A Bibliometric Survey of Paraffin/Olefin Separation Using Membranes

Bibliometric studies allow to collect, organize and process information that can be used to guide the development of research and innovation and to provide basis for decision-making. Paraffin/olefin separations constitute an important industrial issue because cryogenic separation methods are frequently needed in industrial sites and are very expensive. As a consequence, the use of membrane separation processes has been extensively encouraged and has become an attractive alternative for commercial separation processes, as this may lead to reduction of production costs, equipment size, energy consumption and waste generation. For these reasons, a bibliometric survey of paraffin/olefin membrane separation processes is carried out in the present study in order to evaluate the maturity of the technology for this specific application. Although different studies have proposed the use of distinct alternatives for olefin/paraffin separations, the present work makes clear that consensus has yet to be reached among researchers and technicians regarding the specific membranes and operation conditions that will make these processes scalable for large-scale commercial applications.

[1]  Modelling of Ethane/Ethylene Separation Using Microporous , 2005 .

[2]  Luhong Zhang,et al.  Novel supported liquid membranes based on deep eutectic solvents for olefin-paraffin separation via facilitated transport , 2017 .

[3]  I. Pinnau,et al.  Enhanced propylene/propane separation by thermal annealing of an intrinsically microporous hydroxyl-functionalized polyimide membrane , 2015 .

[4]  Lora G. Toy,et al.  Solid polymer electrolyte composite membranes for olefin/paraffin separation , 2001 .

[5]  William J. Koros,et al.  Membrane‐based ethylene/ethane separation: The upper bound and beyond , 2013 .

[6]  M. Hartmann,et al.  Olefin/Paraffin Separation Potential of ZIF‐9 and ZIF‐71: A Combined Experimental and Theoretical Study , 2016 .

[7]  Matthias Wessling,et al.  Super selective membranes in gas-liquid membrane contactors for olefin/paraffin separation , 2004 .

[8]  Jae Hun Lee,et al.  Mixed matrix membranes based on dual-functional MgO nanosheets for olefin/paraffin separation , 2017 .

[9]  Y. Kang,et al.  Effect of nonionic n-octyl β-d-glucopyranoside surfactant on the stability improvement of silver polymer electrolyte membranes for olefin/paraffin separation , 2003 .

[10]  Haixiang Sun,et al.  Satellite TiO2 nanoparticles induced by silver ion in polymer electrolytes membrane for propylene/propane separation , 2014 .

[11]  T. Mohammadi,et al.  Pebax membrane for CO2/CH4 separation: Effects of various solvents on morphology and performance , 2017 .

[12]  M. Khraisheh,et al.  Enhancing Liquid-Phase Olefin-Paraffin Separations Using Novel Silver-Based Ionic Liquids , 2015 .

[13]  M. Boerrigter,et al.  Polyimide hollow fiber gas separation membranes: preparation and the suppression of plasticization in propane/propylene environments , 2001 .

[14]  M. Al-Marzouqi,et al.  Gas–liquid membrane contactor for ethylene/ethane separation by aqueous silver nitrate solution , 2014 .

[15]  Benny D. Freeman,et al.  Maximizing the right stuff: The trade-off between membrane permeability and selectivity , 2017, Science.

[16]  T. Kaghazchi,et al.  Immobilized Liquid Membrane for Propylene- Propane Separation , 2008 .

[17]  Mohammad Askari,et al.  Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes , 2013 .

[18]  Matthias Wessling,et al.  Auto and mutual plasticization in single and mixed gas C3 transport through Matrimid-based hollow fiber membranes , 2008 .

[19]  Jizhong Ren,et al.  Ultrathin solid polymer electrolyte PEI/Pebax2533/AgBF4 composite membrane for propylene/propane separation , 2011 .

[20]  T. Kaghazchi,et al.  Facilitated transport separation of propylene–propane: Experimental and modeling study , 2010 .

[21]  S. Kentish,et al.  Effect of Hydrocarbons on the Separation of Carbon Dioxide From Methane through a Polyimide Gas Separation Membrane , 2009 .

[22]  Ting Yang,et al.  Natural gas purification and olefin/paraffin separation using cross-linkable dual-layer hollow fiber membranes comprising β-Cyclodextrin , 2012 .

[23]  M. Omidkhah,et al.  Phenomenological modeling and analysis of gas transport in polyimide membranes for propylene/propane separation , 2015 .

[24]  Y. Kang,et al.  Olefin-induced dissolution of silver salts physically dispersed in inert polymers and their application to olefin/paraffin separation , 2004 .

[25]  Hyunjoon Lee,et al.  Isoprene/pentane separation using facilitated transport membranes , 2004 .

[26]  Christopher N. Bowman,et al.  Olefin separation using silver impregnated ion-exchange membranes and silver salt/polymer blend membranes , 1996 .

[27]  Anawat Sungpet Silver doped Nafion-poly(pyrrole) membranes for facilitated permeation of liquid-phase olefins , 2001 .

[28]  S. Koh,et al.  Enhanced olefin carrier activity of clean surface silver nanoparticles for facilitated transport membranes , 2009 .

[29]  Laboratory investigation of carbon dioxide separation from methane using a PES/Pebax 1657 composite membrane , 2017 .

[30]  G. Hsiue,et al.  C4 olefin/paraffin separation by poly[(1-trimethylsilyl)-1-propyne]-graft-poly(acrylic acid)-Ag+ complex membranes , 1996 .

[31]  Alexandre F. P. Ferreira,et al.  Accelerated synthesis of all-silica DD3R and its performance in the separation of propylene/propane mixtures , 2008 .

[32]  Benny D. Freeman,et al.  Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes , 1999 .

[33]  H. Yasuda,et al.  Continuous process for propylene/propane separation by use of silver nitrate carrier and zirconia porous membrane , 2002 .

