Synthesis, structure and heterogeneous catalytic activity of a coordination polymer containing tetranuclear Cu(II)-btp units connected by nitrates

A new coordination polymer containing a tetranuclear Cu(II)-btp unit is an effective heterogeneous catalyst for the regioselective ring opening of epoxide by methanol.

[1]  D. M. Hodgson,et al.  Enantioselective desymmetrisation of achiral epoxides , 1996 .

[2]  Katsuyuki Ogura,et al.  Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine , 1994 .

[3]  Y. Aoyama,et al.  Immobilization of Soluble Metal Complexes with a Hydrogen-Bonded Organic Network as a Supporter. A Simple Route to Microporous Solid Lewis Acid Catalysts , 1998 .

[4]  T. Kuroda–Sowa,et al.  Toward the Construction of Functional Solid-State Supramolecular Metal Complexes Containing Copper(I) And Silver(I) , 1998 .

[5]  Jinho Oh,et al.  A homochiral metal–organic porous material for enantioselective separation and catalysis , 2000, Nature.

[6]  Youngmee Kim,et al.  New dirhodium(II,II) carboxylates with 2,6-bis(N′-1,2,4-triazolyl)pyridinato ligand (btp) , 2001 .

[7]  Scott J. Miller,et al.  Bis(oxazoline)copper(II) complexes as chiral catalysts for the enantioselective Diels-Alder reaction , 1993 .

[8]  H Li,et al.  Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. , 2001, Accounts of chemical research.

[9]  M. Zaworotko,et al.  From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids. , 2001, Chemical reviews.

[10]  Miao Du,et al.  First Cu(II) diamondoid net with 2-fold interpenetrating frameworks. The role of anions in the construction of the supramolecular arrays. , 2002, Inorganic chemistry.

[11]  M. Andrus,et al.  Epoxidation of olefins with peracid at low temperature with copper catalysis , 2000 .

[12]  Davidr . Evans,et al.  C2-SYMMETRIC CU(II) COMPLEXES AS CHIRAL LEWIS ACIDS. CATALYTIC ENANTIOSELECTIVE MICHAEL ADDITION OF SILYLKETENE ACETALS TO ALKYLIDENE MALONATES , 1999 .

[13]  N. Iranpoor,et al.  Iron(III) Trifluoroacetate as an Efficient Catalyst for Solvolytic and Nonsolvolytic Nucleophilic Ring Opening of Epoxides , 2000 .

[14]  Louis J. Farrugia,et al.  ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[15]  M. Yamashita,et al.  Framework engineering by anions and porous functionalities of Cu(II)/4,4'-bpy coordination polymers. , 2002, Journal of the American Chemical Society.

[16]  G. Sekar,et al.  Asymmetric Kharasch reaction: catalytic enantioselective allylic oxidation of olefins using chiral pyridine bis(diphenyloxazoline)-copper complexes and tert-butyl perbenzoate , 1998 .