The Different Catalytic Routes for Methane Valorization: An Assessment of Processes for Liquid Fuels

Abstract Scope of Review. This review is written from the point of view of the process design engineer trying to find the best catalytic options for upgrading methane. It is not intended to be a review of catalytic principles. In fact, actual catalysts used are only mentioned in passing. If the reader wishes to explore this aspect further, there are many recent review articles that can be used and these are referred to at an appropriate time and place.

[1]  C. K. Lee,et al.  Predicting fluid‐bed reactor efficiency using adsorbing gas tracers , 1987 .

[2]  N. R. Hunter,et al.  The Direct Conversion of Methane to Methanol (DMTM) , 1992 .

[3]  F. J. Krambeck,et al.  Shaping process makes fuels , 1985 .

[4]  Pio Forzatti,et al.  Higher Alcohol Synthesis , 1991 .

[5]  X. Xiaoding,et al.  Synthesis of higher alcohols from syngas - recently patented catalysts and tentative ideas on the mechanism , 1987 .

[6]  L. J. Christiansen,et al.  Catalyst and reactor requirements for the oxidative coupling of methane , 1992 .

[7]  K. Gubbins Molecular adsorption in micropores , 1990 .

[8]  Rodney J. Dry,et al.  Possibilities for the development of large-capacity methanol synthesis reactors for synfuel production , 1988 .

[9]  J. M. Smith,et al.  Slurry reactor design studies , 1990 .

[10]  H. Kölbel,et al.  The Fischer-Tropsch Synthesis in the Liquid Phase , 1980 .

[11]  Joseph Haggin Methane-to-Gasoline Plant Adds to New Zealand Liquid Fuel Resources , 1987 .

[12]  Y. Shah,et al.  Methanol synthesis via methylformate in a slurry reactor , 1989 .

[13]  J. Fox,et al.  An evaluation of direct methane conversion processes , 1990 .

[14]  S. T. Sie,et al.  Diffusion limitations in fischer‐tropsch catalysts , 1989 .

[15]  Joseph D. Korchnak Advances in Methanol Technology , 1988 .

[16]  Kuo Evaluation of direct methane conversion to higher hydrocarbons and oxygenates: Final report , 1989 .

[17]  G. E. Keller,et al.  Synthesis of ethylene via oxidative coupling of methane: I. Determination of active catalysts , 1982 .

[18]  J. Topp-Jorgensen,et al.  Integrated process offers lower gas-to-gasoline investment , 1986 .

[19]  Y. Shah,et al.  Kinetics of two-step methanol synthesis in the slurry phase , 1988 .

[20]  G. Somorjai,et al.  The conversion of methane to ethylene and ethane with near total selectivity by low temperature (< 610 ° C) oxydehydrogenation over a calcium-nickel-potassium oxide catalyst , 1990 .

[21]  Frederick J. Krambeck,et al.  Chemistry of olefin oligomerization over ZSM-5 catalyst , 1988 .

[22]  R. W. Rousseau,et al.  Methanol synthesis reactions: calculations of equilibrium conversions using equations of state , 1986 .

[23]  J. Sofranko,et al.  The oxidative conversion of methane to higher hydrocarbons over alkali-promoted Mn/SiO2 , 1987 .

[25]  J. Fox Fischer-Tropsch reactor selection , 1990 .

[26]  W. Conner,et al.  The oxyhydrochlorination of methane on fumed silica-based Cu, K, La catalysts. II: Gas phase stoichiometry , 1984 .

[27]  D. Gray,et al.  Assessing the economic impact of indirect liquefaction process improvements: Volume 1, Development of the integrated indirect liquefaction model and baseline case , 1990 .

[28]  K. R. Westerterp,et al.  Synthesis of methanol in a reactor system with interstage product removal , 1989 .

[29]  J. Bart,et al.  Copper-Zinc Oxide-Alumina Methanol Catalysts Revisited , 1987 .

[30]  J. M. Fox,et al.  Remote gas processing and marketing , 1987 .

[31]  S. T. Sie,et al.  The shell middle distillate synthesis process (SMDS) , 1988 .

[32]  W. Conner,et al.  The oxyhydrochlorination of methane on fumed silica - based Cu+1, K, La catalysts: I. Catalyst synthesis , 1984 .