A precise goniometer/tensiometer using a low cost single-board computer

Measuring the surface tension and the Young contact angle of a droplet is extremely important for many industrial applications. Here, considering the booming interest for small and cheap but precise experimental instruments, we have constructed a low-cost contact angle goniometer/tensiometer, based on a single-board computer (Raspberry Pi). The device runs an axisymmetric drop shape analysis (ADSA) algorithm written in Python. The code, here named DropToolKit, was developed in-house. We initially present the mathematical framework of our algorithm and then we validate our software tool against other well-established ADSA packages, including the commercial rame-hart DROPimage Advanced as well as the DropAnalysis plugin in ImageJ. After successfully testing for various combinations of liquids and solid surfaces, we concluded that our prototype device would be highly beneficial for industrial applications as well as for scientific research in wetting phenomena compared to the commercial solutions.

[1]  Julio Soria,et al.  Application of a single-board computer as a low-cost pulse generator , 2015, 1504.07024.

[2]  Xi Zhang,et al.  Superhydrophobic surfaces: from structural control to functional application , 2008 .

[3]  D. Fuerstenau,et al.  Characterization of Coal Oxidation and Coal Wetting Behavior by Film Flotation , 1992 .

[4]  M. Unser,et al.  ow-bond axisymmetric drop shape analysis for surface tension and contact ngle measurements of sessile drops , 2010 .

[5]  Serrita A. McAuley,et al.  Silicon micromachining using a high-density plasma source , 2001 .

[6]  Ali Kalantarian,et al.  Accuracy of surface tension measurement from drop shapes: the role of image analysis. , 2013, Advances in Colloid and Interface Science.

[7]  W. Barthlott,et al.  Purity of the sacred lotus, or escape from contamination in biological surfaces , 1997, Planta.

[8]  J. Florentin,et al.  Handbook of Mathematical Functions. , 1966 .

[9]  G. Whitesides,et al.  Diagnostics for the developing world: microfluidic paper-based analytical devices. , 2010, Analytical chemistry.

[10]  Dongqing Li,et al.  Automation of axisymmetric drop shape analysis for measurements of interfacial tensions and contact angles , 1990 .

[11]  G. Smith,et al.  Numerical Solution of Partial Differential Equations: Finite Difference Methods , 1978 .

[12]  M. J. D. Powell,et al.  An efficient method for finding the minimum of a function of several variables without calculating derivatives , 1964, Comput. J..

[13]  Kenneth Levenberg A METHOD FOR THE SOLUTION OF CERTAIN NON – LINEAR PROBLEMS IN LEAST SQUARES , 1944 .

[14]  Jorge J. Moré,et al.  User Guide for Minpack-1 , 1980 .

[15]  Song,et al.  Determination of Interfacial Tension from the Profile of a Pendant Drop Using Computer-Aided Image Processing , 1996, Journal of colloid and interface science.

[16]  E. Kissa,et al.  Wetting and Wicking , 1996 .

[17]  A Wilhelm Neumann,et al.  Determination of surface tension and contact angle from the shapes of axisymmetric fluid interfaces without use of apex coordinates. , 1983, Langmuir : the ACS journal of surfaces and colloids.

[18]  Jaebum Choo,et al.  A portable surface-enhanced Raman scattering sensor integrated with a lab-on-a-chip for field analysis. , 2008, Lab on a chip.

[19]  Jorge J. Moré,et al.  The Levenberg-Marquardt algo-rithm: Implementation and theory , 1977 .

[20]  Kyle E Mathewson,et al.  Transitioning EEG experiments away from the laboratory using a Raspberry Pi 2 , 2017, Journal of Neuroscience Methods.

[21]  Nathan J. Emery,et al.  Gathering lots of data on a small budget , 2016, Science.

[22]  Howard A. Stone,et al.  ENGINEERING FLOWS IN SMALL DEVICES , 2004 .

[23]  Adrian Daerr,et al.  Pendent_Drop: An ImageJ Plugin to Measure the Surface Tension from an Image of a Pendent Drop , 2016 .

[24]  H. Girault,et al.  DROP IMAGE PROCESSING FOR SURFACE AND INTERFACIAL TENSION MEASUREMENTS , 1982 .