[35]  J. Kim,et al.  Highly Perm-Selective Micro-Porous Hydrotalcite-Silica Membrane for Improved Carbon Dioxide-Methane Separation , 2015 .

[36]  Christopher W. Jones,et al.  ZIF-8 Membranes via Interfacial Microfluidic Processing in Polymeric Hollow Fibers: Efficient Propylene Separation at Elevated Pressures. , 2016, ACS applied materials & interfaces.

[37]  Azmi Mohd Shariff,et al.  Bulk CO2/CH4 separation for offshore operating conditionsusing membrane process , 2016 .

[38]  Z. Hashisho,et al.  Separation of a binary mixture of ethylene and ethane by adsorption on Na-ETS-10 , 2010 .

[39]  Y. Kang,et al.  Silver nanoparticles stabilized by crosslinked poly(vinyl pyrrolidone) and its application for facilitated olefin transport. , 2011, Journal of colloid and interface science.

[40]  Tahereh Kaghazchi,et al.  SUPPORTED LIQUID MEMBRANE SEPARATION OF PROPYLENE-PROPANE MIXTURES USING A METAL ION CARRIER , 2010 .

[41]  Y. Kang,et al.  Durable poly(vinyl alcohol)/AgBF4/Al(NO3)3 complex membrane with high permeance for propylene/propane separation , 2017 .

[42]  M. Hartmann,et al.  Olefin/paraffin separation over the Metal Organic Framework material Cu3(BTC)2 , 2008 .

[43]  R. Mahajan,et al.  Pushing the limits on possibilities for large scale gas separation: which strategies? , 2000 .

[44]  Yen-Hsin Liu,et al.  C2 and C3 hydrocarbon separations in poly(1,5-naphthalene-2,2′-bis(3,4-phthalic) hexafluoropropane) diimide (6FDA-1,5-NDA) dense membranes , 2002 .

[45]  Shimin Zhao,et al.  Multicycle Investigation of Normal Paraffin Separation from Naphtha To Improve Olefin and Aromatic Feed , 2015 .

[46]  T. Graham On the Absorption and Dialytic Separation of Gases by Colloid Septa. [Abstract] , 1866 .

[47]  M. Eddaoudi,et al.  A metal-organic framework–based splitter for separating propylene from propane , 2016, Science.

[48]  Richard D. Noble,et al.  Separation of gaseous olefin isomers using facilitated transport membranes , 1993 .

[49]  G. Hsiue,et al.  Ag+ contained complex membrane for the separation of C4 olefin/paraffin mixture , 1994 .

[50]  P. Gómez-Álvarez,et al.  Olefin/Paraffin Separation in Open Metal Site Cu-BTC Metal–Organic Framework , 2017 .

[51]  B. Freeman,et al.  Propane and propylene sorption in solid polymer electrolytes based on poly(ethylene oxide) and silver salts , 2001 .

[52]  Anil Kumar Pabby,et al.  Handbook of Membrane Separations : Chemical, Pharmaceutical, Food, and Biotechnological Applications , 2008 .

[53]  Jiyong Kim,et al.  Techno-economic evaluation of hybrid systems of pressure swing adsorption and membrane processes for coalbed methane separation , 2016 .

[54]  H. Kita,et al.  Permeation and separation properties of polyimide membranes to olefins and paraffins , 1996 .

[55]  A. B. Haan,et al.  Reactive Ionic Liquid Media for the Separation of Propylene/Propane Gaseous Mixtures , 2010 .

[56]  C. S. Hsu,et al.  Separation and Characterization of Olefin/Paraffin in Coal Tar and Petroleum Coker Oil , 2013 .

[57]  Z. Tang,et al.  Olefin/paraffin separation through membranes: from mechanisms to critical materials , 2019, Journal of Materials Chemistry A.

[58]  E. I. Lozinskaya,et al.  Gas separation characteristics of new membrane materials based on poly(ethylene glycol)-crosslinked polymers and ionic liquids , 2012, Petroleum Chemistry.

[59]  H. Matsuyama,et al.  Ethylene/ethane separation and concentration by hollow fiber facilitated transport membrane module with permeation of silver nitrate solution , 2005 .

[60]  Hyunjoon Lee,et al.  Separation of olefin/paraffin mixtures using zwitterionic silver complexes as transport carriers. , 2007, Chemistry.

[61]  K. Shahidi,et al.  Preparation and C3H8/Gas Separation Properties of a Synthesized Single Layer PDMS Membrane , 2010 .

[62]  Gongpin Liu,et al.  Conformation‐Controlled Molecular Sieving Effects for Membrane‐Based Propylene/Propane Separation , 2019, Advanced materials.

[63]  Zhong Li,et al.  Adsorption performance of MIL-100(Fe) for separation of olefin–paraffin mixtures , 2017 .

[64]  B. Min,et al.  Facilitated transport of ethylene across polymer membranes containing silver salt: effect of HBF4 on the photoreduction of silver ions , 2003 .

[65]  Distinguished discriminatory separation of CO2 from its methane-containing gas mixture via PEBAX mixed matrix membrane , 2017 .

[66]  J. Hayashi,et al.  Separation of ethane/ethylene and propane/propylene systems with a carbonized BPDA-pp'ODA polyimide membrane , 1996 .

[67]  S. Kang,et al.  Effect of Ag2O nanoparticles on long-term stable polymer/AgBF4/Al(NO3)3 complex membranes for olefin/paraffin separation , 2017 .

[68]  V. Zaspalis,et al.  A novel system of Al100P60Oz microporous ceramic membrane for hydrogen separation from hydrogen/propane mixtures , 2007 .

[69]  Matthias Wessling,et al.  Composite hollow fiber gas–liquid membrane contactors for olefin/paraffin separation , 2004 .

