Metal Acetylacetonate Series in Interface Engineering for Full Low‐Temperature‐Processed, High‐Performance, and Stable Planar Perovskite Solar Cells with Conversion Efficiency over 16% on 1 cm2 Scale

A series of metal acetylacetonates produced by a full low-temperature (below 100 °C) process are successfully employed to obtain both "multistable" and high-performance planar-inverted perovskite solar cells. All the three kinds of champion cells in small area exhibit over 18% in conversion-efficiency with negligible hysteresis, along with a conversion efficiency above 16% for planar PSCs in an aperture area of over 1 cm2 .

[1]  Nripan Mathews,et al.  Low-temperature solution-processed wavelength-tunable perovskites for lasing. , 2014, Nature materials.

[2]  Wei Chen,et al.  Low Cost and Solution Processed Interfacial Layer Based on Poly(2-ethyl-2-oxazoline) Nanodots for Inverted Perovskite Solar Cells , 2016 .

[3]  Henry J Snaith,et al.  Metal-halide perovskites for photovoltaic and light-emitting devices. , 2015, Nature nanotechnology.

[4]  C. Brabec,et al.  Overcoming the Interface Losses in Planar Heterojunction Perovskite‐Based Solar Cells , 2016, Advanced materials.

[5]  Jiang Liu,et al.  Highly efficient fullerene/perovskite planar heterojunction solar cells via cathode modification with an amino-functionalized polymer interlayer , 2014 .

[6]  Aron Walsh,et al.  The dynamics of methylammonium ions in hybrid organic–inorganic perovskite solar cells , 2015, Nature Communications.

[7]  Improved Performance and Reliability of p‐i‐n Perovskite Solar Cells via Doped Metal Oxides , 2016, 1610.01776.

[8]  Yongbo Yuan,et al.  Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells , 2015, Nature Communications.

[9]  Padhraic Mulligan,et al.  Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals , 2016, Nature Photonics.

[10]  Kwanghee Lee,et al.  Achieving long-term stable perovskite solar cells via ion neutralization , 2016 .

[11]  Sung Cheol Yoon,et al.  Benefits of very thin PCBM and LiF layers for solution-processed p–i–n perovskite solar cells , 2014 .

[12]  Yang Yang,et al.  Interfacial Degradation of Planar Lead Halide Perovskite Solar Cells. , 2016, ACS nano.

[13]  R. Friend,et al.  Enhanced Performance in Fluorene-Free Organometal Halide Perovskite Light-Emitting Diodes using Tunable, Low Electron Affinity Oxide Electron Injectors , 2015, Advanced materials.

[14]  Philip Schulz,et al.  Interface energetics in organo-metal halide perovskite-based photovoltaic cells , 2014 .

[15]  Yun-Chorng Chang,et al.  Nickel Oxide Electrode Interlayer in CH3NH3PbI3 Perovskite/PCBM Planar‐Heterojunction Hybrid Solar Cells , 2014, Advanced materials.

[16]  W. Choy,et al.  Post‐treatment‐Free Solution‐Processed Non‐stoichiometric NiOx Nanoparticles for Efficient Hole‐Transport Layers of Organic Optoelectronic Devices , 2015, Advanced materials.

[17]  Michele Pavone,et al.  Origin and Electronic Features of Reactive Oxygen Species at Hybrid Zirconia-Acetylacetonate Interfaces. , 2015, ACS applied materials & interfaces.

[18]  Qi Chen,et al.  Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers. , 2016, Nature nanotechnology.

[19]  Alex K.-Y. Jen,et al.  Recent progress and perspective in solution-processed Interfacial materials for efficient and stable polymer and organometal perovskite solar cells , 2015 .

[20]  I. Georgieva,et al.  DFT modeling, UV-Vis and IR spectroscopic study of acetylacetone-modified zirconia sol-gel materials , 2012, Journal of Molecular Modeling.

[21]  Alex K.-Y. Jen,et al.  Polymer Solar Cells That Use Self‐Assembled‐Monolayer‐ Modified ZnO/Metals as Cathodes , 2008 .

[22]  Sang Il Seok,et al.  Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells. , 2014, Nature materials.

[23]  Jinsong Huang,et al.  Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process , 2014 .

[24]  W. Shen,et al.  High-Performance Inverted Perovskite Solar Cells with Mesoporous NiOx Hole Transport Layer by Electrochemical Deposition , 2018, ACS omega.

[25]  Yongfang Li,et al.  High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer , 2014, Scientific Reports.

[26]  J. Matinlinna,et al.  Surface modification of silica-coated zirconia by chemical treatments , 2010 .

[27]  Sergei Tretiak,et al.  High-efficiency solution-processed perovskite solar cells with millimeter-scale grains , 2015, Science.

[28]  Ursula Rothlisberger,et al.  Entropic stabilization of mixed A-cation ABX3 metal halide perovskites for high performance perovskite solar cells , 2016 .

[29]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.

[30]  Bernd Rech,et al.  A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells , 2016, Science.

[31]  H. Snaith Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells , 2013 .

[32]  Ruchuan Liu,et al.  The Impact of Hybrid Compositional Film/Structure on Organic–Inorganic Perovskite Solar Cells , 2018, Nanomaterials.

[33]  Sung Cheol Yoon,et al.  Efficient CH3NH3PbI3 Perovskite Solar Cells Employing Nanostructured p‐Type NiO Electrode Formed by a Pulsed Laser Deposition , 2015, Advanced materials.

