A study on the cement-based decorative materials in the San Fedele Church in Milan

Abstract Cement-based materials have been used since the 19th century for different decorative purposes, and a high levels of expertise has often reached in reproducing or restoring even quite elaborated stoneworks. An important example is the application of cement-based decorative materials on the facades of the San Fedele church in Milan. The church, built in the 16th century and characterized by the presence of pinkish-yellowish Angera stone on the facades, was subjected, especially in the 20th century, to several restoration works. Damaged decorative elements of the facades as well as portions of its structural elements were replaced or covered in the last century by “stone imitating render”, made with cementitious materials which imitate the original Angera stone. In this study, several samples of cement-based decorative materials, collected from different elements of the external facades of the Church, were characterized by several analytic techniques (thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and IR analysis), in order to investigate both their microstructure and composition, how the chromatic aspect of the cementitious materials were obtained and their conservation state and to provide useful information for the possible reproduction of materials with comparable appearance to be used in a further restoration project. Results showed that the cement-based materials and decorations were obtained by the application of different layers of renders; in particular, the colour and texture of finishing layer were achieved by blending the binder with fine dolomite particles, probably obtained by grinding the Angera stone. This technique not only allowed an amazing reproduction of the original stone, but also resulted in a durable protection, since the cement-based decorative materials did not show any significant degradation phenomena in the polluted environment of the centre of Milan.

[1]  L. Bertolini,et al.  Corrosion behaviour of metal inserts in simulated ancient masonry mortars , 2015 .

[2]  Zheng-wu Jiang,et al.  Study on utilization of red brick waste powder in the production of cement-based red decorative plaster for walls , 2016 .

[3]  W. Lin,et al.  Improved microstructure of cement-based composites through the addition of rock wool particles , 2013 .

[4]  Raffaella Rossi-Manaresi,et al.  La Chimica nel Restauro: I Materiali dell'Arte Pittorica , 1991 .

[5]  Lucia Toniolo,et al.  The Angera stone: a challenging conservation issue in the polluted environment of Milan (Italy) , 2013, Environmental Earth Sciences.

[6]  Antonia Moropoulou,et al.  Investigation of the technology of historic mortars , 2000 .

[7]  R. Silverstein,et al.  Spectrometric identification of organic compounds , 2013 .

[8]  Fabio Fatiguso,et al.  Investigation and conservation of artificial stone facades of the early XX century: A case study , 2013 .

[9]  G. W. Small Spectrometric Identification of Organic Compounds , 1992 .

[10]  Luca Bertolini,et al.  Effects of weathering on colour of concrete paving blocks , 2011 .

[11]  F. Fratini,et al.  Artificial stones utilised in Florence historical palaces between the XIX and XX centuries , 2005 .

[12]  Antonia Moropoulou,et al.  Characterization of ancient, byzantine and later historic mortars by thermal and X-ray diffraction techniques☆ , 1995 .

[13]  H. A. Heinemann,et al.  Historic Concrete : From Concrete Repair to Concrete Conservation , 2013 .

[14]  H. Akbari,et al.  Solar spectral optical properties of pigments—Part II: survey of common colorants , 2004 .

[15]  L. Bertolini,et al.  Binder characterisation of mortars used at different ages in the San Lorenzo church in Milan , 2013 .

[16]  S. V. Kumar,et al.  Characterization of 6–11th century A.D decorative lime plasters of rock cut caves of Ellora , 2015 .