[70]  M. Hartmann,et al.  Continuous Separation of Light Olefin/Paraffin Mixtures on ZIF-4 by Pressure Swing Adsorption and Membrane Permeation , 2018, Molecules.

[71]  T. Kaghazchi,et al.  Separation of Propylene-Propane Mixture Using Immobilized Liquid Membrane via Facilitated Transport Mechanism , 2009 .

[72]  T. Tan,et al.  Mixed Matrix Membrane Based on Cross-Linked Poly[(ethylene glycol) methacrylate] and Metal–Organic Framework for Efficient Separation of Carbon Dioxide and Methane , 2018 .

[73]  S. Bhatia,et al.  Microwave heating-synthesized zeolite membrane for CO2/CH4 separation , 2012 .

[74]  Cong-jie Gao,et al.  Synthesis of AgCl/PMMA hybrid membranes and their sorption performance of cyclohexane/cyclohexene , 2007 .

[75]  M. Sadeghi,et al.  Separation of ethylene/ethane and propylene/propane by cellulose acetate-silica nanocomposite membranes , 2012 .

[76]  K. Char,et al.  Correlation between anions of ionic liquids and reduction of silver ions in facilitated olefin transport membranes , 2008 .

[77]  T. Merkel,et al.  Silver salt facilitated transport membranes for olefin/paraffin separations: Carrier instability and a novel regeneration method , 2013 .

[78]  K. Char,et al.  Highly stabilized silver polymer electrolytes and their application to facilitated olefin transport membranes , 2004 .

[79]  D. A. Tanaka,et al.  Recent Advances on Carbon Molecular Sieve Membranes (CMSMs) and Reactors , 2016 .

[80]  Dc Kitty Nijmeijer,et al.  Performance and plasticization behavior of polymer–MOF membranes for gas separation at elevated pressures , 2014 .

[81]  C. Liang,et al.  Advanced Liquid Membranes Based on Novel Ionic Liquids for Selective Separation of Olefin/Paraffin via Olefin-Facilitated Transport , 2008 .

[82]  Liren Xu Carbon molecular sieve hollow fiber membranes for olefin/paraffin separations , 2013 .

[83]  F. Kapteijn,et al.  Ethane/ethene separation turned on its head: selective ethane adsorption on the metal-organic framework ZIF-7 through a gate-opening mechanism. , 2010, Journal of the American Chemical Society.

[84]  I. Ortiz,et al.  Effect of liquid flow on the separation of propylene/propane mixtures with a gas/liquid membrane contactor using Ag+-RTIL solutions , 2011 .

[85]  Y. Kang,et al.  Synthesis of silver halide nanocomposites templated by amphiphilic graft copolymer and their use as olefin carrier for facilitated transport membranes , 2009 .

[86]  Marcos Fallanza,et al.  Polymer–ionic liquid composite membranes for propane/propylene separation by facilitated transport , 2013 .

[87]  S. Sridhar,et al.  Metal-ion mediated separation of propylene from propane using PPO membranes , 1998 .

[88]  Liang Yu,et al.  Ultra-thin MFI membranes for olefin/nitrogen separation , 2017 .

[89]  A. Kargari,et al.  Modification of polycarbonate membrane by polyethylene glycol for CO2/CH4 separation , 2017 .

[90]  Shing Bo Peh,et al.  Alternatives to Cryogenic Distillation: Advanced Porous Materials in Adsorptive Light Olefin/Paraffin Separations. , 2019, Small.

[91]  K. Peinemann,et al.  Development of facilitated transport membranes for the separation of olefins from gas streams , 2002 .

[92]  G. Hsiue,et al.  Selective olefin permeation through Ag(I) contained silicone rubber-graft-poly(acrylic acid) membranes , 1997 .

[93]  Enrico Drioli,et al.  Membrane Gas Separation: A Review/State of the Art , 2009 .

[94]  Kitty Nymeijer,et al.  Propylene/Propane Separation with a Gas/Liquid Membrane Contactor Using a Silver Salt Solution , 2007 .

[95]  Chang-Ha Lee,et al.  Separation of Carbon Dioxide and Methane Mixture by an Adsorbent/Membrane Hybrid System Using Zeolite 5A Pellets and FAU-Zeolite Membrane , 2017 .

[96]  Hui Li,et al.  Poly(amide-6-b-ethylene oxide)/SAPO-34 mixed matrix membrane for CO2 separation , 2014 .

[97]  V. P. Vasilevsky,et al.  Surface Modified Polysulfone Hollow Fiber Membranes for Ethane/Ethylene Separation Using Gas-Liquid Membrane Contactors with Ionic Liquid-Based Absorbent , 2019, Fibers.

[98]  H. Maghsoudi Theoretical screening of zeolites for membrane separation of propylene/propane mixtures , 2018 .

[99]  D. Savage,et al.  Olefin separations via complexation with cuprous diketonate , 1988 .

[100]  Y. J. Kim,et al.  Effect of Plasticizers on the Formation of Silver Nanoparticles in Polymer Electrolyte Membranes for Olefin/Paraffin Separation , 2002 .

[101]  P. Schaetzel,et al.  Fine characterization of the ethylene and ethane sorption in poly(amide 12-block-tetramethylenoxide) copolymer/AgBF4 membranes , 2006 .

[102]  H. Kim,et al.  Highly selective facilitated transport membranes for isoprene/n-pentane separation , 2006 .

[103]  A. B. Fuertes,et al.  Aging of carbon membranes under different environments , 2001 .

[104]  R. T. Yang,et al.  Olefin/paraffin separations by adsorption: π‐Complexation vs. kinetic separation , 1998 .

[105]  K. Char,et al.  Effect of amino acids in polymer/silver salt complex membranes on facilitated olefin transport , 2005 .

[106]  J. Caro,et al.  Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[107]  R. Baker Gas Separation , 2012 .

