Preflight Diffusion Experiments on Liquid Metals Under 1g Conditions for the FOTON‐M2 Mission

Abstract:  We measured diffusion of up to 5% Ag in liquid Pb, using the Foton shear cell (designed and used for the FOTON‐M2 mission). Since the density change of the alloy with composition has been reported to be very small but is not reliably known, we performed two arrangements of layering: (a) with PbAg on top and Pb below and (b) with Pb on top and PbAg below. The Berlin group did interdiffusion experiments from a “thick layer” of PbAg into “semi‐infinite” Pb and the Karlsruhe group did the typical “interdiffusion” experiments with a diffusion couple of PbAg versus Pb. The results of both groups were equivalent, showing much lower D values for arrangement (b) than for (a). The lower values were even definitely lower than reference microgravity values from MIR/MIM and could be fitted by D=ATn with n about 2.2. We discuss the stability/instability by density layering depending on the arrangement.

[1]  Shinsuke Suzuki,et al.  Diffusion Measurement on Liquid Metallic Materials and Development of Shear Cell(Preparation for Russian Satellite Mission Foton-M2) , 2005 .

[2]  Shinsuke Suzuki,et al.  Shear cell development for diffusion experiments in FOTON-Satellite missions and on the ground with consideration of shear-induced convection , 2005 .

[3]  Shinsuke Suzuki,et al.  Diffusion experiments in liquid Sn-Bi and Al-Ni systems with a stable density layering using the FOTON shear cell under 1g conditions , 2005 .

[4]  W. Huang,et al.  The Measurement of Solute Diffusion Coefficients in Dilute Liquid Alloys: The Influence of Unit Gravity and G‐Jitter on Buoyancy Convection , 2004, Annals of the New York Academy of Sciences.

[5]  Shinsuke Suzuki,et al.  Ground‐Based Diffusion Experiments on Liquid Sn‐In Systems Using the Shear Cell Technique of the Satellite Mission Foton‐M1 , 2004, Annals of the New York Academy of Sciences.

[6]  R. Moreau,et al.  A new measurement method of solute diffusivities based on MHD damping of convection in liquid metals and semi-conductors , 2002 .

[7]  R. Willnecker,et al.  Liquid Diffusion Measurements with the Shear Cell Technique - Study of Shear Convection , 2001 .

[8]  P. Bräuer,et al.  Measurements of aluminum diffusion in molten gallium and indium , 1998 .

[9]  G. Müller‐vogt,et al.  Application of the shear cell technique to diffusivity measurements in melts of semiconducting compounds : Ga-Sb , 1998 .

[10]  W. Arnold,et al.  Numerical Simulation of the Effect of Shearing on the Concentration Profile in a Shear Cell , 1995 .

[11]  H. Dodeck,et al.  The German Spacelab Mission D-2. , 1993 .

[12]  L. Martin-Garin,et al.  Masses volumiques de l'argent, du germanium et des alliages Ag-Ge à l'etat liquide , 1975 .

[13]  F. Sauerwald The densities of molten alloys with segregation tendencies , 1967 .