Microfabricated Thermally Isolated Low Work-Function Emitter

In this paper, we report low work function mechanically and thermally robust microfabricated thermionic emitters. Conformal deposition of polycrystalline-silicon carbide (poly-SiC) was used to form stiff suspension legs with U-shaped cross sections, which increased the out-of-plane rigidity and helped to maintain a micrometer-scale gap between emitter and collector. The structurally robust poly-SiC suspended structure was coated with a thin tungsten layer to improve adhesion of a work function lowering coating (BaO/SrO/CaO). The measured emitter work function was 1.2 eV and emission current density was >0.1 A/cm2, which are promising for applications such as thermionic energy converters.

[1]  R. Howe,et al.  Thermionic current densities from first principles. , 2013, The Journal of chemical physics.

[2]  R. Howe,et al.  An orbital-overlap model for minimal work functions of cesiated metal surfaces , 2012, Journal of physics. Condensed matter : an Institute of Physics journal.

[3]  R. Howe,et al.  ENCAPSULATED THERMIONIC ENERGY CONVERTER WITH STIFFENED SUSPENSION , 2012 .

[4]  Jae Hyung Lee,et al.  Optimal emitter-collector gap for thermionic energy converters , 2012 .

[5]  R. Howe,et al.  Microfabricated silicon carbide thermionic energy converter for solar electricity generation , 2012, 2012 IEEE 25th International Conference on Micro Electro Mechanical Systems (MEMS).

[6]  R. Howe,et al.  ALD-metal uncooled bolometer , 2011, 2011 IEEE 24th International Conference on Micro Electro Mechanical Systems.

[7]  Piero Pianetta,et al.  Photon-enhanced thermionic emission for solar concentrator systems. , 2010, Nature materials.

[8]  Albert P. Pisano,et al.  Growth and characterization of nitrogen-doped polycrystalline 3C-SiC thin films for harsh environment MEMS applications , 2010 .

[9]  K. Haenen,et al.  Thermionic electron emission from low work-function phosphorus doped diamond films , 2009 .

[10]  P. Schmidt,et al.  Model of work function of tungsten cathodes with barium oxide coating , 2004 .

[11]  Kevin R. Zavadil,et al.  Low work function material development for the microminiature thermionic converter. , 2004 .

[12]  Chunbo Zhang,et al.  Micro combustion-thermionic power generation: feasibility, design and initial results , 2003, TRANSDUCERS '03. 12th International Conference on Solid-State Sensors, Actuators and Microsystems. Digest of Technical Papers (Cat. No.03TH8664).

[13]  D. King,et al.  Results from the microminiature thermionic converter demonstration testing program , 1998, Collection of Technical Papers. 35th Intersociety Energy Conversion Engineering Conference and Exhibit (IECEC) (Cat. No.00CH37022).

[14]  G. O. Fitzpatrick,et al.  Close-spaced thermionic converters with active spacing control and heat-pipe isothermal emitters , 1996, IECEC 96. Proceedings of the 31st Intersociety Energy Conversion Engineering Conference.

[15]  John M. Houston,et al.  Theoretical Efficiency of the Thermionic Energy Converter , 1959 .

[16]  G. Feaster Thermionic Diodes as Energy Converters : An Addendum† , 1958 .

[17]  George N. Hatsopoulos,et al.  Measured Thermal Efficiencies of a Diode Configuration of a Thermo Electron Engine , 1958 .

[18]  N. Melosh,et al.  THERMIONIC EMISSION FROM MICROFABRICATED SILICON-CARBIDE FILAMENTS , 2009 .

[19]  Chunbo Zhang Combustion-based micro power generation: Thermoelectric and thermionic approaches. , 2003 .

[20]  E. Tomková,et al.  Thermionic energy converter in magnetic field , 1965 .

[21]  Hilary Moss,et al.  XXXII. Thermionic Diodes as Energy Converters , 1957 .

[22]  George Nicholas Hatsopoulos,et al.  The thermo-electron engine , 1956 .

[23]  W. Schlichter,et al.  Die spontane Elektronenemission glhender Metalle und das glhelektrische Element , 1915 .