Flexible and Highly Scalable V2O5‐rGO Electrodes in an Organic Electrolyte for Supercapacitor Devices

Vanadium pentoxide–reduced graphene oxide (rGO) free-standing electrodes are used as electrodes for supercapacitor applications, eliminating the need for current collectors or additives and reducing resistance (sheet resistance 29.1 Ω □−1). The effective exfoliation of rGO allows improved electrolyte ions interaction, achieving high areal capacitance (511.7 mF cm−2) coupled with high mass loadings. A fabricated asymmetric flexible device based on rGO/V2O5-rGO (VGO) consists of approximately 20 mg of active mass and still delivers a low equivalent series resistance (ESR) of 3.36 Ω with excellent cycling stability. A prototype unit of the assembled device with organic electrolyte is shown to light up eight commercial light-emitting diode bulbs.

[1]  Fei Xiao,et al.  Flexible all-solid-state asymmetric supercapacitors based on free-standing carbon nanotube/graphene and Mn3O4 nanoparticle/graphene paper electrodes. , 2012, ACS applied materials & interfaces.

[2]  X. Zhao,et al.  Synthesis and Capacitive Properties of Manganese Oxide Nanosheets Dispersed on Functionalized Graphene Sheets , 2011 .

[3]  Fei Liu,et al.  Folded Structured Graphene Paper for High Performance Electrode Materials , 2012, Advanced materials.

[4]  Ran Liu,et al.  Synthesis and characterization of RuO(2)/poly(3,4-ethylenedioxythiophene) composite nanotubes for supercapacitors. , 2010, Physical chemistry chemical physics : PCCP.

[5]  Junwu Zhu,et al.  Bioinspired Effective Prevention of Restacking in Multilayered Graphene Films: Towards the Next Generation of High‐Performance Supercapacitors , 2011, Advanced materials.

[6]  Afriyanti Sumboja,et al.  Large Areal Mass, Flexible and Free‐Standing Reduced Graphene Oxide/Manganese Dioxide Paper for Asymmetric Supercapacitor Device , 2013, Advanced materials.

[7]  Zhongwei Chen,et al.  Graphene-Based Flexible Supercapacitors: Pulse-Electropolymerization of Polypyrrole on Free-Standing Graphene Films , 2011 .

[8]  G. Lu,et al.  Fabrication of Graphene/Polyaniline Composite Paper via In Situ Anodic Electropolymerization for High-Performance Flexible Electrode. , 2009, ACS nano.

[9]  Y. Qian,et al.  Facile Preparation and Electrochemical Properties of V2O5-Graphene Composite Films as Free-Standing Cathodes for Rechargeable Lithium Batteries , 2012 .

[10]  J. Tarascon,et al.  V2O5-anchored carbon nanotubes for enhanced electrochemical energy storage. , 2011, Journal of the American Chemical Society.

[11]  S. Stankovich,et al.  Preparation and characterization of graphene oxide paper , 2007, Nature.

[12]  Keon Jae Lee,et al.  Bendable inorganic thin-film battery for fully flexible electronic systems. , 2012, Nano letters.

[13]  A. Manivannan,et al.  A reduced graphene oxide/Co3O4 composite for supercapacitor electrode , 2013 .

[14]  R. Ruoff,et al.  Graphene-based ultracapacitors. , 2008, Nano letters.

[15]  Hao Jiang,et al.  High–rate electrochemical capacitors from highly graphitic carbon–tipped manganese oxide/mesoporous carbon/manganese oxide hybrid nanowires , 2011 .

[16]  Ran Liu,et al.  Heterogeneous nanostructured electrode materials for electrochemical energy storage. , 2011, Chemical communications.

[17]  P. J. Ollivier,et al.  Layer-by-Layer Assembly of Ultrathin Composite Films from Micron-Sized Graphite Oxide Sheets and Polycations , 1999 .

[18]  D. Wexler,et al.  Rapid synthesis of free-standing MoO3/Graphene films by the microwave hydrothermal method as cathode for bendable lithium batteries , 2013 .

[19]  Paula T Hammond,et al.  Facilitated ion transport in all-solid-state flexible supercapacitors. , 2011, ACS nano.

[20]  S. Stankovich,et al.  Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide , 2007 .

