Comparative processing-structure-property studies of Al-Cu matrix composites reinforced with TiC particulates

Abstract Effects of TiC content and size on the microstructure, density, hardness and wear resistance of Al–4 wt.% Cu matrix composites were investigated. Al–4 wt.% Cu matrix composites were fabricated using two main processing routes of powder metallurgy (PM) and casting. In the PM process, Al–4 wt.% Cu matrix alloy reinforced with 10 wt.% TiC particulates of two different average sizes (13 μm and 93 μm) were mechanically alloyed and sintered. In the second process, Al–4 wt.% Cu– x TiC ( x  = 5, 10, 15 and 20 vol.%) composites were fabricated using a flux-assisted casting. Both the wear resistance and the hardness of cast composites improved with TiC content. The sintered composite containing smaller TiC particles (0.6–3.5 μm) exhibited higher hardness than that reinforced with coarser TiC (0.8–5.6 μm) particles. However, the detachment of carbide particles from wear surfaces of the composite reinforced with TiC particles (0.6–3.5 μm) results in the deterioration of its wear resistance.

[1]  A. Kennedy,et al.  The thermal stability of TiC particles in an Al7wt.%Si alloy , 2003 .

[2]  B. S. Murty,et al.  Effect of TiB2 particles on sliding wear behaviour of Al-4Cu alloy , 2007 .

[3]  A. R. Daud,et al.  Dry sliding wear behaviour of Al–12Si–4Mg alloy with cerium addition , 2010 .

[4]  T. W. Clyne CHAPTER 30 – METALLIC COMPOSITE MATERIALS , 1996 .

[5]  A. Needleman,et al.  Fundamentals of metal-matrix composites , 1993 .

[6]  D. Dunand,et al.  Strengthening mechanisms in aluminum containing coherent Al3Sc precipitates and incoherent Al2O3 dispersoids , 2007 .

[7]  Taylor Lyman METALS HANDBOOK VOL.8 METALLOGRAPHY, STRUCTURES AND PHASE DIAGRAMS 8th EDITION , 1973 .

[8]  M. G. Bader,et al.  Chapter 16 – Metal-Matrix Composites for Ground Vehicle, Aerospace, and Industrial Applications , 1993 .

[9]  M. Qi,et al.  Dry sliding wear of a Ti50Ni25Cu25 particulate-reinforced aluminum matrix composite , 1998 .

[10]  Y. Run-zhang,et al.  The combustion synthesis process of Al−Ti−C system in an elevated-temperature Al-melt , 2002 .

[11]  A. Kennedy,et al.  The effect of processing on the mechanical properties and interfacial strength of aluminium/TiC MMCs , 2000 .

[12]  Michael B. Bever,et al.  Concise encyclopedia of advanced ceramic materials , 1991 .

[13]  D. Lloyd The solidification microstructure of particulate reinforced aluminium/SiC composites , 1989 .

[14]  K. B. Lee,et al.  Reaction products of Al/TiC composites fabricated by the pressureless infiltration technique , 2005 .

[15]  A. Contreras Wetting of TiC by Al-Cu alloys and interfacial characterization. , 2007, Journal of colloid and interface science.

[16]  R. Pérez,et al.  Processing and Characterization of Al‐Cu and Al‐Mg Base Composites Reinforced with TiC , 2004 .

[17]  A. Kennedy,et al.  Characterising particle–matrix interfacial bonding in particulate Al–TiC MMCs produced by different methods , 2001 .

[18]  M. Fine,et al.  Interfaces in as-extruded XD Al/TiC and Al/TiB_2 metal matrix composites , 1993 .

[19]  Y. Mahajan,et al.  The effect of participate reinforcement on the sliding wear behavior of aluminum matrix composites , 1992 .

[20]  B. Pai,et al.  Production of cast aluminium-graphite particle composites using a pellet method , 1978 .

[21]  M. Vedani,et al.  Influence of interface properties on mechanical behaviour of particle reinforced metal matrix composite , 1994 .

