Residual stresses in microelectronics induced by thermoset packaging materials during cure

This paper presents a constitutive model for predicting the stresses in thermosetting resins during cure. An overview is given of the experimental techniques used for determining the parameters in this model. The model is validated by comparing its predictions to additional measurements, which have not been used for the actual parameter estimation. This validation showed that the model is capable of giving fair predictions of the measured stresses. The model is implemented in a commercially available finite element package and its use is demonstrated by applying it to the study of a flip-chip underfilling process.

[1]  James E. Martin,et al.  Time-cure superposition during crosslinking , 1990 .

[2]  James E. Martin,et al.  Calculation of Stresses in Crosslinking Polymers , 1996 .

[3]  M. Mackay,et al.  Chemorheology of thermosets—an overview , 1996 .

[4]  M. S. Kiasat Curing Shrinkage and Residual Stresses in Viscoelastic Thermosetting Resins and Composites , 2000 .

[5]  R. Farris,et al.  Determination of residual stresses using incremental linear elasticity , 1994 .

[6]  Robert S. Chambers,et al.  Stresses during thermoset cure , 1998 .

[7]  H. Henning Winter,et al.  Rheology of Polymers Near Liquid-Solid Transitions , 1997 .

[8]  J. M. Salla,et al.  Determination of gel and vitrification times of thermoset curing process by means of TMA, DMTA and DSC techniques , 1997 .

[9]  G. Assche,et al.  Modulated temperature differential scanning calorimetry: Cure, vitrification, and devitrification of thermosetting systems , 1997 .

[10]  P. Halley,et al.  Understanding vitrification during cure of epoxy resins using dynamic scanning calorimetry and rheological techniques , 2000 .

[11]  Scott R. White,et al.  Process Modeling of Composite Materials: Residual Stress Development during Cure. Part I. Model Formulation , 1992 .

[12]  J. Gérard,et al.  Temperature dependence of the behavior of a reactive epoxy-amine system by means of dynamic rheology. 2. High-Tg epoxy-amine system , 1996 .

[13]  J. Gérard,et al.  Temperature dependence of the behavior of an epoxy-amine system near the gel point through viscoelastic study. 1. Low-Tg epoxy-amine system , 1996 .

[14]  G. Van Assche,et al.  TMDSC and Dynamic Rheometry, Gelation, Vitrification and Autoacceleration in the Cure of an Unsaturated Polyester Resin , 2000 .

[15]  Christopher W. Macosko,et al.  Rheology: Principles, Measurements, and Applications , 1994 .