Electrooxidative phosphorylation of coumarins by bimetallic catalytic systems Ni(II)/Mn(II) or Co(II)/Mn(II)

GRAPHICAL ABSTRACT ABSTRACT The phosphorylation of coumarins (coumarin, 6-methylcoumarin, 7-methylcoumarin) by catalytic oxidation of a mixture of coumarins and diethyl phosphite (1:1) in electrochemical mild conditions (room temperature and normal pressure) using bimetallic catalyst systems, MnCl2bpy/Ni(BF4)2bpy or MnCl2bpy/CoCl2bpy(bpy-2,2′-bipyridine) was realized.

[1]  M. Khrizanforov,et al.  One-stage synthesis of FcP(O)(OC2H5)2 from ferrocene and α-hydroxyethylphosphonate , 2016 .

[2]  M. Knupfer,et al.  Crystal Growth, Dynamic and Charge Transfer Properties of New Coronene Charge Transfer Complexes , 2016 .

[3]  O. Sinyashin,et al.  Phosphorylation of C–H bonds of aromatic compounds using metals and metal complexes , 2015 .

[4]  M. Khrizanforov,et al.  New method of metal-induced oxidative phosphorylation of benzene , 2015, Russian Chemical Bulletin.

[5]  O. Sinyashin,et al.  Pyridine-directed palladium-catalyzed electrochemical phosphonation of C(sp2)–H bond , 2015 .

[6]  O. Sinyashin,et al.  Novel paste electrodes based on phosphonium salt room temperature ionic liquids for studying the redox properties of insoluble compounds , 2015, Journal of Solid State Electrochemistry.

[7]  O. Sinyashin,et al.  Electrochemical properties of diphosphonate-bridged palladacycles and their reactivity in arene phosphonation , 2015, Journal of Solid State Electrochemistry.

[8]  O. Sinyashin,et al.  Electrochemical C-H phosphorylation of 2-phenylpyridine in the presence of palladium salts , 2014, Russian Chemical Bulletin.

[9]  S. Latypov,et al.  Novel electrochemical pathway to fluoroalkyl phosphines and phosphine oxides , 2013 .

[10]  Meeting abstracts , 2003 .

[11]  M. Różalski,et al.  Cytotoxic effects, alkylating properties and molecular modelling of coumarin derivatives and their phosphonic analogues. , 2003, European journal of medicinal chemistry.

[12]  M. Kadirov,et al.  Novel approach to metal-induced oxidative phosphorylation of aromatic compounds , 2017 .