[22]  W. Wong,et al.  Development of Mg/Cu nanocomposites using microwave assisted rapid sintering , 2007 .

[23]  M. Flemings,et al.  Grain refining of Al-4.5Cu alloy by adding an Al-30TiC master alloy , 1998 .

[24]  Hyo Sug Lee,et al.  The fabrication process and mechanical properties of SiCp/Al–Si metal matrix composites for automobile air-conditioner compressor pistons , 2001 .

[25]  Pradeep K. Rohatgi,et al.  Solidification, structures, and properties of cast metal-ceramic particle composites , 1986 .

[26]  R. Asthana Processing Effects on the Engineering Properties of Cast Metal-Matrix Composites , 1998 .

[27]  K. Chawla,et al.  Metal Matrix Composites , 2006 .

[28]  A. Kennedy,et al.  The microstructure and mechanical properties of TiC and TiB2-reinforced cast metal matrix composites , 1999 .

[29]  Jing Liu,et al.  Wear behaviour and microstructural changes of SiCw-Al composite under unlubricated sliding friction , 1995 .

[30]  Andreas Mortensen,et al.  Size dependent strengthening in particle reinforced aluminium , 2002 .

[31]  A. Miodownik,et al.  Microstructural changes in a mechanically alloyed Al-6.2Zn-2.5Mg-1.7Cu alloy (7010) with and without particulate SiC reinforcement , 1996 .

[32]  A. Kennedy,et al.  The incorporation of ceramic particles in molten aluminium and the relationship to contact angle data , 1999 .

[33]  F. Weng,et al.  In situ reacted titanium nitride-reinforced aluminum alloy composite , 2002 .

[34]  A. Ramesh,et al.  Effect of heat treatment on mechanical properties of particulate reinforced Al6061 composites , 2000 .

[35]  H. Henein,et al.  ZrC particle reinforced Al–4 wt.% Cu alloy composites fabricated by mechanical alloying and vacuum hot pressing: Microstructural evaluation and mechanical properties , 2010 .

[36]  A. Kennedy,et al.  Reaction in Al–TiC metal matrix composites , 2001 .

[37]  Carlos Angeles-Chavez,et al.  Structural, morphological and interfacial characterization of Al–Mg/TiC composites , 2007 .

[38]  Mihir K. Chakraborty,et al.  Wear behaviour of cast and mushy state rolled Al-4.5Cu alloy and in-situ Al4.5Cu-5TiB2 composite , 2008 .

[39]  G. Sundararajan,et al.  The sliding wear behaviour of AlSiC particulate composites—I. Macrobehaviour , 1996 .

[40]  C. Suryanarayana,et al.  Mechanical alloying and milling , 2004 .

[41]  A. Contreras,et al.  Corrosion behaviour of aluminium metal matrix composites reinforced with TiC processed by pressureless melt infiltration , 2006 .

[42]  X. Tong Fabrication of in situ TiC reinforced aluminum matrix composites Part I: Microstructural characterization , 1998 .

[43]  G. Kaptay Interfacial criterion of spontaneous and forced engulfment of reinforcing particles by an advancing solid/liquid interface , 2001 .

[44]  A. Lekatou,et al.  Microstructural Observations in a Cast Al-Si-Cu/TiC Composite , 2010 .

[45]  B. Hwang,et al.  A microstructural study of the wear behaviour of SiCp/Al composites , 1994 .

[46]  E. Feest Interfacial phenomena in metal-matrix composites , 1994 .

[47]  I. Gotman,et al.  Fabrication of Al matrix in situ composites via self-propagating synthesis , 1994 .

[48]  E. Lavernia,et al.  The rapid solidification processing of materials: science, principles, technology, advances, and applications , 2010 .

[49]  H. E. Boyer,et al.  Metallography, structures, and phase diagrams , 1973 .

[50]  D. Lloyd Particle reinforced aluminium and magnesium matrix composites , 1994 .