Organic thin-film transistors: A review of recent advances

In this paper we review recent progress in materials, fabrication processes, device designs, and applications related to organic thin-film transistors (OTFTs), with an emphasis on papers published during the last three years. Some earlier papers that played an important role in shaping the OTFT field are included, and a number of previously published review papers that cover that early period more completely are referenced. We also review in more detail related work that originated at IBM during the last four years and has led to the fabrication of high-performance organic transistors on flexible, transparent plastic substrates requiring low operating voltages.

[1]  Henrik Stubb,et al.  Molecular field‐effect transistors using conducting polymer Langmuir–Blodgett films , 1990 .

[2]  Klaus Müllen,et al.  A Soluble Pentacene Precursor: Synthesis, Solid‐State Conversion into Pentacene and Application in a Field‐Effect Transistor , 1999 .

[3]  Magnus Willander,et al.  Field‐effect mobility of poly(3‐hexylthiophene) , 1988 .

[4]  Gilles Horowitz,et al.  Organic Field‐Effect Transistors , 1998 .

[5]  Richard H. Friend,et al.  Integrated, high-mobility polymer field-effect transistors driving polymer light-emitting diodes , 1999 .

[6]  A. Dodabalapur,et al.  A soluble and air-stable organic semiconductor with high electron mobility , 2000, Nature.

[7]  Guofeng Xu,et al.  Langmuir−Blodgett Films of Regioregular Poly(3-hexylthiophene) as Field-Effect Transistors , 2000 .

[8]  Thomas N. Jackson,et al.  Pentacene-based organic thin-film transistors , 1997 .

[9]  A. Yassar,et al.  All-Polymer Field-Effect Transistor Realized by Printing Techniques , 1994, Science.

[10]  Walter Riess,et al.  Influence of trapped and interfacial charges in organic multilayer light-emitting devices , 2001, IBM J. Res. Dev..

[11]  C. M. Hart,et al.  Low-cost all-polymer integrated circuits , 1998, Proceedings of the 24th European Solid-State Circuits Conference.

[12]  H. Ifill,et al.  High-Information-Content Color 16 . 3 ”-Desktop-AMLCD with 15 . 7 Million a-Si : H TFTs , 1998 .

[13]  R. Friend,et al.  New semiconductor device physics in polymer diodes and transistors , 1988, Nature.

[14]  Howard E. Katz,et al.  Solution-phase deposition of oligomeric TFT semiconductors , 1999 .

[15]  Charles E. Swenberg,et al.  Electronic Processes in Organic Crystals and Polymers , 1999 .

[16]  M. Le Contellec,et al.  Field-effect transistor with diphthalocyanine thin film , 1988 .

[17]  Richard H. Friend,et al.  Field-Enhanced Conductivity in PolyacetyleneDConstruction of a Field-Effect Transistor , 1989 .

[18]  C. Dimitrakopoulos,et al.  Low-voltage organic transistors on plastic comprising high-dielectric constant gate insulators , 1999, Science.

[19]  B. Batlogg,et al.  Ambipolar pentacene field-effect transistors and inverters. , 2000, Science.

[20]  Howard E. Katz,et al.  Synthesis, Morphology, and Field-Effect Mobility of Anthradithiophenes. , 1998 .

[21]  Thomas N. Jackson,et al.  Temperature-independent transport in high-mobility pentacene transistors , 1998 .

[22]  Sampath Purushothaman,et al.  Low-Voltage, High-Mobility Pentacene Transistors with Solution-Processed High Dielectric Constant Insulators , 1999 .

[23]  Niels Bent Larsen,et al.  SELF-ASSEMBLY OF REGIOREGULAR, AMPHIPHILIC POLYTHIOPHENES INTO HIGHLY ORDERED PI -STACKED CONJUGATED POLYMER THIN FILMS AND NANOCIRCUITS , 1998 .

[24]  Howard E. Katz,et al.  Morphological origin of high mobility in pentacene thin-film transistors , 1996 .

[25]  Dago M. de Leeuw,et al.  Field-effect transistors made from solution-processed organic semiconductors , 1997 .

[26]  E. W. Meijer,et al.  Two-dimensional charge transport in self-organized, high-mobility conjugated polymers , 1999, Nature.

[27]  Sampath Purushothaman,et al.  Field-effect transistors comprising molecular beam deposited α,ω-di-hexyl-hexathienylene and polymeric insulator , 1998 .

[28]  S. M. Sze Physics of semiconductor devices /2nd edition/ , 1981 .

[29]  Francis Garnier,et al.  Thin film transistors based on organic conjugated semiconductors , 1997 .

[30]  T. Kurokawa,et al.  Electrical properties of polyacetylene/polysiloxane interface , 1983 .

[31]  H. Sirringhaus,et al.  Integrated optoelectronic devices based on conjugated polymers , 1998, Science.

[32]  Gilles Horowitz,et al.  Dihexylquaterthiophene, A Two-Dimensional Liquid Crystal-like Organic Semiconductor with High Transport Properties† , 1998 .

[33]  Zhenan Bao,et al.  High-performance plastic transistors fabricated by printing techniques , 1997 .