[108]  S. S. Madaeni,et al.  The effect of surfactants on the structure and performance of PES membrane for separation of carbon dioxide from methane , 2012 .

[109]  L. Robeson,et al.  Correlation of separation factor versus permeability for polymeric membranes , 1991 .

[110]  Liyuan Deng,et al.  Fabrication and Evaluation of a Blend Facilitated Transport Membrane for CO2/CH4 Separation , 2015 .

[111]  L. Robeson,et al.  The upper bound revisited , 2008 .

[112]  D. Ruthven,et al.  Adsorptive separation of light olefins from paraffins , 2007 .

[113]  P. F. Scholander,et al.  Oxygen transport through hemoglobin solutions. , 1960, Science.

[114]  J. Ferraris,et al.  Fabrication and characterization of aging resistant carbon molecular sieve membranes for C3 separation using high molecular weight crosslinkable polyimide, 6FDA-DABA , 2019, Journal of Membrane Science.

[115]  Jaap F. Vente,et al.  Membrane Retrofit Option for Paraffin/Olefin Separation—A Technoeconomic Evaluation , 2012 .

[116]  C. Bielawski,et al.  A study of Cu(I)-ethylene complexation for olefin–paraffin separation , 2011 .

[117]  Pei Li,et al.  Natural gas purification and olefin/paraffin separation using cross-linkable 6FDA-Durene/DABA co-polyimides grafted with α, β, and γ-cyclodextrin , 2012 .

[118]  Carlos A. Grande,et al.  New pi-complexation adsorbents for propane-propylene separation. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[119]  A. C. Habert,et al.  Polymeric membranes containing silver salts for propylene/propane separation , 2012 .

[120]  D. Farrusseng,et al.  Absolute molecular sieve separation of ethylene/ethane mixtures with silver zeolite A. , 2012, Journal of the American Chemical Society.

[121]  Hyunjoon Lee,et al.  Highly efficient metal-free membranes for the separation of acetylene/olefin mixtures: Pyrrolidinium-based ionic liquids as acetylene transport carriers , 2010 .

[122]  Yong-ki Park,et al.  Performance Study of Multistage Membrane and Hybrid Distillation Processes for Propylene/Propane Separation† , 2017 .

[123]  Joe D. Goddard,et al.  Facilitated transport via carrier‐mediated diffusion in membranes: Part I. Mechanistic aspects, experimental systems and characteristic regimes , 1974 .

[124]  Separation of Olefin/Paraffin Mixtures with Carrier Facilitated Membranes , 2007 .

[125]  G. W. Meindersma,et al.  Potential of Silver-Based Room-Temperature Ionic Liquids for Ethylene/Ethane Separation , 2009 .

[126]  H. Matsuyama,et al.  Ethylene/ethane separation by facilitated transport membrane accompanied by permeation of aqueous silver nitrate solution , 2002 .

[127]  N. Hu,et al.  Preparation of steam-stable high-silica CHA (SSZ-13) membranes for CO2/CH4 and C2H4/C2H6 separation , 2015 .

[128]  G. Hsiue,et al.  Novel dry poly[(1-trimethylsilyl)-1-propyne]-AgClO4 complex membranes for olefin/paraffin separations , 1996 .

[129]  K. Char,et al.  Novel Application of Partially Positively Charged Silver Nanoparticles for Facilitated Transport in Olefin/Paraffin Separation Membranes , 2008 .

[130]  Y. S. Lin,et al.  Gamma-Alumina Supported Carbon Molecular Sieve Membrane for Propylene/Propane Separation , 2013 .

[131]  Kang Li,et al.  Long term stability of PTFE and PVDF membrane contactors in the application of propylene/propane separation using AgNO3 solution , 2013 .

[132]  E. Aksnes,et al.  Facilitated transport of ethene through Nafion membranes. Part II. Glycerine treated, water swollen membranes , 1993 .

[133]  Bassem A. Al-Maythalony Metal-organic framework based membranes for gas separation , 2019, Advanced Nanomaterials for Membrane Synthesis and its Applications.

[134]  D. Mecerreyes,et al.  Polymeric ionic liquid membranes containing IL–Ag+ for ethylene/ethane separation via olefin-facilitated transport , 2014 .

[135]  Xiaoli Ma,et al.  Zeolitic Imidazolate Framework Membranes for Light Olefin/Paraffin Separation , 2018, Crystals.

[136]  T. Steriotis,et al.  Porous ceramic membranes for propane–propylene separation via the π-complexation mechanism: unsupported systems , 2005 .

[137]  G. Hsiue,et al.  Polymeric complex membranes for olefin/paraffin separation , 1996 .

[138]  Masakoto Kanezashi,et al.  Organic–Inorganic Hybrid Silica Membranes with Controlled Silica Network Size for Propylene/Propane Separation , 2012 .

[139]  A. Corma,et al.  Synthesis of New Zeolite Structures , 2015 .

[140]  F. Kapteijn,et al.  Adsorptive separation of light olefin/paraffin mixtures , 2006 .

[141]  Y. S. Lin,et al.  Cuprous Chloride Modified Nanoporous Alumina Membranes for Ethylene-Ethane Separation , 1999 .

[142]  D. Ghanbari,et al.  Acrylonitrile–butadiene–styrene/poly(vinyl acetate)/nanosilica mixed matrix membrane for He/CH4 separation , 2014 .

[143]  R. Eldridge,et al.  Olefin/paraffin separation technology: a review , 1993 .

[144]  S. Hwang,et al.  Separation of propylene and propane by polyimide hollow-fiber membrane module , 1992 .

[145]  Z. Lai,et al.  Effective separation of propylene/propane binary mixtures by ZIF-8 membranes , 2012 .

