Chemisorption on metals: a personal review

Abstract This review is an unashamedly personal account, in outline, of a thirty year period in surface science which has seen a dramatic transformation in the understanding of solid surfaces and the process of chemisorption.

[1]  U. Landman,et al.  Direct Transform-Deconvolution Method for Surface-Structure Determination , 1974 .

[2]  D. King,et al.  Ambiguities in adsorbate site assignment from vibrational frequencies. A TLEED structural study of (2 X 1)COPd(110) , 1993 .

[3]  D. King,et al.  Spatial intensity distributions from electron impact scattering modes: W{100}(1 × 1)H , 1983 .

[4]  G. Mahan,et al.  Collective vibrational modes of adsorbed CO , 1978 .

[5]  D. King,et al.  Orbitals and bands at metal surfaces: photoemission from the {110} surface of tungsten , 1981, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[6]  D. King.  Phase and Bonding Transitions in Chemisorbed Layers Studied by Vibrational Frequency Shifts , 1983 .

[7]  D. King,et al.  Coupling of Surface Electronic States through the W {001} Phase Transition , 1980 .

[8]  D. King,et al.  A study on the holographic transfrom for electron diffraction from surfaces , 1991 .

[9]  D. King,et al.  Displacive surface phases formed by hydrogen chemisorption on W{001} , 1980 .

[10]  Michael Wolfe,et al.  J+ = J , 1994, ACM SIGPLAN Notices.

[11]  D. A. King,et al.  The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis , 1981 .

[12]  J. Yates,et al.  Isotopic Mixing in CO Chemisorbed on Tungsten. A Kinetic Study , 1965 .

[13]  G. Ehrlich.  MODERN METHODS IN SURFACE KINETICS. FLASH DESORPTION, FIELD EMISSION MICROSCOPY, AND ULTRAHIGH VACUUM TECHNIQUES , 1963 .

[14]  D. King,et al.  Surface extended X-ray absorption fine structure: critical appraisal of a structural tool for adsorbates , 1986, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

[15]  M. A. Chesters.  Infrared spectroscopy of molecules on metal single-crystal surfaces , 1986 .

[16]  D. King,et al.  Surface states on W (001) (1 × 1) and ( square root 2 × square root 2)R 45° phases: angle-resolved photoemission , 1981 .

[17]  Somorjai,et al.  Molecule-induced displacive reconstruction in a substrate surface: Ethylidyne adsorbed on Rh(111) studied by low-energy-electron diffraction. , 1991, Physical review letters.

[18]  J. K. Roberts.  Some problems in adsorption , 1939 .

[19]  King,et al.  Multiple-scattering effects in electron holographic images. , 1992, Physical review. B, Condensed matter.

[20]  C. A. Becker,et al.  Direct inelastic and trapping-desorption scattering of N2 from polycrystalline W; Elementary steps in the chemisorption of nitrogen , 1980 .

[21]  D. King,et al.  Pulsed laser surface heating : nanosecond time-scale temperature measurement , 1991 .

[22]  D. King,et al.  Adsorption microcalorimetry and sticking probabilities on metal single crystal surfaces , 1993 .

[23]  D. King,et al.  Direct measurement of potassium-promoted change in heat of adsorption of CO on Ni{100} , 1992, Nature.

[24]  D. King,et al.  Chemisorption of carbon monoxide on tungsten , 1972, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[25]  David A. King,et al.  Adsorbate diffusion on single crystal surfaces: I.The influence of lateral interactions , 1978 .

[26]  D. King,et al.  Space-group determination of the low-temperature W)001) (. sqrt. 2 x. sqrt. 2) R45/sup 0/ surface structure by low-energy-electron diffraction , 1977 .

[27]  D. King,et al.  Infrared spectra for co isotopes chemisorbed on Pt “111”: Evidence for strong absorbate coupling interactions , 1977 .

[28]  D. King,et al.  An ultrahigh vacuum single crystal adsorption microcalorimeter , 1991 .

[29]  D. King,et al.  Chemisorption of carbon monoxide on tungsten. Part 2.—Lateral interaction model for desorption kinetics , 1973 .

[30]  King,et al.  Dominance of short-range-order effects in low-energy electron-diffraction intensity spectra. , 1992, Physical review. B, Condensed matter.

[31]  D. King,et al.  Characterization and Transferability of Surface States on W{110} , 1979 .

[32]  Bradley,et al.  Nonlinear island growth dynamics in adsorbate-induced restructuring of quasihexagonal reconstructed Pt{100} by CO. , 1993, Physical review letters.

[33]  D. King,et al.  A LEED STRUCTURAL STUDY OF THE CO INDUCED RECONSTRUCTION OF PD(110) - EVIDENCE FOR A MISSING ROW STRUCTURE , 1991 .

