论文信息 - STEREOSPECIFIC PROPENE POLYMERISATION CATALYSIS USING AN ORGANOMETALLIC MODIFIED MESOPOROUS SILICATE

STEREOSPECIFIC PROPENE POLYMERISATION CATALYSIS USING AN ORGANOMETALLIC MODIFIED MESOPOROUS SILICATE

The mesoporous silicate, MCM-41 is modified by grafting the chiral alkene polymerisation catalyst rac-ethenebis(indenyl)zirconium dichloride onto the surfaces of the mesopore and used to produce highly isotactic polypropene with a unique spherulite morphology.

D. O′Hare | J. Tudor

[1] Ji Man Kim,et al. Preparation of nanosize Pt clusters using ion exchange of Pt(NH3)42+ inside mesoporous channel of MCM-41 , 1996 .

[2] F. Rey,et al. Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica , 1995, Nature.

[3] J. S. Beck,et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism , 1992, Nature.

[4] D. Breslow,et al. BIS-(CYCLOPENTADIENYL)-TITANIUM DICHLORIDE —ALKYLALUMINUM COMPLEXLS AS CATALYSTS FOR THE POLYMERIZATION OF ETHYLENE , 1957 .