A process for the preparation of a SCR active zeolite catalyst and SCR active zeolite catalyst
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There are provided a method for producing an SCR-active zeolite catalyst and a correspondingly produced zeolite catalyst. For producing an Fe-ion-exchanged zeolite is first subjected in a reducing hydrocarbon atmosphere to a first heat treatment (3) in a range between 300 ° C and 600 ° C, with the oxidation state of the Fe ions decreases and / or the dispersity the Fe ions increases on the zeolite, the reduced zeolite then in an oxidizing atmosphere a second heat treatment (4) is between 300 ° C and 600 ° C is subjected, said hydrocarbon radicals or hydrocarbon radicals oxidatively removed and the zeolite during the first and the second temperature treatment kaziniert to a catalyst mass (2). By this method of contained iron is stabilized in an oxidation state less than +3 and / or creating a permanent increase in dispersity of the Fe ion on the zeolite in the zeolite. In this way, a high SCR activity in a temperature range of below 300 ° C is achieved.
[1] David Olson,et al. Atlas of Zeolite Framework Types , 2007 .
[2] R. T. Yang,et al. Ultra-active Fe/ZSM-5 catalyst for selective catalytic reduction of nitric oxide with ammonia , 2005 .
[3] Raymond E. Kirk,et al. Encyclopedia of chemical technology , 1998 .
[4] D. Koningsberger,et al. Structure/Reactivity correlation in Fe/ZSM5 dor deNOx Applications : In-Situ XAFS Characterization and Catalysis , 2001 .