Fiber Optical Sensor System Using A Tunable Laser For Detection Of PAHs On Particles And In Water

Laser-induced fluorescence is introduced as an analytical technique for the detection of particle-bond PAHs, which can be found as a result of most combustion processes. A quartz fiber is used to couple the light of a frequency-doubled excimer-pumped dye-laser into the sensor head. The fluorescence light is detected using collecting optics, a set of interference filters and a photomultiplier. PAHs in different forms (crystalline, in solution, as homogeneous particles and coated on NaCl particles) were investigated. Fluorescence spectra and time-resolved signals, which exhibit characteristic decay times, are presented.

[1]  R. Niessner Coated particles: Preliminary results of laboratory studies on interaction of ammonia with coated sulfurid acid droplets or hydrogensulfate particles , 1984 .

[2]  N. Omenetto LASER-FLUORESCENCE TECHNIQUES , 1984 .

[3]  R. Niessner,et al.  The photoelectric aerosol sensor as a fast-responding and sensitive detection system for cigarette smoke analysis , 1989 .

[4]  R. K. Force,et al.  Determination of polynuclear aromatic hydrocarbons in vapor phases by laser-induced molecular fluorescence , 1983 .

[5]  R. K. Force,et al.  Determination of the fluorescence properties of polynuclear aromatic hydrocarbons in the vapor phase and adsorbed on solid supports by laser-induced molecular fluorescence , 1985 .

[6]  Benjamin Y. H. Liu,et al.  Generation of monodisperse aerosol standards , 1973 .

[7]  R. E. Setchell,et al.  Fluorescence Interferences in Raman Scattering from Combustion Products , 1977 .

[8]  L. Vaeck,et al.  Characteristic parameters of particle size distributions of primary organic constituents of ambient aerosols. , 1985 .

[9]  R. Niessner,et al.  Laboratory experiments on the determination of polycyclic aromatic hydrocarbon coverage of submicrometer particles by laser-induced aerosol photoemission , 1989 .

[10]  R. Niessner The chemical response of the photo-electric aerosol sensor (PAS) to different aerosol systems , 1986 .

[11]  L. Szentpály,et al.  Carcinogenesis by polycyclic aromatic hydrocarbons: a multilinear regression on new type PMO indexes , 1984 .

[12]  R. Niessner In-situ-Photoemission an PAH-beschichteten Aerosolen , 1987 .

[13]  G. Grimmer,et al.  PAH—Their contribution to the carcinogenicity of various emissions† , 1985 .

[14]  H. Niki,et al.  Fluorescence spectroscopic study of reactions between gaseous ozone and surface-adsorbed polycyclic aromatic hydrocarbons. , 1984, Environmental science & technology.

[15]  D. P. Aeschliman,et al.  Fluorescence Limitations to Combustion Studies Using Raman Spectroscopy , 1975 .