[34]  Sang Il Seok,et al.  High-performance photovoltaic perovskite layers fabricated through intramolecular exchange , 2015, Science.

[35]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[36]  C. Brabec,et al.  Improved High-Efficiency Perovskite Planar Heterojunction Solar Cells via Incorporation of a Polyelectrolyte Interlayer , 2014 .

[37]  Henry J. Snaith,et al.  Efficient planar heterojunction perovskite solar cells by vapour deposition , 2013, Nature.

[38]  Yang Yang,et al.  Interface engineering of highly efficient perovskite solar cells , 2014, Science.

[39]  Bo Chen,et al.  Impact of Capacitive Effect and Ion Migration on the Hysteretic Behavior of Perovskite Solar Cells. , 2015, The journal of physical chemistry letters.

[40]  Chunyan Wu,et al.  Hybrid UV-Ozone-Treated rGO-PEDOT:PSS as an Efficient Hole Transport Material in Inverted Planar Perovskite Solar Cells , 2017, Nanoscale Research Letters.

[41]  Yongbo Yuan,et al.  Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells , 2014, Nature Communications.

[42]  P. Odier,et al.  Synthesis and thermal decomposition of a novel zirconium acetato-propionate cluster: [Zr12] , 2011 .

[43]  Yunlong Guo,et al.  Sulfamic Acid-Catalyzed Lead Perovskite Formation for Solar Cell Fabrication on Glass or Plastic Substrates. , 2016, Journal of the American Chemical Society.

[44]  Peng Gao,et al.  A molecularly engineered hole-transporting material for efficient perovskite solar cells , 2016, Nature Energy.

[45]  K. Wong,et al.  Vacuum-assisted thermal annealing of CH3NH3PbI3 for highly stable and efficient perovskite solar cells. , 2015, ACS nano.

[46]  Kam Sing Wong,et al.  Pinhole-Free and Surface-Nanostructured NiOx Film by Room-Temperature Solution Process for High-Performance Flexible Perovskite Solar Cells with Good Stability and Reproducibility. , 2016, ACS nano.

[47]  Qingfeng Dong,et al.  Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers , 2014 .

[48]  Jae Woong Jung,et al.  A Low‐Temperature, Solution‐Processable, Cu‐Doped Nickel Oxide Hole‐Transporting Layer via the Combustion Method for High‐Performance Thin‐Film Perovskite Solar Cells , 2015, Advanced materials.

[49]  Aslihan Babayigit,et al.  Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite , 2015 .

[50]  Tzung-Fang Guo,et al.  CH3NH3PbI3 Perovskite/Fullerene Planar‐Heterojunction Hybrid Solar Cells , 2013, Advanced materials.

[51]  Anders Hagfeldt,et al.  Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5ee03874j Click here for additional data file. , 2016, Energy & environmental science.

[52]  Jenny Nelson,et al.  Reversible Hydration of CH3NH3PbI3 in Films, Single Crystals, and Solar Cells , 2015 .

[53]  W. Jaegermann,et al.  Hybrid Perovskite/Perovskite Heterojunction Solar Cells. , 2016, ACS nano.

[54]  Chun-Guey Wu,et al.  Planar heterojunction perovskite/PC71BM solar cells with enhanced open-circuit voltage via a (2/1)-step spin-coating process , 2014 .

[55]  A. Polman,et al.  Photovoltaic materials: Present efficiencies and future challenges , 2016, Science.

[56]  D. Barreca,et al.  Zirconium Dioxide Thin Films Characterized by XPS , 2000 .

[57]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[58]  C. Brabec,et al.  Interface Engineering of Perovskite Hybrid Solar Cells with Solution-Processed Perylene–Diimide Heterojunctions toward High Performance , 2015 .

[59]  Zhike Liu,et al.  Efficient and stable perovskite solar cells prepared in ambient air irrespective of the humidity , 2016, Nature Communications.

[60]  Namchul Cho,et al.  High‐Performance and Environmentally Stable Planar Heterojunction Perovskite Solar Cells Based on a Solution‐Processed Copper‐Doped Nickel Oxide Hole‐Transporting Layer , 2015, Advanced materials.

[61]  Wei Chen,et al.  Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers , 2015, Science.

[62]  Tae‐Woo Lee,et al.  Planar heterojunction organometal halide perovskite solar cells: roles of interfacial layers , 2016 .

[63]  Henry J. Snaith,et al.  Stability of Metal Halide Perovskite Solar Cells , 2015 .

[64]  S. Meloni,et al.  Ionic polarization-induced current–voltage hysteresis in CH3NH3PbX3 perovskite solar cells , 2016, Nature Communications.

[65]  Yongbo Yuan,et al.  Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability. , 2016, Accounts of chemical research.

[66]  Chang-Lyoul Lee,et al.  Multicolored Organic/Inorganic Hybrid Perovskite Light‐Emitting Diodes , 2015, Advanced materials.

[67]  Chin‐Ti Chen,et al.  Room-Temperature Solution-Processed n-Doped Zirconium Oxide Cathode Buffer Layer for Efficient and Stable Organic and Hybrid Perovskite Solar Cells , 2016 .

[68]  Kai Zhu,et al.  Origin of J-V Hysteresis in Perovskite Solar Cells. , 2016, The journal of physical chemistry letters.

[69]  Aron Walsh,et al.  Ionic transport in hybrid lead iodide perovskite solar cells , 2015, Nature Communications.