Photoluminescence imaging of mechanically produced defects in MgO

Abstract Deformed MgO displays a strong blue photoluminescence when illuminated by 248 nm excimer laser radiation. This photoluminescence is readily imaged in situ (during laser exposure) using commercial microscope optics. Photoluminescence images of indented, cleaved, abraded, and laser-damaged surfaces, are reported and the observed features are related to the expected deformation patterns. Locally deformed regions on MgO single crystals are sites of localized absorption at 248 nm and serve to nucleate localized damage under high fluence irradiation. Photoluminescence imaging has great potential for the identification of flaws in optical materials prior to, during and after exposure to damaging fluences of laser radiation and for fundamental studies of deformation, fracture and tribology.

[1]  J. Hirth,et al.  Theory of Dislocations (2nd ed.) , 1983 .

[2]  M. M. Chaudhri The displacement of material and the formation of {1l0}90, cracks around spherical indentations in MgO crystals , 1986 .

[3]  J. Dickinson,et al.  Production and Properties of Ejecta Released by Fracture of Materials , 1988 .

[4]  J. Wertz,et al.  Electron spin resonance studies of radiation effects in inorganic solids , 1961 .

[5]  Jens Lothe John Price Hirth,et al.  Theory of Dislocations , 1968 .

[6]  T. Schultheiss,et al.  A Study of the Effect of Deformation on Optical Absorption of MgO Single Crystals , 1973 .

[7]  T. Hasegawa,et al.  Wear damage of MgO single crystals , 1978 .

[8]  G. K. Walters,et al.  Paramagnetic Resonance of Defects Introduced Near the Surface of Solids by Mechanical Damage , 1961 .

[9]  S. C. Langford,et al.  Interactions of wide band gap single crystals with 248 nm excimer laser radiation. III. The role of cleavage‐induced defects in MgO , 1993 .

[10]  T. J. Turner,et al.  Luminescence in deformed MgO, CaO and SrO , 1975 .

[11]  W. A. Sibley,et al.  A Study of the Effect of Deformation on the ESR, Luminescence, and Absorption of MgO Single Crystals , 1969 .

[12]  W. Read,et al.  Dislocations in Crystals , 1953 .

[13]  S. C. Langford,et al.  Interactions of wide band-gap single crystals with 248 nm excimer laser radiation. II: NaCl , 1993 .

[14]  W. Johnston,et al.  Dislocation Multiplication in Lithium Fluoride Crystals , 1960 .

[15]  C. C. Wu,et al.  Lattice Misorientation and Displaced Volume for Microhardness Indentations in MgO Crystals , 1978 .

[16]  B. Lawn,et al.  Cleavage step deformation in brittle solids , 1974 .

[17]  J. Dickinson,et al.  Electrical charge measurements on ejecta from impact loading of explosive crystals , 1989 .