[34]  D. King,et al.  Rate expressions for adsorption and desorption kinetics with precursor states and lateral interactions , 1981 .

[35]  D. King.  Clean and Adsorbate-Induced Surface Phase Transitions on W{100} , 1983 .

[36]  D. King,et al.  Chemisorption of carbon monoxide on platinum {111}: Reflection-absorption infrared spectroscopy , 1976 .

[37]  P. Hollins.  The influence of surface defects on the infrared spectra of adsorbed species , 1992 .

[38]  D. King,et al.  Oxygen adsorption, reconstruction, and thin oxide film formation on clean metal surfaces - Ni, Fe, W and Mo , 1970 .

[39]  D. King,et al.  Reaction mechanism in chemisorption kinetics: nitrogen on the {100} plane of tungsten , 1974, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[40]  D. King,et al.  Orientation of chemisorbed species from electron impact and dipole selection rules: The formate ion on Pt{110} , 1983 .

[41]  D. King,et al.  A direct inversion method for surface structure determination from LEED intensities , 1992, Nature.

[42]  R. Gomer,et al.  Field Emission and Field Ionization , 1961 .

[43]  D. King,et al.  Trapping, sticking and reactive scattering in chemisorption: Nitrogen isotopes on W{100} , 1983 .

[44]  D. King,et al.  Orientation of chemisorbed species from orthogonal-plane arups: Tilted CO on Pt{110} and upright CO on Pt{111}. , 1982 .

[45]  L. Germer,et al.  ADSORPTION ON SINGLE-CRYSTAL PLANES OF TUNGSTEN. I. NITROGEN. , 1971 .

[46]  D. King.  Nitrogen adsorption on nickel and palladium films , 1968 .

[47]  D. King,et al.  Molecular adsorbate-induced surface reconstruction: CO/Pd{110} , 1990 .

[48]  C. Rettner,et al.  Effect of collision energy and incidence angle on the precursor‐mediated dissociative chemisorption of N2 on W(100) , 1988 .

[49]  D. King,et al.  The influence of soft mode adsorbate vibrations on NEXAFS analyses: NO on Pd{110} , 1991 .

[50]  John B. Pendry,et al.  Low-Energy Electron Diffraction , 1990 .

[51]  D. King,et al.  Oxygen diffusion on tungsten single crystal surfaces: Secondary electron emission studies , 1980 .

[52]  R. Gomer,et al.  Does co dissociate on the (100) plane of tungsten , 1974 .

[53]  D. King,et al.  Multiple scattering effects in the fourier transform deconvolution procedure for leed analysis , 1979 .

[54]  C. Duke.  Hot Atoms and Cold Facts: Mysteries and Opportunties in Vibration-Assisted Surface Chemistry , 1983 .

[55]  Clarke,et al.  Dynamics of dissociative chemisorption: Cl2/Si(111)-(2 x 1). , 1993, Physical review letters.

[56]  D. King.  The influence of weakly bound intermediate states on thermal desorption kinetics , 1977 .

[57]  D. King.  Kinetics of adsorption, desorption, and migration at singlecrystal metal surfaces , 1978 .

[58]  D. King,et al.  Holographic images of iodine atoms on a silver surface from electron emission patterns , 1991, Nature.

[59]  D. King,et al.  Molecular Beam Investigation of Adsorption Kinetics on Bulk Metal Targets: Nitrogen on Tungsten , 1972 .

[60]  Norman,et al.  Determination of an adlayer bonding transition by surface extended x-ray-absorption fine-structure spectroscopy: Cesium adsorbed on Ag{111} , 1988, Physical review letters.

[61]  D. King,et al.  Single crystal adsorption microcalorimetry , 1991 .

[62]  M. A. Chesters,et al.  Infrared spectrum and surface potential of carbon monoxide chemisorbed on a copper (100) single-crystal surface , 1970 .

[63]  D. King,et al.  Adsorbate diffusion on single crystal surfaces II. Extension to next nearest neighbour interactions , 1978 .

[64]  F. Propst,et al.  Detection of the Vibrational States of Gases Adsorbed on Tungsten by Low-Energy Electron Scattering , 1967 .

[65]  D. King,et al.  CHEMISORPTION OF CARBON MONOXIDE ON TUNGSTEN: CORRELATION OF REFLECTION-- ABSORPTION INFRARED SPECTRA WITH CO BINDING STATE POPULATION. , 1972 .

[66]  D. King,et al.  Isotope Effect in Electron Stimulated Desorption: Oxygen Chemisorbed on Tungsten , 1970 .

[67]  D. King,et al.  Crystallographic anisotropy in chemisorption: Nitrogen on tungsten single crystal planes , 1975 .

[68]  U. Landman,et al.  Controlled Deposition, Soft Landing, and Glass Formation in Nanocluster-Surface Collisions , 1993, Science.