[34]  Yuan Taur,et al.  Fundamentals of Modern VLSI Devices , 1998 .

[35]  J. Jacobson,et al.  An electrophoretic ink for all-printed reflective electronic displays , 1998, Nature.

[36]  Hiroshi Koezuka,et al.  Field-effect transistor with a conducting polymer film , 1991 .

[37]  Andrew J. Lovinger,et al.  Soluble Regioregular Polythiophene Derivatives as Semiconducting Materials for Field-Effect Transistors , 1999 .

[38]  Olle Inganäs,et al.  Electronic and optical studies with Langmuir-Blodgett transistors , 1992 .

[39]  T. Jackson,et al.  Stacked pentacene layer organic thin-film transistors with improved characteristics , 1997, IEEE Electron Device Letters.

[40]  Lewis J. Rothberg,et al.  Electrically active organic and polymeric materials for thin-film-transistor technologies , 1996 .

[41]  Howard E. Katz,et al.  Synthesis, Solubility, and Field-Effect Mobility of Elongated and Oxa-Substituted α,ω-Dialkyl Thiophene Oligomers. Extension of “Polar Intermediate” Synthetic Strategy and Solution Deposition on Transistor Substrates , 1998 .

[42]  B. Servet,et al.  Molecular engineering of organic semiconductors: design of self-assembly properties in conjugated thiophene oligomers , 1993 .

[43]  Hiroshi Koezuka,et al.  Polythienylenevinylene thin‐film transistor with high carrier mobility , 1993 .

[44]  A. R. Brown,et al.  Logic Gates Made from Polymer Transistors and Their Use in Ring Oscillators , 1995, Science.

[45]  Stephen C. Moratti,et al.  Bis(dithienothiophene) organic field-effect transistors with a high ON/OFF ratio , 1997 .

[46]  Howard E. Katz,et al.  α,ω-Dihexylquaterthiophene: A Second Thin Film Single-Crystal Organic Semiconductor , 1998 .

[47]  Susanne Scheinert,et al.  Theory of organic field effect transistors , 1998 .

[48]  T. M. Klapwijk,et al.  Coulomb-blockade transport in single-crystal organic thin-film transistors , 2000, Nature.

[49]  Tian-An Chen,et al.  Regiocontrolled Synthesis of Poly(3-alkylthiophenes) Mediated by Rieke Zinc: Their Characterization and Solid-State Properties , 1995 .

[50]  Zhenan Bao,et al.  Organic field‐effect transistors with high mobility based on copper phthalocyanine , 1996 .

[51]  Hiroyuki Sakaki,et al.  Field‐effect transistors using alkyl substituted oligothiophenes , 1991 .

[52]  Gilles Horowitz,et al.  Role of the semiconductor/insulator interface in the characteristics of π-conjugated-oligomer-based thin-film transistors , 1992 .

[53]  Sampath Purushothaman,et al.  trans-trans-2,5-Bis-[2-{5-(2,2'-bithienyl)}ethenyl]thiophene : synthesis, characterization, thin film deposition and fabrication of organic field-effect transistors , 1997 .

[54]  Wilhelm Warta,et al.  High-field saturation of charge carrier drift velocities in ultrapurified organic photoconductors , 1991 .

[55]  Henrik Stubb,et al.  Field-effect conduction in polyalkylthiophenes , 1991 .

[56]  T. Jackson,et al.  High-mobility pentacene organic thin film transistors , 1996, 1996 54th Annual Device Research Conference Digest.

[57]  L. Torsi,et al.  Organic Transistors: Two-Dimensional Transport and Improved Electrical Characteristics , 1995, Science.

[58]  N. Karl,et al.  Charge-Carrier Mobility in Organic Crystals , 2001 .

[59]  Zhenan Bao,et al.  Soluble and processable regioregular poly(3‐hexylthiophene) for thin film field‐effect transistor applications with high mobility , 1996 .

[60]  Luisa Torsi,et al.  AN ANALYTICAL MODEL FOR SHORT-CHANNEL ORGANIC THIN-FILM TRANSISTORS , 1995 .

[61]  Robert C. Haddon,et al.  C60 thin film transistors , 1995 .

[62]  D.B.M. Klaassen,et al.  PRECURSOR ROUTE PENTACENE METAL-INSULATOR-SEMICONDUCTOR FIELD-EFFECT TRANSISTORS , 1996 .

[63]  Gilles Horowitz,et al.  A field-effect transistor based on conjugated alpha-sexithienyl , 1989 .

[64]  Christos D. Dimitrakopoulos,et al.  Molecular beam deposited thin films of pentacene for organic field effect transistor applications , 1996 .

[65]  Howard E. Katz,et al.  Organic molecular solids as thin film transistor semiconductors , 1997 .

[66]  Robert Wisnieff,et al.  Display technology: Printing screens , 1998, Nature.

[67]  H. Grubin The physics of semiconductor devices , 1979, IEEE Journal of Quantum Electronics.

[68]  Torahiko Ando,et al.  Macromolecular electronic device: Field-effect transistor with a polythiophene thin film , 1986 .

[69]  Zhenan Bao,et al.  The Physical Chemistry of Organic Field-Effect Transistors , 2000 .