[146]  W. Koros,et al.  Carbon molecular sieve dense film membranes derived from Matrimid® for ethylene/ethane separation , 2012 .

[147]  Y. Kang,et al.  Silver polymer electrolytes by π-complexation of silver ions with polymer containing CC bond and their application to facilitated olefin transport membranes , 2004 .

[148]  L. Lijun,et al.  Propylene/propane separation by porous graphene membrane: Molecular dynamic simulation and first-principle calculation , 2017 .

[149]  Yunxiang Bai,et al.  Poly(ether-b-amide)/ethylene glycol monophenyl ether gel membrane with superior CO2/N2 separation performance fabricated by thermally induced phase separation method , 2016 .

[150]  Yichang Pan,et al.  Enhanced C3H6/C3H8 separation performance in poly(vinyl acetate) membrane blended with ZIF-8 nanocrystals , 2018 .

[151]  B. Jose,et al.  Effect of phthalates on the stability and performance of AgBF4-PVP membranes for olefin/paraffin separation. , 2001, Chemical communications.

[152]  Chang Kon Kim,et al.  An ab initio study of ionic liquid silver complexes as carriers in facilitated olefin transport membranes , 2005 .

[153]  B. Kirchner,et al.  Use of water in aiding olefin/paraffin (liquid + liquid) extraction via complexation with a silver bis(trifluoromethylsulfonyl)imide salt , 2014 .

[154]  M. Junginger,et al.  Application of new sulfonated ionomer membranes in the separation of pentene and pentane by facilitated transport , 1997 .

[155]  K. K. Lau,et al.  Single and Binary CO2/CH4 Separation of a Zeolitic Imidazolate Framework‐8 Membrane , 2017 .

[156]  Eric Litwiller,et al.  High-performance carbon molecular sieve membranes for ethylene/ethane separation derived from an intrinsically microporous polyimide , 2016 .

[157]  W. Koros,et al.  Matrimid derived carbon molecular sieve hollow fiber membranes for ethylene/ethane separation , 2011 .

[158]  A. Rodrigues,et al.  Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment , 2009 .

[159]  Lorenz T. Biegler,et al.  Optimization of multistage olefin/paraffin membrane separation processes through rigorous modeling , 2019, AIChE Journal.

[160]  B. Min,et al.  Anomalous temperature dependence of facilitated propylene transport in silver polymer electrolyte membranes , 2003 .

[161]  H. Kita,et al.  Preparation and gas separation performance of flexible pyrolytic membranes by low-temperature pyrolysis of sulfonated polyimides , 2005 .

[162]  Farzad Seidi,et al.  Preparation and characterization of an Amino‐Cellulose (AC) derivative for development of thin film composite membrane for CO2/CH4 separation , 2016 .

[163]  Hui Xie,et al.  Separation of the hydrogen sulfide and methane mixture by the porous graphene membrane: Effect of the charges , 2014 .

[164]  Akira Ohkawa,et al.  Separation of propylene/propane mixture by a supported liquid membrane containing triethylene glycol and a silver salt , 2003 .

[165]  Loan A. Le,et al.  Hollow Fibers Structured Packings in Olefin/Paraffin Distillation: Apparatus Scale-Up and Long-Term Stability , 2013 .

[166]  Matthias Wessling,et al.  Ionic liquid silver salt complexes for propene/propane separation. , 2011, Physical chemistry chemical physics : PCCP.

[167]  S. Sridhar,et al.  Simulation studies for the separation of propylene and propane by ethylcellulose membrane , 1999 .

[168]  E. G. Litvinova,et al.  A Novel Poly(4‐methyl‐2‐pentyne)/TiO2 Hybrid Nanocomposite Membrane for Natural Gas Conditioning: Butane/Methane Separation , 2007 .

[169]  S. Semenova Polymer membranes for hydrocarbon separation and removal , 2004 .

[170]  Y. S. Lin,et al.  Propylene/Propane Mixture Separation Characteristics and Stability of Carbon Molecular Sieve Membranes , 2015 .

[171]  M. Zastrow Why South Korea is the world's biggest investor in research. , 2016, Nature.

[172]  William J. Koros,et al.  Olefin/paraffin gas separations with 6FDA-based polyimide membranes , 2000 .

[173]  S. Deng,et al.  Fabrication of cuprous nanoparticles in MIL-101: an efficient adsorbent for the separation of olefin–paraffin mixtures , 2014 .

[174]  P. Li,et al.  Preparation of nanoporous graphene and the application of its nanocomposite membrane in propylene/propane separation , 2015 .

[175]  A. Mohamed,et al.  Development of a hybrid membrane through coupling of high selectivity zeolite T on ZIF-8 intermediate layer and its performance in carbon dioxide and methane gas separation , 2014 .

[176]  Marcos Fallanza,et al.  Experimental study of the separation of propane/propylene mixtures by supported ionic liquid membranes containing Ag+–RTILs as carrier , 2012 .

[177]  K. Zamaraev,et al.  Separation of ethylene and ethane over polyphenyleneoxides membranes: transient increase of selectivity , 1993 .

[178]  V. Valtchev,et al.  Co3(HCOO)6 microporous metal-organic framework membrane for separation of CO2/CH4 mixtures. , 2011, Chemistry.

[179]  Yichao Lin,et al.  Fabrication of highly selective organosilica membrane for gas separation by mixing bis(triethoxysilyl)ethane with methyltriethoxysilane , 2019, Separation and Purification Technology.

[180]  W. Koros,et al.  Iron-containing carbon molecular sieve membranes for advanced olefin/paraffin separations , 2018 .

[181]  F. Kapteijn,et al.  Recent developments in zeolite membranes for gas separation , 2016 .

[182]  J. Lai,et al.  Metal ion modified PIM-1 and its application for propylene/propane separation , 2016 .

