Flow simulation and analysis of high-power flow batteries

Abstract The cost of a flow battery system can be reduced by increasing its power density and thereby reducing its stack area. If per-pass utilizations are held constant, higher battery power densities can only be achieved using higher flow rates. Here, a 3D computational fluid dynamics model of a flow battery flow field and electrode is used to analyze the implications of increasing flow rates to high power density operating conditions. Interdigitated and serpentine designs, and cell sizes ranging from 10 cm 2 to 400 cm 2 , are simulated. The results quantify the dependence of pressure loss on cell size and design, demonstrating that the details of the passages that distribute flow between individual channels and the inlet and outlet have a major impact on pressure losses in larger cells. Additionally, in-cell flow behavior is analyzed as a function of cell size and design. Flow structures are interrogated to show how and where electrode parameters influence pressure drops, and how regions where transport is slow are correlated with the presence of experimentally observed cell degradation.

[1]  Yasushi Katayama,et al.  Investigation on V(IV)/V(V) species in a vanadium redox flow battery , 2004 .

[2]  Sreenivas Jayanti,et al.  A hydrodynamic network model for interdigitated flow fields , 2009 .

[3]  Haisheng Chen,et al.  Progress in electrical energy storage system: A critical review , 2009 .

[4]  Cheng-Hung Huang,et al.  Optimal Gas Channel Shape Design for a Serpentine PEMFC: Theoretical and Experimental Studies , 2009 .

[5]  D. Chin,et al.  A Hydrogen‐Bromine Cell for Energy Storage Applications , 1980 .

[6]  Venkat Srinivasan,et al.  High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage , 2012 .

[7]  Victor E. Brunini,et al.  Semi‐Solid Lithium Rechargeable Flow Battery , 2011 .

[8]  Farrokh Albuyeh,et al.  Grid of the future , 2009, IEEE Power and Energy Magazine.

[9]  K. Wippermann,et al.  Effect of Spiral Flow Field Design on Performance and Durability of HT-PEFCs , 2013 .

[10]  Maria Skyllas-Kazacos,et al.  Characteristics of a new all-vanadium redox flow battery , 1988 .

[11]  M. Fowler,et al.  In-plane and through-plane gas permeability of carbon fiber electrode backing layers , 2006 .

[12]  Chao-Yang Wang,et al.  Computational Fluid Dynamics Modeling of Proton Exchange Membrane Fuel Cells , 2000 .

[13]  W. Jones,et al.  The prediction of laminarization with a two-equation model of turbulence , 1972 .

[14]  B. Launder,et al.  The numerical computation of turbulent flows , 1990 .

[15]  Michael L. Perry,et al.  Redox Flow Batteries: An Engineering Perspective , 2014, Proceedings of the IEEE.

[16]  Robert M. Darling,et al.  Oxygen Transport in Polymer-Electrolyte Fuel Cells with Interdigitated Air Channels in Porous Bipolar Plates , 2011 .

[17]  S. Jayanti,et al.  Hydrodynamic analysis of flow fields for redox flow battery applications , 2014, Journal of Applied Electrochemistry.

[18]  Chao-Yang Wang,et al.  Transport Phenomena in Elevated Temperature PEM Fuel Cells , 2007 .

[19]  E. U. Ubong,et al.  Three-Dimensional Modeling and Experimental Study of a High Temperature PBI-Based PEM Fuel Cell , 2009 .

[20]  D. H. Schwarz,et al.  3D Modeling of Catalyst Layers in PEM Fuel Cells Effects of Transport Limitations , 2007 .

[21]  M. Mench,et al.  Redox flow batteries: a review , 2011 .

[22]  Venkat Srinivasan,et al.  Cyclic Performance Analysis of Hydrogen/Bromine Flow Batteries for Grid‐Scale Energy Storage , 2015 .

[23]  Mike L. Perry,et al.  The Influence of Electrode and Channel Configurations on Flow Battery Performance , 2014 .

[24]  Hung-Yi Li,et al.  Three-Dimensional Analysis of PEMFCs with Different Flow Channel Designs , 2006 .

[25]  Maria Skyllas-Kazacos,et al.  Progress in Flow Battery Research and Development , 2011 .

[26]  T. Shih,et al.  A new k-ϵ eddy viscosity model for high reynolds number turbulent flows , 1995 .

[27]  T. Isono.  Density, viscosity, and electrolytic conductivity of concentrated aqueous electrolyte solutions at several temperatures. Alkaline-earth chlorides, LaCl3, Na2SO4, NaNO3, NaBr, KNO3, KBr, and Cd(NO3)2 , 1984 .

[28]  James J. McGuirk,et al.  2D and 3D Modeling of a PEMFC Cathode with Interdigitated Gas Distributors , 2005 .

[29]  W. Craig Carter,et al.  Modeling the hydrodynamic and electrochemical efficiency of semi-solid flow batteries , 2012 .

[30]  Ned Djilali,et al.  A 3D, Multiphase, Multicomponent Model of the Cathode and Anode of a PEM Fuel Cell , 2003 .

[31]  C. Ponce de León,et al.  Redox flow cells for energy conversion , 2006 .

[32]  T. Ishii,et al.  Viscosities of aqueous hydrochloric acid solutions, and densities and viscosities of aqueous hydroiodic acid solutions , 1981 .

[33]  Werner Lehnert,et al.  3D modeling of a 200 cm2 HT-PEFC short stack , 2012 .

[34]  Venkat Srinivasan,et al.  Optimization and Analysis of High‐Power Hydrogen/Bromine‐Flow Batteries for Grid‐Scale Energy Storage , 2013 .

[35]  Kyle C. Smith,et al.  Maximizing Energetic Efficiency in Flow Batteries Utilizing Non-Newtonian Fluids , 2014 .

[36]  Ryan J. Balliet,et al.  Modeling Water Management in Polymer-Electrolyte Fuel Cells , 2008 .

[37]  B. Dunn,et al.  Electrical Energy Storage for the Grid: A Battery of Choices , 2011, Science.

[38]  Xabier Garikano,et al.  Influence of geometric parameters of the flow fields on the performance of a PEM fuel cell. A review , 2012 .

[39]  Jack S. Brenizer,et al.  Study of water distribution and transport in a polymer electrolyte fuel cell using neutron imaging , 2005 .

[40]  Sivagaminathan Balasubramanian,et al.  Proton Exchange Membrane Fuel Cells , 2012 .