EVOLUTION OF THE STRATOSPHERIC TEMPERATURE AND CHEMICAL COMPOSITION OVER ONE TITANIAN YEAR

Since the Voyager 1 (V1) flyby in 1980, Titan's exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titanian year or 29.5 Earth years had elapsed in 2010 May). In this study, we search for temporal variations affecting Titan's atmospheric thermal and chemical structure within that year. We process Cassini/CIRS data taken during the Titan flybys from 2006–2013 and find a rather uneventful equatorial evolution. Conversely, at northern latitudes, we found enhanced abundances around the period of the northern spring equinox in mid-2009, which subsequently decreased (from 2010 to 2012), returning to values similar to those found in the V1 epoch, one Titanian year before. In the southern latitudes, since 2012, we see a trend for an increase of several trace gases (C4H2, C3H4, and HCN), indicative of a seasonal atmospheric reversal setting in. When we compare the CIRS 2010 and the 1980 V1/IRIS spectra (reanalyzed here), we find limited inter-annual variations. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50°N to 50°S, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by general circulation and photochemical models. Exceptions concern the most complex hydrocarbons (C4H2 and C3H4). We also consider data from ground-based and Earth-orbiting observatories (such as from the Infrared Space Observatory, revisited here) and discuss possible atmospheric composition trends during a Titanian year.

[1]  A. Coustenis,et al.  DETECTION OF PROPENE IN TITAN'S STRATOSPHERE , 2013, 1309.4489.

[2]  A. Coustenis,et al.  FIRST OBSERVATION IN THE SOUTH OF TITAN'S FAR-INFRARED 220 cm−1 CLOUD , 2012 .

[3]  Athena Coustenis,et al.  THERMAL AND CHEMICAL STRUCTURE VARIATIONS IN TITAN'S STRATOSPHERE DURING THE CASSINI MISSION , 2012 .

[4]  A. Coustenis,et al.  Active upper-atmosphere chemistry and dynamics from polar circulation reversal on Titan , 2012, Nature.

[5]  E. Lellouch,et al.  Water vapor in Titan's stratosphere from Cassini CIRS far-infrared spectra , 2012 .

[6]  G. Rottman,et al.  Solar Ultraviolet Variability Over Time Periods of Aeronomic Interest , 2012 .

[7]  B. Charnay,et al.  Titan global climate model: A new 3-dimensional version of the IPSL Titan GCM , 2012 .

[8]  P. Hartogh,et al.  First results of Herschel-SPIRE observations of Titan , 2011 .

[9]  V. M. Devi,et al.  The 2009 edition of the GEISA spectroscopic database , 2011 .

[10]  Jonathan C. Balloch,et al.  The evolution of Titan's detached haze layer near equinox in 2009 , 2011 .

[11]  P. Gierasch,et al.  Temporal Variations of Titan's Middle-Atmospheric Temperatures from 2004 to 2009 Observed by Cassini/CIRS , 2011 .

[12]  Conor A. Nixon,et al.  Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm−1 spectral range , 2010 .

[13]  N. Teanby,et al.  SEASONAL CHANGES IN TITAN'S POLAR TRACE GAS ABUNDANCE OBSERVED BY CASSINI , 2010 .

[14]  D. Buhl,et al.  High spectral resolution infrared studies of Titan: Winds, temperature, and composition , 2010 .

[15]  A. Coustenis,et al.  Titan trace gaseous composition from CIRS at the end of the Cassini–Huygens prime mission , 2010 .

[16]  Conor A. Nixon,et al.  Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission I. Hydrocarbons, nitriles and CO2 vertical mixing ratio profiles , 2010 .

[17]  J. Flaud,et al.  Titan’s prolific propane: The Cassini CIRS perspective , 2009, 0909.1794.

[18]  N. Teanby,et al.  Dynamical implications of seasonal and spatial variations in Titan's stratospheric composition , 2009, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[19]  A. Coustenis,et al.  Detection of C2HD and the D/H ratio on Titan , 2008 .

[20]  F. Hourdin,et al.  Diagnostics of Titan’s stratospheric dynamics using Cassini/CIRS data and the 2-dimensional IPSL circulation model , 2008 .

[21]  A. Coustenis,et al.  Isotopic Ratios in Titan’s Atmosphere from Cassini CIRS Limb Sounding: HC3N in the North , 2008 .

[22]  A. Coustenis,et al.  The 12C/13C isotopic ratio in Titan hydrocarbons from Cassini/CIRS infrared spectra , 2008 .

[23]  P. Gierasch,et al.  Titan's middle-atmospheric temperatures and dynamics observed by the Cassini Composite Infrared Spectrometer , 2008 .

[24]  A. Coustenis,et al.  Global and temporal variations in hydrocarbons and nitriles in Titan's stratosphere for northern winter observed by Cassini/CIRS , 2008 .

[25]  G. Orton,et al.  The composition of Titan's stratosphere from Cassini/CIRS mid-infrared spectra , 2007 .

[26]  Athena Coustenis,et al.  Vertical abundance profiles of hydrocarbons in Titan's atmosphere at 15° S and 80° N retrieved from Cassini/CIRS spectra , 2007 .

[27]  R. Schieder,et al.  High‐resolution infrared spectroscopy of ethane in Titan's stratosphere in the Huygens epoch , 2006 .

[28]  P. J. Schinder,et al.  Titan's Atmospheric Temperatures, Winds, and Composition , 2005, Science.

[29]  T. Geballe,et al.  Clouds, haze, and CH4, CH3D, HCN, and C2H2 in the atmosphere of Titan probed via 3 μm spectroscopy , 2005 .

[30]  F. Hourdin,et al.  Titan's stratospheric composition driven by condensation and dynamics , 2004 .

[31]  M. Gurwell Submillimeter Observations of Titan: Global Measures of Stratospheric Temperature, CO, HCN, HC3N, and the Isotopic Ratios 12C/13C and 14N/15N , 2004, astro-ph/0407169.

[32]  H. Roe,et al.  Propane on Titan , 2003, astro-ph/0309653.

[33]  T. Encrenaz,et al.  Titan’s atmosphere from ISO mid-infrared spectroscopy , 2003 .

[34]  A. Marten,et al.  New Millimeter Heterodyne Observations of Titan: Vertical Distributions of Nitriles HCN, HC3N, CH3CN, and the Isotopic Ratio 15N/14N in Its Atmosphere , 2002 .

[35]  T. Hewagama,et al.  Improved Determination of Ethane (C2H6) Abundance in Titan's Stratosphere , 2002 .

[36]  J. Waite,et al.  Atmospheres in the solar system : comparative aeronomy , 2002 .

[37]  D. Buhl,et al.  Ethane abundance on Titan , 1997 .

[38]  T. Owen,et al.  Millimeter and Submillimeter Heterodyne Observations of Titan: Retrieval of the Vertical Profile of HCN and the12C/13C Ratio , 1997 .

[39]  A. Coustenis,et al.  Titan's Atmosphere from Voyager Infrared Observations: IV. Latitudinal Variations of Temperature and Composition , 1995 .

[40]  A. Coustenis,et al.  Titan's atmospheric structure from Voyager 2 infrared spectra , 1993 .

[41]  A. Coustenis,et al.  Titan's atmosphere from voyager infrared observations: III. Vertical distributions of hydrocarbons and nitriles near Titan's North Pole , 1991 .

[42]  B. Bézard,et al.  Stratospheric profile of HCN on Titan from millimeter observations , 1989 .

[43]  F. Gillett Further observations of the 8--13 micron spectrum of Titan , 1975 .