[21]  Zhong Lin Wang,et al.  Fiber supercapacitors made of nanowire-fiber hybrid structures for wearable/flexible energy storage. , 2011, Angewandte Chemie.

[22]  Jaclyn D. Wiggins-Camacho,et al.  Influence of hydrofluoric acid formation on lithium ion insertion in nanostructured V 2O 5 , 2012 .

[23]  Sanjaya D. Perera,et al.  Vanadium oxide nanowire – Graphene binder free nanocomposite paper electrodes for supercapacitors: A facile green approach , 2013 .

[24]  John R. Reynolds,et al.  Poly[Bis-EDOT-Isoindigo]: An Electroactive Polymer Applied to Electrochemical Supercapacitors , 2012 .

[25]  Feng Li,et al.  Graphene–Cellulose Paper Flexible Supercapacitors , 2011 .

[26]  Guangmin Zhou,et al.  Graphene anchored with co(3)o(4) nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. , 2010, ACS nano.

[27]  Khalil Amine,et al.  Chemically active reduced graphene oxide with tunable C/O ratios. , 2011, ACS nano.

[28]  Xin Zhao,et al.  Flexible holey graphene paper electrodes with enhanced rate capability for energy storage applications. , 2011, ACS nano.

[29]  Xiaohong Liu,et al.  Flexible graphene/MnO2 composite papers for supercapacitor electrodes , 2011 .

[30]  Changsheng Liu,et al.  Flexible pillared graphene-paper electrodes for high-performance electrochemical supercapacitors. , 2012, Small.

[31]  G. Rubloff,et al.  Ozone-Based Atomic Layer Deposition of Crystalline V2O5 Films for High Performance Electrochemical Energy Storage , 2012 .

[32]  L. Tong,et al.  Single‐Crystalline V2O5 Ultralong Nanoribbon Waveguides , 2009 .

[33]  Jun Zhou,et al.  Flexible solid-state supercapacitors based on carbon nanoparticles/MnO2 nanorods hybrid structure. , 2012, ACS nano.

[34]  R. Ruoff,et al.  Carbon-Based Supercapacitors Produced by Activation of Graphene , 2011, Science.

[35]  W. Fang Synthesis and Electrochemical Characterization of Vanadium Oxide/Carbon Nanotube Composites for Supercapacitors , 2008 .

[36]  Y. Gogotsi,et al.  Materials for electrochemical capacitors. , 2008, Nature materials.

[37]  Songtao Lu,et al.  Synergistic effects from graphene and carbon nanotubes enable flexible and robust electrodes for high-performance supercapacitors. , 2012, Nano letters.

[38]  Wei Luo,et al.  Self-assembled hierarchical MoO2/graphene nanoarchitectures and their application as a high-performance anode material for lithium-ion batteries. , 2011, ACS nano.

[39]  Yi Cui,et al.  Solution-processed graphene/MnO2 nanostructured textiles for high-performance electrochemical capacitors. , 2011, Nano letters.

[40]  G. Shi,et al.  Highly conductive chemically converted graphene prepared from mildly oxidized graphene oxide , 2011 .

[41]  Xing Xie,et al.  High-performance nanostructured supercapacitors on a sponge. , 2011, Nano letters.

[42]  Ji‐Guang Zhang,et al.  Self-assembled TiO2-graphene hybrid nanostructures for enhanced Li-ion insertion. , 2009, ACS nano.

[43]  Quan-hong Yang,et al.  A sandwich structure of graphene and nickel oxide with excellent supercapacitive performance , 2011 .

[44]  Eun Sung Kim,et al.  Thermal stability of graphite oxide , 2009 .

[45]  Jiaqiang Xu,et al.  Vanadium oxides–reduced graphene oxide composite for lithium-ion batteries and supercapacitors with improved electrochemical performance , 2013 .

[46]  Wentao Song,et al.  Facile synthesis of layered Zn2SnO4/graphene nanohybrid by a one-pot route and its application as high-performance anode for Li-ion batteries , 2013 .

[47]  Pooi See Lee,et al.  Electrochemical energy storage in a β-Na0.33V2O5 nanobelt network and its application for supercapacitors , 2010 .

[48]  S. Nguyen,et al.  Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials. , 2010, Small.