parameters , 2011 .

[10]  D. Graves,et al.  Improving the Efficiency of Organic Fertilizer and Nitrogen Use via Air Plasma and Distributed Renewable Energy , 2015 .

[11]  David B. Graves,et al.  Long-term antibacterial efficacy of air plasma-activated water , 2011 .

[12]  Sarah N. Gucker,et al.  Perspectives on the Interaction of Plasmas With Liquid Water for Water Purification , 2012, IEEE Transactions on Plasma Science.

[13]  J. Brisset,et al.  Combined Effects of Long-Living Chemical Species during Microbial Inactivation Using Atmospheric Plasma-Treated Water , 2010, Applied and Environmental Microbiology.

[14]  P. Bruggeman,et al.  On OH production in water containing atmospheric pressure plasmas , 2010 .

[15]  P. Bruggeman,et al.  Assessment of Potential Applications of Plasma with Liquid Water , 2013 .

[16]  I. Kornev,et al.  Formation of Nitrite- and Nitrate-Ions in Aqueous Solutions Treated with Pulsed Electric Discharges , 2013 .

[17]  Martin Clupek,et al.  Aqueous-phase chemistry and bactericidal effects from an air discharge plasma in contact with water: evidence for the formation of peroxynitrite through a pseudo-second-order post-discharge reaction of H2O2 and HNO2 , 2014 .

[18]  R. Lundin,et al.  A handbook formula for the inductance of a single-layer circular coil , 1985, Proceedings of the IEEE.

[19]  Christophe Leys,et al.  Non-thermal plasmas in and in contact with liquids , 2009 .

[20]  Kevin Davis,et al.  Reactive nitrogen species produced in water by non-equilibrium plasma increase plant growth rate and nutritional yield , 2013 .