Facile synthesis of functionalized porous carbon with three-dimensional interconnected pore structure for high volumetric performance supercapacitors

Abstract Functionalized porous carbon with three-dimensional (3D) interconnected pore structure has been successfully synthesized through direct heat-treatment of KOH-soaked soybeans. Benefiting from heteroatoms (N, O) doping, interconnected porous carbon framework with high surface area as well as high packing density (up to 1.1 g cm −3 ), the as-obtained porous carbon material exhibits high volumetric capacitance of 468 F cm −3 , good rate capability and excellent cycling stability (91% of capacitance retention after 10,000 cycles) in 6 M KOH electolyte. More importantly, the as-assembled symmetric supercapacitor delivers high volumetric energy density of 28.6 Wh L −1 in 1 M Na 2 SO 4 aqueous solution.

[1]  R. Ruoff,et al.  Carbon-Based Supercapacitors Produced by Activation of Graphene , 2011, Science.

[2]  Q. Wang,et al.  Template synthesis of hollow carbon spheres anchored on carbon nanotubes for high rate performance supercapacitors , 2013 .

[3]  V. Presser,et al.  Carbons and Electrolytes for Advanced Supercapacitors , 2014, Advanced materials.

[4]  Wenhui He,et al.  Template-free synthesis of renewable macroporous carbon via yeast cells for high-performance supercapacitor electrode materials. , 2013, ACS applied materials & interfaces.

[5]  A. Burke Ultracapacitors: why, how, and where is the technology , 2000 .

[6]  P. Shen,et al.  Simultaneous Formation of Ultrahigh Surface Area and Three‐Dimensional Hierarchical Porous Graphene‐Like Networks for Fast and Highly Stable Supercapacitors , 2013, Advanced materials.

[7]  Satishchandra Ogale,et al.  From dead leaves to high energy density supercapacitors , 2013 .

[8]  Jinhua Jiang,et al.  Hierarchical porous carbons with controlled micropores and mesopores for supercapacitor electrode materials , 2008 .

[9]  Y. Gogotsi,et al.  True Performance Metrics in Electrochemical Energy Storage , 2011, Science.

[10]  A. Benayad,et al.  Synthesis of Chemically Bonded Graphene/Carbon Nanotube Composites and their Application in Large Volumetric Capacitance Supercapacitors , 2013, Advanced materials.

[11]  Jiayan Luo,et al.  Effect of sheet morphology on the scalability of graphene-based ultracapacitors. , 2013, ACS nano.

[12]  L. Zhi,et al.  Porous layer-stacking carbon derived from in-built template in biomass for high volumetric performance supercapacitors , 2015 .

[13]  Q. Wang,et al.  Recent Advances in Design and Fabrication of Electrochemical Supercapacitors with High Energy Densities , 2014 .

[14]  Zhanwei Xu,et al.  Colossal pseudocapacitance in a high functionality–high surface area carbon anode doubles the energy of an asymmetric supercapacitor , 2014 .

[15]  S. Liao,et al.  High-performance doped carbon electrocatalyst derived from soybean biomass and promoted by zinc chloride , 2014 .

[16]  G. Lu,et al.  3D aperiodic hierarchical porous graphitic carbon material for high-rate electrochemical capacitive energy storage. , 2008, Angewandte Chemie.

[17]  Xiulei Ji,et al.  Pyrolysis of cellulose under ammonia leads to nitrogen-doped nanoporous carbon generated through methane formation. , 2014, Nano letters.

[18]  M. Marina,et al.  High performance liquid chromatography and capillary electrophoresis in the analysis of soybean proteins and peptides in foodstuffs. , 2007, Journal of separation science.

[19]  Don Harfield,et al.  Interconnected carbon nanosheets derived from hemp for ultrafast supercapacitors with high energy. , 2013, ACS nano.

[20]  F. Wei,et al.  Template‐Directed Synthesis of Pillared‐Porous Carbon Nanosheet Architectures: High‐Performance Electrode Materials for Supercapacitors , 2012 .

[21]  Jun Yan,et al.  Template-assisted low temperature synthesis of functionalized graphene for ultrahigh volumetric performance supercapacitors. , 2014, ACS nano.

[22]  M. Oehzelt,et al.  Nitrogen-doped graphene: efficient growth, structure, and electronic properties. , 2011, Nano letters.

[23]  Long Hao,et al.  Carbonaceous Electrode Materials for Supercapacitors , 2013, Advanced materials.

[24]  T. Kyotani,et al.  Templated Nanocarbons for Energy Storage , 2012, Advanced materials.

[25]  Chi Cheng,et al.  Liquid-Mediated Dense Integration of Graphene Materials for Compact Capacitive Energy Storage , 2013, Science.

[26]  Fan Yang,et al.  Promising Carbons for Supercapacitors Derived from Fungi , 2011, Advanced materials.

[27]  Meilin Liu,et al.  Facile Synthesis of Nitrogen‐Doped Graphene via Pyrolysis of Graphene Oxide and Urea, and its Electrocatalytic Activity toward the Oxygen‐Reduction Reaction , 2012 .

[28]  Markus Antonietti,et al.  Engineering Carbon Materials from the Hydrothermal Carbonization Process of Biomass , 2010, Advances in Materials.

[29]  M. Čadek,et al.  Tuning Carbon Materials for Supercapacitors by Direct Pyrolysis of Seaweeds , 2009 .

[30]  Q. Wang,et al.  Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors , 2014 .

[31]  Y. Gogotsi,et al.  Capacitive energy storage in nanostructured carbon-electrolyte systems. , 2013, Accounts of chemical research.

[32]  Jun Song Chen,et al.  Nitrogen-containing microporous carbon nanospheres with improved capacitive properties , 2011 .

[33]  Maria Angeles Lillo-Rodenas,et al.  Understanding chemical reactions between carbons and NaOH and KOH: An insight into the chemical activation mechanism , 2003 .

[34]  François Béguin,et al.  A High‐Performance Carbon for Supercapacitors Obtained by Carbonization of a Seaweed Biopolymer , 2006 .

[35]  A. Bhaumik,et al.  Hierarchically porous carbon derived from polymers and biomass: effect of interconnected pores on energy applications , 2014 .

[36]  Y. Gogotsi,et al.  Materials for electrochemical capacitors. , 2008, Nature materials.

[37]  B. Dunn,et al.  Where Do Batteries End and Supercapacitors Begin? , 2014, Science.

[38]  Q. Wang,et al.  Interconnected Frameworks with a Sandwiched Porous Carbon Layer/Graphene Hybrids for Supercapacitors with High Gravimetric and Volumetric Performances , 2014 .

[39]  Jun Yan,et al.  Supercapacitors based on graphene-supported iron nanosheets as negative electrode materials. , 2013, ACS nano.