Determination of atmospheric aerosol size distribution functions from screen diffusion battery data: Mathematical aspects

Abstract This paper considers the mathematical aspects of the reconstruction of size distribution functions of fine atmospheric aerosol from screen-type diffusion battery (SDB) measurements. It is shown that the problem of reconstruction may be successfully solved using Tikhonov's regularization method of the second order. A series of experimental data is considered, and the spectra obtained are classified. The bimodal size distribution is proved to exist in the highly dispersed fraction of atmospheric aerosol. The reliability of the solutions is analysed; it is found that, for the existing characteristics of the SDB, it is impossible to determine more than two modes. Recommendations on the planning of SDB experiments are given.

[1]  John H. Seinfeld,et al.  A New Algorithm for Inversion of Aerosol Size Distribution Data , 1981 .

[2]  S. Twomey The application of numerical filtering to the solution of integral equations encountered in indirect sensing measurements , 1965 .

[3]  Yung-sung Cheng,et al.  Analysis of Screen Diffusion Battery Data , 1984 .

[4]  Benjamin Y. H. Liu,et al.  Data Inversion by Simplex Minimization for the Electrical Aerosol Analyzer , 1982 .

[5]  Yung-sung Cheng,et al.  Theory and Calibration of a Screen-Type Diffusion Battery , 1980 .

[6]  S. Twomey Comparison of constrained linear inversion and an iterative nonlinear algorithm applied to the indirect estimation of particle size distributions , 1975 .

[7]  R. Bechmann,et al.  Numerical data and functional relationships in science and technology , 1969 .

[8]  S. Twomey,et al.  On the Numerical Solution of Fredholm Integral Equations of the First Kind by the Inversion of the Linear System Produced by Quadrature , 1963, JACM.

[9]  Nan M. Laird,et al.  Em algorithm reconstruction of particle size distributions from diffusion battery data , 1985 .

[10]  P. Mcmurry New particle formation in the presence of an aerosol: Rates, time scales, and sub-0.01 μm size distributions , 1983 .

[11]  Yung-sung Cheng,et al.  Theory of a screen-type diffusion battery , 1980 .

[12]  David L. Phillips,et al.  A Technique for the Numerical Solution of Certain Integral Equations of the First Kind , 1962, JACM.

[13]  D. Schryer Heterogeneous atmospheric chemistry , 1982 .

[14]  S. Friedlander,et al.  Aerosol formation in reacting gases: Relation of surface area to rate of gas-to-particle conversion , 1978 .

[15]  Douglas W. Cooper,et al.  Data inversion using nonlinear programming with physical constraints: Aerosol size distribution measurement by impactors , 1976 .

[16]  N. Shokhirev,et al.  Electron-ion pair distance distribution functions reconstructed from radiation-chemical and photochemical experiments , 1986 .