Optical properties of Au-Ag alloys: An ellipsometric study

Optical properties of AgxAu1-x alloys were obtained experimentally using spectroscopic ellipsometry measurements on thin films fabricated by electron beam evaporation. Thin film thicknesses varied between 170 and 330 nm, making size effects negligible. Values of the complex refractive index of the pure metals were in good agreement with literature reports. The optical data set reported in this work can accurately reproduce experimental results. This is very important because there are not reliable and systematic optical constants for the alloys. Moreover, we show that the weighted average of the refractive indices of the pure metals fails to represent those of the alloys, not only in the region near the onset for interband transitions but also in the near-IR region.

[1]  T. Puig,et al.  Optical properties of ceria-zirconia epitaxial films grown from chemical solutions , 2013 .

[2]  Yoshiaki Nishijima,et al.  Unusual optical properties of the Au/Ag alloy at the matching mole fraction , 2012 .

[3]  D. N. Rao,et al.  Laser-assisted synthesis of Au-Ag alloy nanoparticles with tunable surface plasmon resonance frequency , 2012 .

[4]  H. Atwater,et al.  Plasmonics for improved photovoltaic devices. , 2010, Nature materials.

[5]  Ovidio Peña-Rodríguez,et al.  Scattering of electromagnetic radiation by a multilayered sphere , 2009, Comput. Phys. Commun..

[6]  Blaine D. Johs,et al.  Dielectric function representation by B‐splines , 2008 .

[7]  P. Alivisatos The use of nanocrystals in biological detection , 2004, Nature Biotechnology.

[8]  R. Stafford,et al.  Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance , 2003, Proceedings of the National Academy of Sciences of the United States of America.

[9]  W. Barnes,et al.  Surface plasmon subwavelength optics , 2003, Nature.

[10]  E. Coronado,et al.  The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment , 2003 .

[11]  A. Kiennemann,et al.  Effect of Fischer–Tropsch synthesis on the microstructure of Fe–Co-based metal/spinel composite materials , 2001 .

[12]  C. Domínguez,et al.  ELLIPSOMETRY ON VERY THICK MULTILAYER STRUCTURES , 1999 .

[13]  Mostafa A. El-Sayed,et al.  Alloy Formation of Gold−Silver Nanoparticles and the Dependence of the Plasmon Absorption on Their Composition , 1999 .

[14]  G. W. Arnold,et al.  Metal Nanocluster Formation by Ion Implantation in Silicate Glasses:. Nonlinear Optical Applications , 1996 .

[15]  Paul Mulvaney,et al.  Surface Plasmon Spectroscopy of Nanosized Metal Particles , 1996 .

[16]  Gerald Earle Jellison,et al.  Data analysis for spectroscopic ellipsometry , 1993 .

[17]  G. Grimvall,et al.  Electrical transport and deviations from Matthiessen's rule in alloys , 1980 .

[18]  D. Aspnes,et al.  Investigation of effective-medium models of microscopic surface roughness by spectroscopic ellipsometry , 1979 .

[19]  J. Rivory Comparative study of the electronic structure of noble-metal-noble-metal alloys by optical spectroscopy , 1977 .

[20]  R. W. Christy,et al.  Optical Constants of the Noble Metals , 1972 .

[21]  Knut Ripken,et al.  Die optischen Konstanten von Au, Ag und ihren Legierungen im Energiebereich 2,4 bis 4,4 eV , 1972 .

[22]  H. Fukutani Optical Constants of Silver-Gold Alloys , 1971 .

[23]  G. Mie Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen , 1908 .