[183]  G. Hsiue,et al.  Swollen polymeric complex membranes for olefin/paraffin separation , 1998 .

[184]  K. Char,et al.  Nanocomposite membranes containing positively polarized gold nanoparticles for facilitated olefin transport , 2008 .

[185]  S. S. Madaeni,et al.  The effect of polyurethane on the structure and performance of PES membrane for separation of carbon dioxide from methane , 2014 .

[186]  T. Vlugt,et al.  Effective Model for Olefin/Paraffin Separation using (Co, Fe, Mn, Ni)-MOF-74 , 2017 .

[187]  T. Kaghazchi,et al.  Effect of Complexation Reaction Constant on the Separation of Propylene/Propane by Supported Liquid Membrane , 2015 .

[188]  T. Tsuru,et al.  Separation of propylene/propane binary mixtures by bis(triethoxysilyl) methane (BTESM)-derived silica membranes fabricated at different calcination temperatures , 2012 .

[189]  Kang Li,et al.  Polymeric membranes for light olefin/paraffin separation , 2012 .

[190]  T. Merkel,et al.  50th Anniversary Perspective: Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities , 2017 .

[191]  Carlos A. Grande,et al.  Olefin–Paraffin Separation Using Calcium-ETS-4 , 2014 .

[192]  William J. Koros,et al.  Olefins-selective asymmetric carbon molecular sieve hollow fiber membranes for hybrid membrane-distillation processes for olefin/paraffin separations , 2012 .

[193]  Kang Li,et al.  Separation of Olefin/Paraffin Gas Mixtures Using Ceramic Hollow Fiber Membrane Contactors , 2013 .

[194]  Kamalesh K. Sirkar,et al.  Glycerol-based immobilized liquid membranes for olefin-paraffin separation , 2002 .

[195]  Upgrading Carbon Dioxide/Methane Mixtures by using a Hybrid Membrane–Condensed Rotational Separation Process , 2014 .

[196]  Benny D. Freeman,et al.  Gas solubility, diffusivity and permeability in poly(ethylene oxide) , 2004 .

[197]  I. Ortiz,et al.  A Perspective of Solutions for Membrane Instabilities in Olefin/Paraffin Separations: A Review , 2018, Industrial & Engineering Chemistry Research.

[198]  M. Matsukata,et al.  Olefin Selective Ag-Exchanged X-Type Zeolite Membrane for Propylene/Propane and Ethylene/Ethane Separation. , 2019, ACS applied materials & interfaces.

[199]  M. Guiver,et al.  Advances in high permeability polymer-based membrane materials for CO2 separations , 2016 .

[200]  Inmaculada Ortiz,et al.  Room temperature ionic liquid with silver salt as efficient reaction media for propylene/propane separation: Absorption equilibrium , 2008 .

[201]  Kang Li,et al.  Olefin/Paraffin Separation using Ceramic Hollow Fiber Membrane Contactors , 2012 .

[202]  Yen-Hsin Liu,et al.  Gas and hydrocarbon (C2 and C3) transport properties of co-polyimides synthesized from 6FDA and 1,5-NDA (naphthalene)/Durene diamines , 2003 .

[203]  R. Goering Complexation structure and transport mechanism of 1,5-hexadiene and 1-hexene through silver facilitated transport membranes , 2000 .

[204]  Michael O'Keeffe,et al.  Reticular synthesis and the design of new materials , 2003, Nature.

[205]  Minh-Thong Le An assessment of the potential for the development of the shale gas industry in countries outside of North America , 2018, Heliyon.

[206]  V. Saini,et al.  Ethane selective IRMOF-8 and its significance in ethane-ethylene separation by adsorption. , 2014, ACS applied materials & interfaces.

[207]  Y. Kang,et al.  Facilitated olefin transport through room temperature ionic liquids for separation of olefin/paraffin mixtures , 2012 .

[208]  Hae‐Kwon Jeong,et al.  In situ synthesis of thin zeolitic-imidazolate framework ZIF-8 membranes exhibiting exceptionally high propylene/propane separation. , 2013, Journal of the American Chemical Society.

[209]  K. Char,et al.  Nanocomposite silver polymer electrolytes as facilitated olefin transport membranes , 2006 .

[210]  P. Apel,et al.  Prospects of Membrane Science Development , 2019, Membranes and Membrane Technologies.

[211]  W. Ho,et al.  Facilitated transport of olefins in Ag+-containing polymer membranes , 1994 .

[212]  Z. Man,et al.  Composite blending of ionic liquid–poly(ether sulfone) polymeric membranes: Green materials with potential for carbon dioxide/methane separation , 2016 .

[213]  D. C. Nijmeijer,et al.  Mixed matrix membranes containing MOF's for ethelyne/ethane separation. Part A: Membrane preparation and characterization , 2013 .

[214]  C. Bowman,et al.  Role of ion-exchange membrane morphology and sorption properties in facilitated transport di-olefin/mono-olefin separations , 1998 .

[215]  M. Hartmann,et al.  Adsorptive Separation of Olefin/Paraffin Mixtures with ZIF-4. , 2015, Langmuir : the ACS journal of surfaces and colloids.

[216]  V. Volkov,et al.  Polysulfone porous hollow fiber membranes for ethylene-ethane separation in gas-liquid membrane contactor , 2017 .

[217]  Tahereh Kaghazchi,et al.  Application of membrane separation processes in petrochemical industry: a review , 2009 .

[218]  Hideto Matsuyama,et al.  Separation of ethylene from ethane by a flowing liquid membrane using silver nitrate as a carrier , 1989 .

[219]  Y. Kang,et al.  Preparation of Poly(ethylene glycol) Brushes on Polysulfone Membranes for Olefin/Paraffin Separation , 2000 .

[220]  T. Merkel,et al.  Transport properties of PA12-PTMO/AgBF4 solid polymer electrolyte membranes for olefin/paraffin separation , 1997 .

