Numerical expressions for viscosity, surface tension and density of biodiesel: analysis and experimental validation

The purpose of this work was to test the accuracy and predictive power of different numerical methods in order to compute reliable values of viscosity, surface tension and density of biodiesel in a wide range of temperature. Available formulae in literature were used to compute the mentioned properties in the temperature ranges in which they were developed. To validate the numerical expressions we have used experimental measurements of viscosity, surface tension and density performed in our laboratory and published in the literature. In this article, the results obtained by the application of different expressions are shown and possible sources of discrepancy between measured and predicted values are mentioned. The method that predicts the best results is identified for each property. In order to achieve a better fitting to the experimental data, corrections in the expression of the temperature-dependent properties were made when they were necessary.

[1]  K. Kobe The properties of gases and liquids , 1959 .

[2]  Mustafa Ertunc Tat,et al.  The specific gravity of biodiesel and its blends with diesel fuel , 2000 .

[3]  Alan Christopher Hansen,et al.  PREDICTING THE PHYSICAL PROPERTIES OF BIODIESEL FOR COMBUSTION MODELING , 2003 .

[4]  Calvin F. Spencer,et al.  Improved equation for prediction of saturated liquid density , 1972 .

[5]  G. Knothe Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters , 2005 .

[6]  Cecil A. W. Allen,et al.  Predicting the surface tension of biodiesel fuels from their fatty acid composition , 1999 .

[7]  Jürgen Krahl,et al.  The Biodiesel Handbook , 2005 .

[8]  C. E. Goering,et al.  Vegetable Oil Atomization in a DI Diesel Engine , 1983 .

[9]  K. Krisnangkura,et al.  An empirical approach in predicting biodiesel viscosity at various temperatures , 2006 .

[10]  S. Kerschbaum,et al.  Measurement of the temperature dependent viscosity of biodiesel fuels , 2004 .

[11]  K. Watts,et al.  The viscosities of three biodiesel fuels at temperatures up to 300 °C , 2006 .

[12]  M. Pegg,et al.  Predicting the viscosity of biodiesel fuels from their fatty acid ester composition , 1999 .

[13]  Mustafa Ertunc Tat,et al.  The kinematic viscosity of biodiesel and its blends with diesel fuel , 1999 .

[14]  C. J. A. Roelands,et al.  Physical properties of fatty acid methyl esters. VI. Viscosity , 1966 .

[15]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[16]  G. Knothe,et al.  Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components , 2005 .