Mica Structure and Fibrous Growth of Illite

The relative growth rates of the three joint chains of silica tetrahedra and metal octahedra in the [100], [1̅10] and [1̅1̅0] directions within the mica layer (referring to the 1M unit-cell) seem to control the morphology of mica crystallites. Laths and fibers are the products of relatively fast growth along the [100] direction compared to growth along the [1̅10] and [1̅1̅0] directions. The (010) growth front in 1M micas with trans-octahedral vacancies exposes a pair of reactive OH ions that can form organic or inorganic complexes and ‘poison’ the growth on the (010) face.Authigenic illite fibers in two sandstones with contrasting lithologies are found to have grown on mica or kaolinite cores. Illite fibers appear in single sets or in multiple sets, 120° apart. This texture seems to be related to the stacking sequence of the layers in mica or kaolinite in the core of these fibers.

[1]  A. Bauer,et al.  Experimental constraints on illite crystal morphology , 2000, Clay Minerals.

[2]  D. Beaufort,et al.  Illitization of Diagenetic Kaolinite-to-dickite Conversion Series: Late-stage Diagenesis of the Lower Permian Rotliegend Sandstone Reservoir, Offshore of the Netherlands , 1996 .

[3]  J. Small Experimental Determination of the Rates of Precipitation of Authigenic Illite and Kaolinite in the Presence of Aqueous Oxalate and Comparison to the K/Ar Ages of Authigenic Illite in Reservoir Sandstones , 1993 .

[4]  J. Small,et al.  Experimental Simulation of Clay Precipitation Within Reservoir Sandstones 2: Mechanism of Illite Formation and Controls on Morphology , 1992 .

[5]  N. Güven,et al.  Effects of Octahedral Mg2+ and Fe3+ Substitutions on Hydrothermal Illitization Reactions , 1991 .

[6]  D. Champion,et al.  The I/S-to-illite reaction in the late stage diagenesis , 1991 .

[7]  D. K. Davies,et al.  Nature of Authigenic Illites in Sandstone Reservoirs , 1980 .

[8]  Michael D. Wilson,et al.  Authigenic Clays in Sandstones: Recognition and Influence on Reservoir Properties and Paleoenvironmental Analysis , 1977 .

[9]  D. Triplehorn Occurrence of Pure, Well-Crystallized 1m Illite in Cambro-Ordovician Sandstone from Rhourde El Baguel Field, Algeria , 1967 .

[10]  J. Karger‐Kocsis,et al.  Structure and morphology , 1995 .

[11]  H. Heasler,et al.  Organic-Inorganic Interactions and Sandstone Diagenesis , 1989 .

[12]  J. Goldstein Principles of Thin Film X-Ray Microanalysis , 1979 .

[13]  Wallace Brady Howe,et al.  The stratigraphic succession in Missouri , 1961 .