Anomalous behavior of Transiting Exoplanet Survey Satellite (TESS) optical assembly: root cause investigation reveals crystallization of RTV 566 at low temperatures

During qualification thermal testing of the Transiting Exoplanet Survey Satellite (TESS) lens assemblies, an anomalous focus change was observed during thermal-vacuum testing at its cold operating temperature (-75°C to - 85°C). Optical testing of the lens assemblies performed in the thermal-vacuum chamber indicated the magnitude and direction of the focus change, but did not identify the specific changes in the lens elements that were causing the focus shift. Individual lens motions measured using an interferometer indicated that lens vertices were moving relative to one another in a way that was inconsistent with predictions from detailed structural/thermal/optical (STOP) modeling. Further STOP analysis indicated the focus and vertex motion data were consistent with changes in lens curvature, suggesting that radial forces were deforming the lens. Finite element modeling showed that material property changes in the silicone adhesive material (room temperature vulcanizing, RTV 566) used to bond the lenses to the aluminum bezels could produce the necessary forces. The root cause of the focus shift was suspected to be unanticipated crystallization of the RTV 566 which has not previously been documented. Despite its widespread use, very little information has been published about the mechanical properties of RTV 566, and typical thermomechanical testing of its behavior has always utilized temperature sweeps. For this investigation, extensive testing was performed to characterize material property changes of RTV 566 samples under isothermal conditions at low temperatures (-75 to -85°C), for extended periods and at different levels of applied strain. The data presented here provide conclusive evidence that RTV 566 experiences time-dependent changes in mechanical properties that are consistent with crystallization phenomena.

[1]  M. Tosaka Strain-Induced Crystallization of Crosslinked Natural Rubber As Revealed by X-ray Diffraction Using Synchrotron Radiation , 2007 .

[2]  M. Haller,et al.  Morphology of Polysiloxanes Crystallized from the Melt , 1969 .

[3]  Kurt Binder,et al.  Supercooled Liquids and the Glass Transition , 2011 .

[4]  J. Kelly,et al.  The use of tests on high-shape-factor bearings to estimate the bulk modulus of natural rubber , 2011 .

[5]  A. Gent Crystallization in natural rubber. IV. Temperature dependence , 1955 .

[6]  Haibing Zhang,et al.  The Permeability Characteristics of Silicone Rubber , 2006 .

[7]  A. Gent,et al.  Strain-Induced Crystallization and Strength of Rubber , 2002 .

[8]  Rajeshuni Ramesham,et al.  Reliability and Qualification of Hardware to Enhance The Mission Assurance of JPL/NASA Projects , 2010 .

[9]  J. L. Cam,et al.  Effects of temperature on the mechanical behavior of filled and unfilled silicone rubbers , 2013 .

[10]  T. Mower Thermomechanical behavior of aerospace-grade RTV (silicone adhesive) , 2018, International Journal of Adhesion and Adhesives.

[11]  Patrick M. Sheridan,et al.  Design of Components , 2012 .

[12]  B. Huneau STRAIN-INDUCED CRYSTALLIZATION OF NATURAL RUBBER: A REVIEW OF X-RAY DIFFRACTION INVESTIGATIONS , 2011 .

[13]  E. H. Andrews Strain-induced crystallization in natural rubber , 1964 .

[14]  Á. Alegría,et al.  Dynamical and structural aspects of the cold crystallization of poly(dimethylsiloxane) (PDMS) , 2008 .

[15]  Paul R. Yoder Mounting optics in optical instruments , 2002 .

[16]  J. H. Magill Crystallization of poly(tetramethyl‐p‐silphenylene)‐siloxane (TMPS) polymers. Part II , 1967 .

[17]  C. Weir,et al.  Crystallization and Second-Order Transitions in Silicone Rubbers , 1950 .

[18]  Zhiping Zhou,et al.  Features of strain-induced crystallization of natural rubber revealed by experiments and simulations , 2017 .

[19]  J. M. Horton,et al.  Axial Loading of Bonded Rubber Blocks , 2002 .

[20]  A. Gent,et al.  Strain-induced crystallization and strength of elastomers. I. cis-1,4-polybutadiene , 2001 .

[21]  Victor L. Genberg,et al.  Athermal design of nearly incompressible bonds , 2002, SPIE Optics + Photonics.