Reactivity of silyl-substituted heterobimetallic iron–platinum hydride complexes: Part III. Alkyne insertions into the platinum–hydride bond and competition between μ-vinylidene and dimetallacyclopentenone formation

[1]  A. Orpen,et al.  The synthesis of [FeRu(CO)2(μ-CO)2(η-C5H5)(η-C5Me5)] and convenient entries to its organometallic chemistry , 2005 .

[2]  M. Knorr,et al.  Reactivity of silyl-substituted heterobimetallic iron–platinum hydride complexes towards unsaturated molecules: Part II. Insertion of trifluoropropyne and hexafluorobutyne into the platinum–hydride bond , 2005 .

[3]  C. Incarvito,et al.  Electronic and Steric Effects in the Insertion of Alkynes into an Iridium(III) Hydride , 2005 .

[4]  C. Cazin,et al.  Alkyne insertion reactions of [RuH(κ2-S2CNEt2)(CO)(PPh3)2]: synthesis of alkenyl, alkynyl and enynyl complexes , 2000 .

[5]  H. Matsuzaka Synthesis, structure, and reactivities of the Ru–Co heterobimetallic complex. Molecular structures of Cp*Ru(CO)2(μ2-CO)Co(CO)3, Cp*Ru(μ2-CO)2(μ2-dppm)Co(CO)2, Cp*Ru(CNBut)(CO)(μ2-CO)Co(CO)3, and Cp*(CO)Ru{η2:η4–μ2–C(Tol)CHC(Tol)CH}Co(CO)2 (Cp*=η5-C5Me5, dppm=Ph2PCH2PPh2, Tol=C6H4Me-4) , 2000 .

[6]  M. Knorr,et al.  Reactivity of Silyl-Substituted Heterobimetallic Iron–Platinum Hydride Complexes towards Unsaturated Molecules, I Alkyne Insertions into the Platinum-Hydride Bond, Phosphane-Induced σ-Alkenyl–μ-Vinylidene Rearrangements and Formation of μ-Isonitrile Complexes , 2000 .

[7]  Green,et al.  Rhodium-Promoted Linear Tetramerization and Cyclization of 3,3-Dimethylbut-l-yne. , 1999, Angewandte Chemie.

[8]  P. Fanwick,et al.  Reactions of Alkynes and Olefins with Tantalum Hydrides Containing Aryloxide Ancillary Ligation: Relevance to Catalytic Hydrogenation† , 1999 .

[9]  M. Cowie,et al.  Mixed-Metal Hydrocarbyl Complexes Involving the Rh/Mo and Rh/W Metal Combinations , 1999 .

[10]  K. G. Caulton,et al.  Hydride Is Not a Spectator Ligand in the Formation of Hydrido Vinylidene from Terminal Alkyne and Ruthenium and Osmium Hydrides: Mechanistic Differences , 1998 .

[11]  D. Steinborn,et al.  Platin(II)-Komplexe mit schwefelfunktionalisierten Alkenylliganden , 1998 .

[12]  J. Takats,et al.  SYNTHESIS AND REACTIVITY OF FE(CO)4(ETA 2-RC?CR') (R, R' = CF3, H, ME) COMPOUNDS: HUBEL'S WORK REVISITED AND BEYOND , 1997 .

[13]  D. J. Crowther,et al.  Synthesis, Structure, and Reactivity of a Novel Hafnium Carboranyl Hydride Complex , 1997 .

[14]  C. Casey,et al.  Reaction of Cp*(CO)2ReRe(CO)2Cp* with Alkynes Produces Dimetallacyclopentenones Cp*(CO)2Re(μ-η1,η3-CRCR‘CO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes , 1997 .

[15]  A. Pombeiro,et al.  Formation of vinyl and dithioformate metallacycles by insertion of an ester-functionalized alkyne or carbon disulfide into an FeH bond: crystal structure ofcis-[Fe(CHCHCOOMe)(Ph2PCH2CH2PPh2)2][BF4] , 1996 .

[16]  B. Grant,et al.  REACTIONS OF TERMINAL ALKYNES WITH GROUP 6-GROUP 10 HETEROBIMETALLICS , 1996 .

[17]  M. Knorr,et al.  Reactivity of Silylated Dinuclear Iron−Platinum Acyl Complexes: Formation of μ-Vinylidene Complexes and Crystal Structures of the Acyl Complex [(OC)3{(MeO)3Si}Fe(μ-dppm)Pt{C(O)Me}(t-BuNC)] and the μ-Vinylidene Complex [(OC)3Fe{μ-CC(H)Ph}(μ-dppm)Pt(PPh3)] , 1996 .

[18]  S. García-Yuste,et al.  STUDIES ON THE INSERTION REACTIONS OF ACTIVATED ALKYNES INTO NB-H BONDS INHYDRIDE-NIOBOCENE COMPLEXES. X-RAY CRYSTAL STRUCTURES OF NB(ETA 5-C5H4SIME3 )2(H)ETA 2-RO2C(H)=C(H)CO2R (R=ME OR TBU) , 1996 .

[19]  S. Lo,et al.  Reactions of molybdenum-cobalt complex with phenylacetylene: X-ray crystal structure of [MoCo(CO)4{CPhCHCHCPh}(η5-C5H5)] , 1995 .

[20]  B. Santarsiero,et al.  Condensation of Os(CO)4(.eta.2-HCCH) with CpRh(CO)(PR3). Unexpected phosphine dependence in the formation of dimetallacycles: reverse regiochemistry and a zwitterionic compound , 1994 .

[21]  M. U. Pilotti,et al.  Synthesis and crystal structures of the complexes [RhPt(µ-H)(µ-CO)(PEt3)2(PPh3)(η5-C2B9H11)] and [RhPt{σ-C(C6H4Me-4)C(C6H4Me-4)H}(CO)(PEt3)(PPh3)(η5-C2B9H11)] , 1990 .

[22]  M. Knorr,et al.  Complexes with an η2‐μ2‐SiO Bridge. Structure of the Bimetallic Complex , 1989 .

[23]  B. Shaw,et al.  Organo–platinum–iron complexes containing one bridging Ph2PCH2PPh2 ligand. Crystal structures of [(OC)3Fe(µ-dppm)(µ-CO)Pt(PPh3)], [(OC)2Fe(µ-dppm){µ-C(O)C2H2}Pt(PPh3)], and [(OC)3Fe(µ-dppm)(µ-CMeCH2)Pt(PPh3)][BF4] , 1988 .

[24]  H. Werner,et al.  Konkurrierende bildung von heterometall-zweikern-komplexen mit μ-CCHPh und μ-ηPsu1,η3-CHCPhCO-brückenliganden bei der reaktion von C5H5Rh(PhCCH)PPri3 MIT Fe2(CO)9 , 1986 .

[25]  J. Amaudrut,et al.  Insertion of activated acetylenes into the metal-hydride bond of [(η5-C5H5)2M(CO)H] (M = Nb, Ta) , 1985 .

[26]  R. Mercier,et al.  Chimie organométallique du niobium VIII. Etude détaillée de la réaction d'acétyléniques perfluorés avec (η5C5H5)2NbH3: Mise en evídence de la coupure de liaison C-F, de la formation de liaison Nb-F et de la reduction du niobium. Structure cristalline d'un dérivé niobiacyclopentadiène , 1981 .

[27]  C. S. Wong,et al.  Chemistry of metal hydrides. Part XX. The nature of the insertion rearrangement of acetylenes with platinum(II) hydrides , 1977 .