Assessment of Anticorrosion Performance of Zinc-Rich Epoxy Coatings Added with Zinc Fibers for Corrosion Protection of Steel

The effect of adding 0.5 wt % zinc fibers on the anticorrosion performance of zinc-rich epoxy (ZRE) coatings with 85, 75, and 65 wt % of zinc dust was investigated. The salt spray testing, scanning electron microscopy, open circuit potential, and electrochemical impedance spectroscopy measurements were used to characterize the corrosion protection performance of coatings. The results indicate that the ZRE coating containing 85 wt % zinc dust showed superior cathodic protection, while the coating with 65 wt % zinc dust provided neither cathodic protection nor good barrier protection. No significant improvement in the anticorrosion performance was observed for both coatings with the addition of 0.5 wt % zinc fibers. In contrast, the ZRE coating containing 75 wt % zinc dust, which provided short-term cathodic protection followed by barrier protection, showed remarkably improved anticorrosion performance with the addition of zinc fibers.

[1]  H. Bi,et al.  Enhanced anticorrosion performance of zinc rich epoxy coatings modified with stainless steel flakes , 2021, Progress in Organic Coatings.

[2]  H. Bi,et al.  Effects of Biochar Nanoparticles on Anticorrosive Performance of Zinc-rich Epoxy Coatings , 2021 .

[3]  Y. Zuo,et al.  Degradation of zinc-rich epoxy coating in 3.5% NaCl solution and evolution of its EIS parameters , 2021, Journal of Coatings Technology and Research.

[4]  Xiao Wang Application of EIS and transmission line model to study the effect of arrangement of graphene on electromagnetic shielding and cathodic protection performance of zinc-rich waterborne epoxy coatings , 2020, International Journal of Electrochemical Science.

[5]  Y. Qiang,et al.  Incorporation of electroconductive carbon fibers to achieve enhanced anti-corrosion performance of zinc rich coatings. , 2020, Journal of colloid and interface science.

[6]  Y. F. Cheng,et al.  Preparation of graphene nanoplate added zinc-rich epoxy coatings for enhanced sacrificial anode-based corrosion protection , 2019, Corrosion Science.

[7]  E. Han,et al.  Corrosion resistance and mechanism of one-component organic Zn15Al-rich coating , 2019, Progress in Organic Coatings.

[8]  L. Zhi,et al.  Zinc-reduced graphene oxide for enhanced corrosion protection of zinc-rich epoxy coatings , 2018, Progress in Organic Coatings.

[9]  B. Shaw,et al.  A Comparison of the Corrosion Response of Zinc-Rich Coatings with and Without Presence of Carbon Nanotubes Under Erosion and Corrosion Conditions , 2018, Corrosion.

[10]  H. Castaneda,et al.  Influence of Zinc Content and Chloride Concentration on the Corrosion Protection Performance of Zinc-Rich Epoxy Coatings Containing Carbon Nanotubes on Carbon Steel in Simulated Concrete Pore Environments , 2016 .

[11]  M. Selvaraj,et al.  Corrosion resistance and improved adhesion properties of propargyl alcohol impregnated mesoporous titanium dioxide built-in epoxy zinc rich primer , 2016 .

[12]  M. Rostami,et al.  An investigation of the electrochemical action of the epoxy zinc-rich coatings containing surface modified aluminum nanoparticle , 2015 .

[13]  F. Sharif,et al.  Evaluating protection performance of zinc rich epoxy paints modified with polyaniline and polyaniline-clay nanocomposite , 2014 .

[14]  Z. Pászti,et al.  Galvanic function of zinc-rich coatings facilitated by percolating structure of the carbon nanotubes. Part II: Protection properties and mechanism of the hybrid coatings , 2014 .

[15]  B. Ramezanzadeh,et al.  Application of the electrochemical noise to investigate the corrosion resistance of an epoxy zinc-rich coating loaded with lamellar aluminum and micaceous iron oxide particles , 2013 .

[16]  M. Shishesaz,et al.  Evaluation of synergistic effect of nanozinc/nanoclay additives on the corrosion performance of zinc-rich polyurethane nanocomposite coatings using electrochemical properties and salt spray testing , 2013 .

[17]  T. H. Yun,et al.  The improvement of anticorrosion properties of zinc-rich organic coating by incorporating surface-modified zinc particle , 2012 .

[18]  G. Guillemot,et al.  The Corrosion Protection Behaviour of Zinc Rich Epoxy Paint in 3% NaCl Solution , 2011 .

[19]  J. Rauch,et al.  Comparison of corrosion behaviour of zinc in NaCl and in NaOH solutions. Part I: Corrosion layer characterization , 2010 .

[20]  C. Alemán,et al.  Partial replacement of metallic zinc dust in heavy duty protective coatings by conducting polymer , 2010 .

[21]  P. Bajaj,et al.  Electrochemical impedance spectroscopy investigations of epoxy zinc rich coatings: Role of Zn content on corrosion protection mechanism , 2010 .

[22]  K. Dam-Johansen,et al.  Anticorrosive coatings: a review , 2009 .

[23]  M. Zheludkevich,et al.  A SVET investigation on the modification of zinc dust reactivity , 2008 .

[24]  Daniel de la Fuente,et al.  Long-term atmospheric corrosion of zinc , 2007 .

[25]  M. Bjordal,et al.  Zinc-rich primers : Test performance and electrochemical properties , 2005 .

[26]  C. Hsu,et al.  Technical Note: Concerning the Conversion of the Constant Phase Element Parameter Y0 into a Capacitance , 2001 .

[27]  A. Kalendová,et al.  Anticorrosion efficiency of zinc-filled epoxy coatings containing conducting polymers and pigments , 2015 .

[28]  T. Spychaj,et al.  Zinc-free varnishes and zinc-rich paints modified with ionic liquids , 2014 .

[29]  A. Miszczyk,et al.  Improvement of electrochemical action of zinc-rich paints by addition of nanoparticulate zinc , 2013 .