Solvent dependent synthesis of micro- and nano- crystalline phosphinate based 1D tubular MOF: structure and CO2 adsorption selectivity

A novel porous tubular 1D-MOF, built from Cu(II), 1,2-bis(4-pyridyl)ethane and P,P′-diphenyl-diphosphinate, has been prepared by an easy and direct self-assembly process in either needle microcrystal or nanorod form depending on the synthesis conditions. The CO2 absorption kinetics drastically increased from the micrometric crystals to the nanorods. The selectivity towards other gases and polar solvents was also investigated.

[1]  Yurong Tang,et al.  Ultrasound-induced switching of sheetlike coordination polymer microparticles to nanofibers capable of gelating solvents. , 2009, Journal of the American Chemical Society.

[2]  V. Choudhary,et al.  Adsorption of methane, ethane, ethylene, and carbon dioxide on silicalite-l , 1996 .

[3]  R. Ranjan,et al.  Microporous Metal Organic Framework Membrane on Porous Support Using the Seeded Growth Method , 2009 .

[4]  A. Orlandini,et al.  A new copper(II) tubelike metal–organic framework constructed from P,P′-diphenylmethylenediphosphinic acid and 4,4′-bipyridine: Synthesis, structure, and thermal behavior , 2008 .

[5]  Seth M. Cohen,et al.  Postsynthetic modification of metal-organic frameworks. , 2009, Chemical Society reviews.

[6]  T. Luo,et al.  A journey in search of single-walled metal–organic nanotubes , 2011 .

[7]  C. Pinel,et al.  Metal-organic frameworks: opportunities for catalysis. , 2009, Angewandte Chemie.

[8]  Jianping Ma,et al.  Independent 1D nanosized metal-organic tube: anion exchange, separation, and anion-responsive luminescence. , 2012, Inorganic chemistry.

[9]  P. Sozzani,et al.  Conformation and molecular dynamics of single polystyrene chain confined in coordination nanospace. , 2008, Journal of the American Chemical Society.

[10]  O. Shekhah,et al.  Thin films of metal-organic frameworks. , 2009, Chemical Society reviews.

[11]  K. Seki.  Design of an adsorbent with an ideal pore structure for methane adsorption using metal complexes , 2001 .

[12]  L. Cronin,et al.  Polymeric silver(I) coordination tubes. , 2004, Chemical communications.

[13]  Michael O'Keeffe,et al.  Reticular synthesis and the design of new materials , 2003, Nature.

[14]  Daofeng Sun,et al.  A metal-organic nanotube exhibiting reversible adsorption of (H2O)12 cluster. , 2008, Journal of the American Chemical Society.

[15]  T. Malcherek,et al.  Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate. , 2012, Chemical communications.

[16]  R. Cao,et al.  A new type of three-dimensional framework constructed from dodecanuclear cadmium(II) macrocycles. , 2003, Chemical communications.

[17]  Zhao,et al.  A Silver(I) Coordination Polymer Chain Containing Nanosized Tubes with Anionic and Solvent Molecule Guests This work was supported by the National Nature Science Foundation of China. M.C.H. thanks the Croucher Foundation of Hong Kong for financial support. , 2000, Angewandte Chemie.

[18]  C. Serre,et al.  Crystallized frameworks with giant pores: are there limits to the possible? , 2005, Accounts of chemical research.

[19]  Rosario Scopelliti,et al.  A synthetic zwitterionic water channel: characterization in the solid state by X-ray crystallography and NMR spectroscopy. , 2005, Angewandte Chemie.

[20]  A. Ienco,et al.  Inorganic-organic hybrids of the p,p'-diphenylmethylenediphosphinate, pcp2-. Synthesis, characterization, and XRPD structures of [Sn(pcp)] and [Cu(pcp)]. , 2005, Inorganic chemistry.

[21]  Susumu Kitagawa,et al.  Controlled Multiscale Synthesis of Porous Coordination Polymer in Nano/Micro Regimes , 2010 .

[22]  S. Solovieva,et al.  Molecular tectonics: on the formation of 1-D silver coordination networks by thiacalixarenes bearing nitrile groups. , 2007, Dalton transactions.

[23]  A. Ienco,et al.  Copper(II) Complexes with Bridging Diphosphinates : The Effect of the Elongation of the Aliphatic Chain on the Structural Arrangements Around the Metal Centres , 2008 .

[24]  S Bracco,et al.  Methane and carbon dioxide storage in a porous van der Waals crystal. , 2005, Angewandte Chemie.

[25]  X. You,et al.  A ZnII-Based Chiral Crystalline Nanotube , 2006 .

[26]  C. Petit,et al.  MOF–Graphite Oxide Composites: Combining the Uniqueness of Graphene Layers and Metal–Organic Frameworks , 2009 .

[27]  P. Cheng,et al.  A CNT-like coordination tube with cyano-bridges. , 2007, Dalton transactions.

[28]  A. Clearfield,et al.  Polymorphism and Phase Transition in Nanotubular Uranyl Phenylphosphonate: (UO2)3(HO3PC6H5)2(O3PC6H5)2·H2O , 1998 .

[29]  Dan Li,et al.  A metal-organic framework containing discrete single-walled nanotubes based on curved trinuclear [Cu3(micro3-O)(micro-OH)(triazolate)2]+ building blocks. , 2008, Chemical communications.

[30]  Weiqi Wang,et al.  Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines. , 2008, Chemical communications.

[31]  Susumu Kitagawa,et al.  Functional porous coordination polymers. , 2004, Angewandte Chemie.

[32]  Keiji Nakagawa,et al.  Rapid preparation of flexible porous coordination polymer nanocrystals with accelerated guest adsorption kinetics. , 2010, Nature chemistry.

[33]  P. Sozzani,et al.  Nanochannels of two distinct cross-sections in a porous Al-based coordination polymer. , 2008, Journal of the American Chemical Society.

[34]  S. Teat,et al.  Metal-organic calixarene nanotubes. , 2010, Angewandte Chemie.

[35]  Omar M Yaghi,et al.  Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5). , 2007, Journal of the American Chemical Society.

[36]  C. Wöll,et al.  Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111). , 2005, Journal of the American Chemical Society.

[37]  E. Bernstein,et al.  Aromatic van der Waals Clusters: Structure and Nonrigidity , 1996 .

[38]  Mohamed Eddaoudi,et al.  Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties , 2000 .

[39]  H. Choi,et al.  Carbon nanotube coated snowman-like particles and their electro-responsive characteristics. , 2012, Chemical communications.

[40]  T. Odom,et al.  Size control of arsenic trioxide nanocrystals grown in nanowells. , 2009, Journal of the American Chemical Society.

[41]  T. Tseng,et al.  Self-assembled arrays of single-walled metal-organic nanotubes. , 2009, Angewandte Chemie.

[42]  Daofeng Sun,et al.  Polymorphism in high-crystalline-stability metal-organic nanotubes. , 2009, Inorganic chemistry.

[43]  P. Sozzani,et al.  Methane, carbon dioxide and hydrogen storage in nanoporous dipeptide-based materials. , 2009, Chemical communications.

[44]  S. Kitagawa,et al.  Porous coordination polymer hybrid device with quartz oscillator: effect of crystal size on sorption kinetics. , 2011, Journal of the American Chemical Society.