The ν1 and ν3 bands of 16O18O16O: Line positions and intensities

Abstract Room temperature absorption spectra of 18 O-enriched ozone have been recorded around 10 μm using a high-resolution Fourier transform spectrometer. The ν 1 and ν 3 bands of 16 O 18 O 16 O have been extensively analyzed, leading to the determination of precise vibrational energies and rotational and coupling constants. The following band centers were derived: ν 1 = 1074.30756 ± 0.00041 cm −1 and ν 3 = 1008.45277 ± 0.00015 cm −1 . The line intensities were calculated transferring the dipole moment function of 16 O 3 to 16 O 18 O 16 O, and finally a complete list of line positions and intensities of the ν 1 and ν 3 bands of 16 O 18 O 16 O has been generated.

[1]  Wm. Bruce Olson,et al.  Tables of N2O absorption lines for the calibration of tunable infrared lasers from 522 cm−1 to 657 cm−1 and from 1115 cm−1 to 1340 cm−1 , 1981 .

[2]  J. Flaud,et al.  Improved ozone line parameters in the 10- and 4.8-microm regions. , 1980, Applied optics.

[3]  F. X. Kneizys,et al.  Coriolis Interaction in the ν1 and ν3 Fundamentals of Ozone , 1966 .

[4]  A. Barbe,et al.  Infrared and microwave high-resolution spectrum of the ν3 band of ozone , 1977 .

[5]  V. Malathy Devi,et al.  Identification of 18O-isotopic lines of ozone in infrared ground-based solar absorption spectra , 1985 .

[6]  Konrad Mauersberger,et al.  Measurement of heavy ozone in the stratosphere , 1981 .

[7]  A Goldman,et al.  AFGL atmospheric absorption line parameters compilation: 1982 edition. , 1981, Applied optics.

[8]  Jack S. Margolis,et al.  The infrared and microwave spectra of ozone for the (0,0,0), (1,0,0), and (0,0,1) states , 1985 .

[9]  S. R. Drayson,et al.  Spectroscopy and transmittances for the LIMS Experiment , 1984 .

[10]  A. Barbe,et al.  High-resolution infrared atmospheric spectra of ozone in the 10-μm region: Analysis of ν1 and ν3 bands-assignment of the (ν1 + ν2) − ν2 band , 1981 .

[11]  A. Barbe,et al.  Intensity of the ν3 band of ozone from a study of its anomalous dispersion at 10 μm , 1981 .

[12]  J. Muenter,et al.  Stark and Zeeman properties of ozone from molecular beam spectroscopy , 1977 .

[13]  J. Shewchun,et al.  High sensitivity point monitoring of ozone, and high resolution spectroscopy of the nu(3) band of ozone using a tunable semiconductor diode laser. , 1979, Applied optics.

[14]  Charles W. Bauschlicher,et al.  Theoretical calculation of ozone vibrational infrared intensities , 1985 .

[15]  J. Bellet,et al.  Rotational spectra of 16O3 and of the five 18O isotopic species , 1977 .

[16]  J. H. Shaw,et al.  The infrared spectrum of ozone , 1968 .

[17]  S. Clough,et al.  Millimeter wave spectrum of ozone , 1971 .