[221]  P. Dutta,et al.  Modification of a continuous zeolite membrane grown within porous polyethersulfone with Ag(I) cations for enhanced propylene/propane gas separation , 2019, Microporous and Mesoporous Materials.

[222]  A. Feldhoff,et al.  Oriented Zeolitic Imidazolate Framework-8 Membrane with Sharp H2/C3H8 Molecular Sieve Separation , 2011 .

[223]  Y. Kang,et al.  Unusual separation property of propylene/propane mixtures through polymer/silver complex membranes containing mixed salts , 2005 .

[224]  L. Giorno,et al.  Thin-film composite hollow fiber membranes for ethylene/ethane separation in gas-liquid membrane contactor , 2019, Separation and Purification Technology.

[225]  Separation of 1-hexene/n-hexane mixtures using a hybrid membrane/extraction system , 1999 .

[226]  V. Valtchev,et al.  Nanocomposite MFI-alumina and FAU-alumina Membranes: Synthesis, Characterization and Application to Paraffin Separation and CO2 Capture , 2009 .

[227]  A. Shariff,et al.  Gas Separation of Carbon Dioxide from Methane Using Polysulfone Membrane Incorporated with Zeolite-T☆ , 2016 .

[228]  R. Krishna,et al.  Reprint of: Transient breakthroughs of CO2/CH4 and C3H6/C3H8 mixtures in fixed beds packed with Ni-MOF-74 , 2015 .

[229]  H. Kita,et al.  Permeation and separation properties of polyimide membranes to 1,3-butadiene and n-butane , 1997 .

[230]  E. Kamio,et al.  A facilitated transport ion-gel membrane for propylene/propane separation using silver ion as a carrier , 2013 .

[231]  Y. Yeong,et al.  Zeolitic Imidazolate Frameworks (ZIF): A Potential Membrane for CO2/CH4 Separation , 2014 .

[232]  R. Lichtenthaler,et al.  Propene/propane separation with copolyimide membranes containing silver ions , 2006 .

[233]  R. Krishna,et al.  Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation, adsorption, diffusion , 2011 .

[234]  K. K. Lau,et al.  Development and performance evaluation of Polydimethyl siloxane/Polysulfone (PDMS/PSF) composite membrane for CO2/CH4 separation , 2016 .

[235]  Ying Dai,et al.  High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations , 2012 .

[236]  B. Ahn,et al.  Reversible olefin complexation by silver ions in dry poly(vinyl methyl ketone) membrane and its application to olefin/paraffin separations , 2000 .

[237]  Jong Hak Kim,et al.  Facile preparation of Cu(I) impregnated MIL-101(Cr) and its use in a mixed matrix membrane for olefin/paraffin separation , 2018 .

[238]  Dinh Quan Nguyen,et al.  Effect of ester group on the performance of zwitterionic imidazolium compounds as membrane materials for separating alkene/alkane mixtures , 2008 .

[239]  A. Ismail,et al.  Separation of Binary Mixtures of Propylene and Propane by Facilitated Transport through Silver Incorporated Poly(Ether-Block-Amide) Membranes , 2015 .

[240]  Chang Kon Kim,et al.  Control of Ionic Interactions in Silver Salt−Polymer Complexes with Ionic Liquids: Implications for Facilitated Olefin Transport , 2006 .

[241]  P. Goh,et al.  The incorporation of graphene oxide into polysulfone mixed matrix membrane for CO2/CH4 separation , 2016 .

[242]  V. Linkov,et al.  Influence of oxygen-containing hydrocarbons on the separation of olefin/paraffin mixtures using facilitated transport , 1997 .

[243]  Nevra Ercan,et al.  High performance cyclic olefin copolymer (COC) membranes prepared with melt processing method and using of surface modified graphitic nano-sheets for H2/CH4 and H2/CO2 separation , 2016 .

[244]  Alexandre F. P. Ferreira,et al.  Suitability of Cu-BTC extrudates for propane–propylene separation by adsorption processes , 2011 .

[245]  K. Char,et al.  Effect of the polarity of silver nanoparticles induced by ionic liquids on facilitated transport for the separation of propylene/propane mixtures , 2008 .

[246]  Seong-Joong Kim,et al.  Preparation of carbon molecular sieve membranes on low-cost alumina hollow fibers for use in C3H6/C3H8 separation , 2018 .

[247]  M. Aghajani,et al.  Modified zeolitic-midazolate framework 8/poly(ether-block-amide) mixed-matrix membrane for propylene and propane separation , 2018 .

[248]  B. Min,et al.  Coordination structure of various ligands in crosslinked PVA to silver ions for facilitated olefin transport. , 2002, Chemical communications.

[249]  H. Kita,et al.  Olefin/paraffin separation performance of asymmetric hollow fiber membrane of 6FDA/BPDA-DDBT copolyimide , 2003 .

[250]  H. Kita,et al.  Olefin/Paraffin Separation through Carbonized Membranes Derived from an Asymmetric Polyimide Hollow Fiber Membrane , 1999 .

[251]  Qingping Xin,et al.  Poly (ethylene oxide) composite membrane synthesized by UV-initiated free radical photopolymerization for CO2 separation , 2017 .

[252]  Y. Kang,et al.  Selective coordination of silver ions to poly(styrene-b-(ethylene-co-butylene)-b-styrene) and its influence on morphology and facilitated olefin transport , 2008 .

[253]  D. Olson,et al.  Zeolitic imidazolate frameworks for kinetic separation of propane and propene. , 2009, Journal of the American Chemical Society.

[254]  A. C. Habert,et al.  Brazilian Journal of Chemical Engineering RECENT ACHIEVEMENTS IN FACILITATED TRANSPORT MEMBRANES FOR SEPARATION PROCESSES , 2007 .

