Synthese und kristallstrukturuntersuchung von bis[dicarbonyl(μ-trifluormethylisocyanid)-(η-pentamethylcyclopentadienyl)molybdän)], [Mo(CO)2(μ-CNCF3)(η-Cp★)]2 und dessen isomerisierung zu Cp★(CO)2Mo(μ-F3CNCCNCF3)Mo(CO)2Cp★

[1]  D. Beach,et al.  X-ray photoelectron spectroscopic study of trifluoromethyl isocyanide. Back-bonding, fluorine lone-pair ionization potentials, and the CF3NC→CF3CN isomerization energy , 1985 .

[2]  D. Lentz,et al.  Gas-phase structure of pentacarbonyl(trifluoromethyl isocyanide)chromium, (CF3NC)Cr(CO)5 , 1985 .

[3]  D. Lentz Tetrakis(trifluormethylisocyanid)nickel, Ni(CNCF3)4, und Bis[μ‐(trifluormethylisocyanid)‐(η‐cyclopentadienyl)nickel], [Ni(μ‐CNCF3)(η‐C5H5]2 , 1985 .

[4]  D. Lentz,et al.  F3CNCCNCF3, ein neuer Brückenligand: Bildung durch CC‐Verknüpfung zweier CF3NC‐Liganden und Spaltung einer MoMo‐Bindung , 1984 .

[5]  D. Lentz Trifluormethylisocyanid. Eine neue synthese [1] , 1984 .

[6]  D. Lentz Trifluormethylisocyanid, ein starker π‐Akzeptor‐Ligand — Pentacarbonyl(trifluormethylisocyanid)chrom und ‐wolfram , 1984 .

[7]  M. Curtis,et al.  Metal-metal multiple bonds. 13. Structural diversity in the reactions of Cp2Mo2(CO)4(Mo.tplbond.Mo) with diazoalkanes and aryl azides , 1983 .

[8]  R. D. Adams,et al.  Addition of isocyanides to [CpMo(CO)2]2. Crystal and molecular structure of Cp2Mo2(CO)4(.mu.-.eta.2-CNPh) which contains a bridging .eta. isocyanide ligand , 1982 .

[9]  N. Coville The reaction between [?5-C5H5M(CO)3]2, ?5-C5H5M(CO)3I (M _ Mo, W) and isonitriles , 1981 .

[10]  F. Cotton,et al.  Molecular structures and barriers to internal rotation in bis (.eta.5-cyclopentadienyl)hexacarbonylditungsten and its molybdenum analog , 1974 .

[11]  M. Brice,et al.  Intramolecular ligand scrambling via bridged transition states or intermediates in di(pentahapto-cyclopentadienyl)(methyl isocyanide)(pentacarbonyl)dimolybdenum , 1973 .