Chemistry of Synthetic Models Relevant to the Active Sites of Molybdenum and Tungsten Containing Enzymes

Recent advance of bioinspired coordination chemistry of molybdenum and tungsten ions has been reviewed. New synthetic methods to modeling uncommon core structures, sulfido and oxo-sulfido metal centers, involved in molybdenum and tungsten enzyme active sites have been discussed. Reactivity in proton-coupled electron transfer of the model compounds also is included.

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