[255]  K. Kuraoka,et al.  Ethylene/Ethane Separation through a SiO2–Poly(sodium acrylate)–Ag+ Organic–Inorganic Hybrid Membrane , 2014 .

[256]  Xu Li,et al.  A novel multi-armed and star-like poly(ethylene oxide) membrane for CO2 separation , 2015 .

[257]  J. Caro,et al.  Paralyzed membrane: Current-driven synthesis of a metal-organic framework with sharpened propene/propane separation , 2018, Science Advances.

[258]  Xiaotong Wei,et al.  Ultrathin carbon molecular sieve membrane for propylene/propane separation , 2016 .

[259]  G. Hsiue,et al.  Novel methods in separation of olefin/paraffin mixtures by functional polymeric membranes , 1993 .

[260]  Chen Zhang,et al.  Carbon molecular sieve structure development and membrane performance relationships , 2017 .

[261]  Kang Li,et al.  Olefin/paraffin separation using membrane based facilitated transport/chemical absorption techniques , 2012 .

[262]  Invited Contribution Modelling of Ethane/Ethylene Separation Using Microporous Carbon , 2005 .

[263]  Richard W. Baker,et al.  Gas Separation Membrane Materials: A Perspective , 2014 .

[264]  H. Kita,et al.  Olefin/paraffin separation performance of carbonized membranes derived from an asymmetric hollow fiber membrane of 6FDA/BPDA-DDBT copolyimide , 2003 .

[265]  H. Maghsoudi Comparative study of adsorbents performance in ethylene/ethane separation , 2016, Adsorption.

[266]  Rong Wang,et al.  Separation of CO2 from CH4 by using gas–liquid membrane contacting process , 2007 .

[267]  Luhong Zhang,et al.  A Novel Copper(I)-Based Supported Ionic Liquid Membrane with High Permeability for Ethylene/Ethane Separation , 2017 .

[268]  I. Ortiz,et al.  Using Membrane Reactive Absorption Modeling to Predict Optimum Process Conditions in the Separation of Propane–Propylene Mixtures , 2013 .

[269]  D. Sholl,et al.  Screening of Copper Open Metal Site MOFs for Olefin/Paraffin Separations Using DFT-Derived Force Fields , 2016 .

[270]  A. Ismail,et al.  Characterization of Polyethersulfone/Cloisite 15A Mixed Matrix Membrane for CO2/CH4 Separation , 2014 .

[271]  Xianshe Feng,et al.  Liquid Separation by Membrane Pervaporation: A Review , 1997 .

[272]  A. Ahmad,et al.  Comparative studies on the effects of casting solvent on physico-chemical and gas transport properties of dense polysulfone membrane used for CO2/CH4 separation , 2015 .

[273]  W. Koros,et al.  Performance of 6FDA6FpDA polyimide for propylene/propane separations , 2010 .

[274]  A. Russell,et al.  Review of recent advances in carbon dioxide separation and capture , 2013 .

[275]  R. Sheikholeslami,et al.  Fouling mitigation in membrane processes: Report on a Workshop held January 26–29, 1999, Technion — Israel Institute of Technology, Haifa, Israel☆ , 1999 .

[276]  Luhong Zhang,et al.  A Novel Supported Liquid Membrane Based on Binary Metal Chloride Deep Eutectic Solvents for Ethylene/Ethane Separation , 2017 .

[277]  M. Toriida,et al.  Enhanced propylene/propane separation by carbonaceous membrane derived from poly (aryl ether ketone)/2,6-bis(4-azidobenzylidene)-4-methyl-cyclohexanone interpenetrating network , 2009 .

[278]  Luhong Zhang,et al.  Silver-Based Deep Eutectic Solvents as Separation Media: Supported Liquid Membranes for Facilitated Olefin Transport , 2017 .

[279]  T. Kaghazchi,et al.  A novel separation process for olefin gas purification: Effect of operating parameters on separation performance and process optimization , 2009 .

[280]  Rajamani Krishna,et al.  Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites , 2012, Science.

[281]  V. Nikolakis,et al.  Separation of Propylene/Propane Mixtures Using Faujasite-Type Zeolite Membranes , 2005 .

[282]  T. Kaghazchi,et al.  Propylene/propane separation using N-methyl pyrrolidone/AgNO3 supported liquid membrane , 2015 .

[283]  Yi Li,et al.  MIXED MATRIX MEMBRANES (MMMS) COMPRISING ORGANIC POLYMERS WITH DISPERSED INORGANIC FILLERS FOR GAS SEPARATION , 2007 .

[284]  R. Eldridge,et al.  Olefin/Paraffin Separations by Reactive Absorption: A Review , 1998 .

[285]  Chang Kon Kim,et al.  Role of anions for the reduction behavior of silver ions in polymer/silver salt complex membranes , 2005 .

[286]  Shuji Himeno,et al.  Synthesis and Permeation Properties of a DDR-Type Zeolite Membrane for Separation of CO2/CH4 Gaseous Mixtures , 2007 .

[287]  Y. Kang,et al.  Facile Synthesis of Copper Nanoparticles by Ionic Liquids and Its Application to Facilitated Olefin Transport Membranes , 2009 .

[288]  Seong Uk Hong,et al.  Effect of water on the facilitated transport of olefins through solid polymer electrolyte membranes , 2001 .

[289]  A. Chakma,et al.  Unusual behavior of poly(ethylene oxide)/AgBF4 polymer electrolyte membranes for olefin–paraffin separation , 2004 .

[290]  Y. Kang,et al.  Dependence of facilitated olefin transport on the thickness of silver polymer electrolyte membranes , 2004 .

[291]  Yingfei Hou,et al.  Molecular simulation for separation of ethylene and ethane by functionalised graphene membrane , 2019, Molecular Simulation.