Bis(trimethylammonium) tetrachloridodiphenylstannate(IV)

The title compound, [(CH3)3NH]2[Sn(C6H5)2Cl4], consists of [(CH3)3NH]+ cations and [SnPh2Cl4]2− anions in which the Sn atom, located on a centre of inversion, is bonded to four Cl atoms and two phenyl rings, giving an octahedral geometry with the phenyl rings in trans positions. In the crystal, the cations and the anions are connected by N—H⋯Cl hydrogen bonds and C—H⋯Cl interactions.

[1]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[2]  G. Yeap,et al.  Syntheses of stannate(IV) complexes: [LH+]2[SnCl6]2−, [LH+]2[Me4Sn2 Cl6]2− and [LH+]2[Ph2SnCl4]2− (LH+ = protonated benzalideneaniline Schiff bases). Crystal structure of the tetrachlorodiphenylstannate(IV) salt [L′H+]2[Ph2SnCl4]2− {L′ = N-(4-hydroxybenzalidene)-4-methoxyaniline}, derived from pheny , 1992 .

[3]  R. Blessing,et al.  An empirical correction for absorption anisotropy. , 1995, Acta crystallographica. Section A, Foundations of crystallography.

[4]  C. J. Evans,et al.  Organotin compounds in modern technology , 1985 .

[5]  K. Pannell,et al.  Di(p-tert-butylphenyl)-N,N-di-(iso-butyl) carbamoylmethylphosphine oxide and its organotin and uranyl adducts: structural and spectroscopic characterization , 2005 .

[6]  Louis J. Farrugia,et al.  WinGX suite for small-molecule single-crystal crystallography , 1999 .

[7]  Yan Xu,et al.  Reactions of 8-methoxyquinoline [C10H9ON] and diorganotin dichlorides. Crystal structures of [C10H9ON·H]2Ph2SnCl4 and [C10H9ON·H·NOH9C10]Ph2SnCl3 , 1998 .

[8]  Maria Cristina Burla,et al.  SIR97: a new tool for crystal structure determination and refinement , 1999 .

[9]  L. Kollár,et al.  Preparation and structural characterization of ionic five-coordinate palladium(II) and platinum(II) complexes of the ligand Tris[2-(diphenylphosphino)ethyl]phosphine. Insertion of SnCl2 into M-Cl bonds (M = Pd, Pt) and hydroformylation activity of the Pt-SnCl3 systems , 2002 .

[10]  Louis J. Farrugia,et al.  ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[11]  J. Casas,et al.  The crystal structure of the salts [Hthiamine][SnMe2(H2O)Cl3]Cl and [Hthiamine][SnPh2Cl4]H2O: competition between water and chloride for coordination to diorganotin dihalides , 1996 .

[12]  Z. Berente,et al.  Crystal structure and reactivity of mononuclear cationic palladium(II) and platinum(II) triphos complexes with phenyltin(IV) anions. The formation of polynuclear platinum-triphos ionic and covalent complexes , 2001 .