Changes in surface layer of silicon wafers from diamond scratching

Abstract This study investigates diamond scratching at a high speed comparable to that in a grinding process on an ultraprecision grinder. Diamond tips are prepared for the study. The scratched silicon wafer is observed for changes in the surface layer with transmission electron microscopy. The observation discovers that an amorphous layer is formed on top of the pristine Si-I phase before the onset of chip formation. This discovery is different from the previous findings in which a damaged silicon layer is identified underneath the amorphous layer. Furthermore, no high pressure phase is found before the onset of chip formation.

[1]  C. del Cañizo,et al.  Crystalline silicon solar module technology: Towards the 1 € per watt‐peak goal , 2009 .

[2]  James Williams,et al.  High pressure crystalline phase formation during nanoindentation: Amorphous versus crystalline silicon , 2006 .

[3]  Spandan Maiti,et al.  A New Analytical Model for Estimation of Scratch‐Induced Damage in Brittle Solids , 2007 .

[4]  S. Lee Analysis of ductile mode and brittle transition of AFM nanomachining of silicon , 2012 .

[5]  Fengzhou Fang,et al.  Nanometric cutting of single crystal silicon surfaces modified by ion implantation , 2011 .

[6]  G. Pharr,et al.  An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments , 1992 .

[7]  H. Gatzen,et al.  Investigations on the friction force anisotropy of the silicon lattice , 2003 .

[8]  G. Pharr,et al.  A different type of indentation size effect , 2008 .

[9]  Shreyes N. Melkote,et al.  Effects of carbide and nitride inclusions on diamond scribing of multicrystalline silicon for solar cells , 2013 .

[10]  Shreyes N. Melkote,et al.  Study of Ductile-to-Brittle Transition in Single Grit Diamond Scribing of Silicon: Application to Wire Sawing of Silicon Wafers , 2012 .

[11]  Liangchi Zhang,et al.  Subsurface nanocracking in monocrystalline Si (0 0 1) induced by nanoscratching , 2014 .

[12]  Han Huang,et al.  Grinding of silicon wafers using an ultrafine diamond wheel of a hybrid bond material , 2011 .

[13]  Dongming Guo,et al.  A model for nanogrinding based on direct evidence of ground chips of silicon wafers , 2013 .

[14]  F. Ebrahimi,et al.  Fracture anisotropy in silicon single crystal , 1999 .

[15]  Shreyes N. Melkote,et al.  Role of surfaces and interfaces in solar cell manufacturing , 2014 .