Gas-based hydride applications: recent progress and future needs

Hydride applications can be cataloged under five main categories: H2 storage, thermal compression (including closed thermodynamic systems), gas separation, electrochemical and processing and miscellaneous. Recent commercial and R&D hydride applications activities are reviewed herein (excluding the NiMH battery). Growing interest in fuel cell power has stimulated interest in hydride storage of H2, with good near-term commercial potential in the subcategories of stationary, small portable and on-board vehicular storage. The competition for vehicular hydride storage is high pressure compressed H2 held in lightweight composite cylinders. If hydrides are to compete, we must develop radical new concepts to substantially increase the gravimetric capacity at low desorption temperatures.

[1]  Gianluca Morgante,et al.  Evaluation of hydride compressor elements for the Planck sorption cryocooler , 2002 .

[2]  D. Noréus,et al.  Mechanically reversible conductor–insulator transition in Mg2NiH4 , 2002 .

[3]  M. Ron,et al.  A hydrogen heat pump as a bus air conditioner , 1984 .

[4]  I. H. Öğüş,et al.  NATO ASI Series , 1997 .

[5]  M. Prina,et al.  Assessment of Zr–V–Fe getter alloy for gas-gap heat switches , 2002 .

[6]  R. A. Fellows,et al.  Aircraft thermal detection utilizing metal hydrides , 1984 .

[7]  Manfred Groll,et al.  The two-stage metal hydride heat transformer , 1999 .

[8]  J. Corriou,et al.  Modeling of hydrogen isotopes separation in a metal hydride bed , 1999 .

[9]  J. H. Rector,et al.  Yttrium and lanthanum hydride films with switchable optical properties , 1996, Nature.

[10]  M. Au,et al.  The recovery, purification, storage and transport of hydrogen separated from industrial purge gas by means of mobile hydride containers , 1996 .

[11]  Yūta Noda,et al.  Catalytic transfer hydrogenation of butene on hydrogen-absorbing alloys (LaNi5, CaNi5 and LaNi4Al) , 2001 .

[12]  Heat-mass transfer during hydrogen sorption from gas mixture by hydride-forming sorbents , 1994 .

[13]  M. Ron,et al.  Optimization of a Hydrogen Heat Pump* , 1989 .

[14]  Byung Ha Kang,et al.  Thermal modelling and analysis of a metal hydride chiller for air conditioning , 1995 .

[15]  G. Sandrock A panoramic overview of hydrogen storage alloys from a gas reaction point of view , 1999 .

[16]  M. Ron The normalized pressure dependence method for the evaluation of kinetic rates of metal hydride formation/decomposition , 1999 .

[17]  Yu. I. Shanin,et al.  An installation for water cooling based on a metal hydride heat pump , 2002 .

[18]  Y. Yurum,et al.  Hydrogen energy system : production and utilization of hydrogen and future aspects , 1996 .

[19]  G. Sandrock,et al.  Catalyzed Complex Metal Hydrides , 2002 .

[20]  M. Groll,et al.  A multi-hydride thermal wave device for simultaneous heating and cooling , 1999 .

[21]  A. Solovey,et al.  Metal hydride heat pump for watering systems , 2001 .

[22]  M. Nishikawa,et al.  Isotope separation factor and isotopic exchange rate between hydrogen and deuterium of palladium , 1995 .

[23]  H. Wipf Hydrogen in Metals III , 1997 .

[24]  P. M Golben,et al.  Hydride-based cold-start heater for automotive catalyst , 1997 .

[25]  Jamil A. Khan,et al.  Effective heat transfer in a metal-hydride-based hydrogen separation process , 2001 .

[26]  Hubert A. Gasteiger,et al.  Handbook of fuel cells : fundamentals technology and applications , 2003 .

[27]  Jeong-Gun Park,et al.  The operating characteristics of the compressor-driven metal hydride heat pump system , 2001 .

[28]  P. Lund,et al.  Combined hydrogen compressing and heat transforming through metal hydrides , 1999 .

[29]  Dieter M. Gruen,et al.  Preparation and properties of porous metal hydride compacts , 1980 .

[30]  H. Imamura,et al.  Transfer hydrogenation of olefin from alcohol using a hydrogen-absorbing alloy (CaNi5) catalyst , 1999 .

[31]  B. Bogdanovic,et al.  A process steam generator based on the high temperature magnesium hydride/magnesium heat storage system , 1995 .

[32]  M. Nishikawa,et al.  Hydrogen isotope separation using particle beds of LaNi3Al2 hydride , 1993 .