Microstructure and hardened state properties on pozzolan-containing concrete

Abstract The homogeneous state of the concrete in the fresh state has consequences on their properties in the hardened state. The use of pozzolanic concrete must be carefully evaluated, because the physical and chemical differences of each pozzolan have consequences on concrete hardened state properties. In this work, two physical and chemically different pozzolans were used to evaluate the effect on concrete microstructure and its basic hardened state properties. Scanning electron microscopy (SEM) was used and can be an effective tool in the analysis of the microstructure allowing a better understanding of the properties of concrete in hardened state. It allows showing that the differences in the two pozzolans (metakaolin and diatomite) promote different microstructures as well as different final properties of pozzolanic concrete. Moreover, it was also shown that the use of a water reducing agent, to adjust workability instead of water, promotes an improvement in both the microstructure and the hardened state features such as porosity and mechanical strength.

[1]  Gemma Rodríguez de Sensale,et al.  Strength development of concrete with rice-husk ash , 2006 .

[2]  C. Poon,et al.  Compressive strength, chloride diffusivity and pore structure of high performance metakaolin and silica fume concrete , 2006 .

[3]  A. Silva,et al.  POZZOLANIC ACTIVITY OF METAKAOLINS BY THE FRENCH STANDARD OF THE MODIFIED CHAPELLE TEST: A DIRECT METHODOLOGY , 2015 .

[4]  W. Tsai,et al.  Characterization and adsorption properties of diatomaceous earth modified by hydrofluoric acid etching. , 2006, Journal of colloid and interface science.

[5]  E. Samson,et al.  Durability of concrete — Degradation phenomena involving detrimental chemical reactions , 2008 .

[6]  M. Stamatakis,et al.  The influence of biogenic micro-silica-rich rocks on the properties of blended cements , 2003 .

[7]  G. Prokopski,et al.  Interfacial transition zone in cementitious materials , 2000 .

[8]  G. Kakali,et al.  Properties and hydration of blended cements with calcareous diatomite , 2006 .

[9]  P. Hewlett,et al.  Lea's chemistry of cement and concrete , 2001 .

[10]  Alice Ergün Effects of the usage of diatomite and waste marble powder as partial replacement of cement on the mechanical properties of concrete , 2011 .

[11]  J. G. Cabrera,et al.  Pore size distribution and degree of hydration of metakaolin–cement pastes , 2000 .

[12]  M. Stroeven,et al.  Reconstructions by SPACE of the Interfacial Transition Zone , 2001 .

[13]  Bülent Yılmaz,et al.  The use of raw and calcined diatomite in cement production , 2008 .

[14]  A. Yilmaz,et al.  Use of diatomite as partial replacement for Portland cement in cement mortars , 2009 .

[15]  A. Aydın,et al.  Influence of volcanic originated natural materials as additives on the setting time and some mechanical properties of concrete , 2007 .

[16]  S. Wild,et al.  Relative strength, pozzolanic activity and cement hydration in superplasticised metakaolin concrete , 1996 .

[17]  J. A. Rossignolo Interfacial interactions in concretes with silica fume and SBR latex , 2009 .

[18]  V. Ferreira,et al.  Effect of metakaolin dispersion on the fresh and hardened state properties of concrete , 2012 .

[19]  S. Diamond The patch microstructure in concrete : The effect of superplasticizer , 2006 .

[20]  Sidney Diamond,et al.  The ITZ in concrete – a different view based on image analysis and SEM observations , 2001 .

[21]  R. Talero,et al.  Calorimetry of Portland cement with silica fume, diatomite and quartz additions , 2009 .

[22]  J. Pera,et al.  Hydration reaction and hardening of calcined clays and related minerals V. Extension of the research and general conclusions , 1985 .

[23]  V. Ferreira,et al.  Correlation between mortar and concrete behavior using rheological analysis , 2015 .

[24]  U. Helbig,et al.  Primary particle size and agglomerate size effects of amorphous silica in ultra-high performance concrete , 2013 .